Conductivity of carbon black-based polymer composites under creep in the molten state

The mechanical deformation of conductive polymer composites during melt processing affects their final electrical properties considerably. To get an insight in this relationship, simultaneous electrical-rheological measurements can be used to follow the changes in composite phase structure induced by defined deformation. In this work, the evolution of electrical conductivity was investigated during and after shear deformation at constant stress. From the experiments performed it can be concluded, that the flow-induced build-up mechanism leads to the formation of conductive pathways with enhanced stability compared to the structures build-up under quiescent conditions. This finding can be explained by the orientation of particle structures in the shear direction. Therefore, materials with different deformation history but the same electrical conductivity can display markedly different electrical behaviour under deformation.     

A computational characterization of CO@C60

The carbon monoxide encapsulation into C₆₀ is evaluated using the DFT and MP2 calculations. The CO encapsulation is attractive, yielding an energy gain of more than 12 kcal/mol. This substantial encapsulation energy should produce at the conditions used in the high-temperature and high-pressure synthesis (originally used for encapsulation of rare gases in fullerenes) an equilibrium CO@C₆₀ fraction of about 3.5% compared to the empty C₆₀. The computed IR and NMR spectra agree with the available observations for CO encapsulated into open-cage C₆₀ derivatives.     

Comparative triplex tandem mass spectrometry assays of lysosomal enzyme activities in dried blood spots using fast liquid chromatography: application to newborn screening of Pompe, Fabry, and Hurler diseases

We report a comparative study of triplex tandem mass spectrometry (MS/MS) based assays of lysosomal enzymes in dried blood spots for the early detection of Pompe, Fabry, and Hurler diseases in newborns. Four methods have been evaluated that differed in sample handling and the equipment used. A newly developed method uses assay quenching with acetonitrile to precipitate blood proteins followed by analysis on an LC-electrospray/MS/MS system capable of multiple consecutive sample injections on two parallel chromatographic columns. This method requires 1.5 min per a triplex analysis of enzyme products and internal standards, which matches the throughput of the previously reported flow injection method. LC separation reduces matrix effects and allows for more facile sample workup. The new LC-based method showed figures of merit that were superior to those of the currently used method based on liquid-liquid extraction into ethyl acetate and flow injection into the mass spectrometer. The other methods we investigated for comprehensive comparison involved liquid-liquid extraction into ethyl acetate followed by LC-ESI-MS/MS and acetonitrile quenching followed by direct flow injection. Both methods using acetonitrile quenching were found to be robust and provide good quality data while requiring fewer liquid transfer steps and less disposable material and labor than did the extraction methods. The individual merits of the new methods are discussed to present an evaluated alternative approach to high-throughput analysis in newborn screening laboratories.     

Why the Observed Motion History of World Trade Center Towers Is Smooth

The collapse of the World Trade Center towers was initiated by the impact of the upper falling part onto the underlying intact story. At the moment of impact, the velocity of the upper part must have decreased. The fact that no velocity decrease can be discerned in the videos of the early motion of the tower top has been recently exploited to claim that the collapse explanation generally accepted within the structural mechanics community was invalid. This claim is here shown to be groundless. Calculations show that the velocity drop is far too small to be perceptible in amateur video records and is much smaller than the inevitable error of such video records.     

Carbon nanotubes: do they toughen brittle matrices?

The development of a model CNT-brittle matrix composite system, based on SiO₂ glass containing well-dispersed CNTs at up to 15 wt%, allows a direct assessment of the effect of the nanoscale filler on fracture toughness (K _IC). Samples were prepared by colloidal heterocoagulation followed by spark plasma sintering. Detailed K _IC measurements, using both indentation and notched beam techniques, show a linear improvement with CNT content, with up to a twofold increase of fracture toughness at maximum loading. The results from the two methods used in this study show equivalent trends but differing absolute values; the relative merits of these two approaches to measuring nanocomposite toughness are compared. Possible toughening mechanisms associated with CNT pull-out, crack bridging, and crack deflection are identified, and discussed quantitatively, drawing on conventional short-fibre composite theory and the potential effects of scaling fibre diameter.     

Some optical and electrical properties of the As2Se3−xTex system

Some optical and electrical properties of the As₂Se_3?xTe_x system (0 ≤ x ≤ 0.15) have been studied. The value of the optical gap decreases from 1.74 eV to 1.59 eV. The slope of the absorption edge changes, so that value of E_o from the relation α ～ exp ($\text{h}\text{?}\text{ω}\text{E}{}_{\mathrm{o}}$) exhibits a maximum value in neighbourhood of composition As₂Se_2.9Te_0.1. The d.c. and a.c. conductivities have been studied. The value of the activation energy E_el ～ 1.8 eV is almost unchanged up to x = 0.15. The a.c. conductivity fulfils the relation $\text{б(ω) ～ ω}{}^{\mathrm{<mtext>s</mtext>}}$ where s ? 1 and 1.1. at frequencies f < 1 kHz and f > 1 kHz respectively.     

Justification and refinements of model B3 for concrete creep and shrinkage 2. Updating and theoretical basis

Following statistical evaluation in part 1, this part deals with the improvement of prediction by updating one or two parameters of the model on the basis of short term tests and theoretical derivation of some formulae. The updating of model parameters is particularly important for high strength concretes and other special concretes containing various admixtures, superplasticizers, water-reducing agents and pozzolanic materials. For the updating of shrinkage prediction, a new method is presented in which the shrinkage half-time is calibrated by simultaneous measurements of water loss. This approach circumvents the ill-posedness of the shrinkage extrapolation problem. Theoretical justifications of various aspects of the model are given and a new formula for the additional creep due to drying (or stress-induced shrinkage) is derived. The new model should allow a more realistic assessment of the creep and shrinkage effects in concrete structures, which significantly affect durability and long term serviceability of civil engineering infrastructure.