pH measurement in the vicinity of a cathode evolving hydrogen gas using an antimony microelectrode

An antimony microelectrode was prepared by quenching a molten Sb–Sb2O3 mixture (2% Sb2O3). The local pH in the vicinity of a cathode evolving hydrogen gas was directly measured using the microelectrode. The local pH during electrolysis of KCl-glycine aqueous solutions was increased by proton consumption; however, the increment decreased with increasing concentrations of glycine, a buffering agent. The diffusion-limiting current density of hydrogen evolution involving proton reduction was controlled by the concentrations of the proton-donating species: protonated-glycine +H3NCH2COOH and H3O+ ions. A plot of the current density against the sum of the concentrations gives a single straight line passing through the origin. The phenomena are discussed in terms of electrodeposition processes of base metals.     

Dual roles of proteasome in the metabolism of presenilin 1

Presenilin 1 (PS1) has been identified as a causative gene for most early-onset familial Alzheimer's disease. Biochemical studies revealed that PS1 exists predominantly as two processed fragments in cells and brain tissues. We prepared stably transfected cells expressing the wild-type and familial Alzheimer's disease-associated mutants of PS1 and investigated the enzyme that participates in the metabolism of PS1. After treatment of the cells with proteasome inhibitors, the full-length PS1 was significantly accumulated. The levels of N- and C-terminal fragments were also increased. The accumulation of PS1 with a deletion of exon 10, which is unable to be processed, on treatment of the transfected cells with lactacystin indicated that proteasome can degrade full-length PS1. A synthetic peptide that includes the processing region of PS1 was cleaved by 20S proteasome at the putative processing sites after Met288 and Glu299. Metabolic labeling experiments showed that the appearance of the N-terminal fragment was attenuated by the inhibitor. Finally, 28-kDa N- and 20-kDa C-terminal fragments were generated by purified PS1 in vitro. These data indicated that the proteasome pathway is involved in PS1 processing. These results demonstrate that the proteasome pathway plays dual roles in processing and degradation of PS1.     

Pyrrolizidine Alkaloids Mediate Host-Plant Recognition by Ovipositing Females of an Old World Danaid Butterfly, Idea leuconoe

A giant danaid butterfly, Idea leuconoe, specializes on apocynaceous plants such as Parsonsia laevigata, which has been reported to contain pyrrolizidine alkaloids. Females of I. leuconoe deposited eggs in response to methanolic extract of P. laevigata, and subsequent bioassay-guided fractionation of the extract revealed that phytochemicals crucial for host recognition by ovipositing females are Parsonsia-specific macrocyclic pyrrolizidine alkaloids including parsonsianine, parsonsianidine, and 17-methylparsonsianidine. Parsonine, another P. laevigata pyrrolizidine component with a keto-dihydropyrrolizine moiety that is closely related in structure to male pheromones of the butterfly, and several nonhost pyrrolizidine alkaloids were entirely inactive. We interpret these data as strong evidence for an ancestral association through herbivory between danaid butterflies and pyrrolizidine alkaloids.     

Magnetic specific heat and magnetoresistance of URhSi

Specific heat of a single crystalline URhSi was measured by a relaxation method in a temperature range 0.3–25 K in magnetic fields up to 8 T applied along the two of the principal axes. The low-temperature specific heat exponentially decays with magnetic field. The decay is much faster in fields applied along the easy magnetization direction (the c-axis) than for the hard axis (the a-axis) case. A strong upturn in c_p/T versus T below 0.6 K that disappears with application of magnetic field is observed suggesting possible magnetic or superconducting phase transition at lower temperatures. The electrical resistivity in the vicinity of the ferromagnetic phase temperature is found to be reduced by more than 50% upon application of magnetic field of 8 T applied along the c-axis. URhSi represent an itinerant ferromagnetic system with influence of spin fluctuations.     

A novel method for suppressing silicidation of tungsten catalyzer during silane decomposition in Cat-CVD

Growth of tungsten silicide (WSi_x) on tungsten (W) catalyzer surface is investigated by monitoring resistance change of heated W wire in silane (SiH₄) atmosphere. To know a method suppressing the silicide formation, the effect of carbonization of W surface is also studied. Resistance change of heated W, observed in initial stage just after SiH₄ introduction, is brought about increase in power consumption due to decomposition of SiH₄. This power consumption can be drastically reduced when W surface is carbonized. Therefore, carbonization of tungsten surface is effective to stabilize the catalyzer temperature and to suppress W silicidation.     

A robot language for parts handling based on hierarchical structure of verbs

An operation-level robot language for parts handling has been developed, in which stress is laid on the systematization of the hierarchical structure of verbs (and verb phases) and the realization of and interpreter of the language for controlling a robot arm. In this research, the circumstances are defined as a robot arm, shelves (work benches), boxes and objects on a floor. In the user's programming, eighteen verbs can be utilized: [Level 3] place on, stack on, lift down, carry, direct to, put in, put out, push and draw; [Level 2] have, lift and put; [Level 1] go, raise, lower, seize (grip), detach and turn. In the system, a verb module is reduced to a sequence of the verb modules immediately one level below it, and a series of control commands to a robot controller is automatically generated.     

Position control for a linear slider with twin linear drives

In this paper, position control of a linear slider with twin linear drives is considered. Recently, for high‐speed response, several linear motors have been used for linear slider systems. In such a linear slider, if the linear drives are controlled individually, their position responses may undergo vibrational disturbance by interaction with the output of the motors. To control this vibration, this paper presents a dynamic model of a linear slider system which consists of two motion systems decoupled by coordinate transformation, and proposes a feedback controller which is designed for these two decoupled systems. The effectiveness of the proposed method is confirmed by experiments. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 147(4): 68–76, 2004; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10291     

Polymer-derived β-SiAlON:Eu2+ phosphors

A series of β-SiAlON:Eu²⁺ phosphors were synthesized from single-source precursors, perhydropolysilazane chemically modified with Al(OCH(CH₃)₂)₃, AlCl₃, and EuCl₂. The single-source precursors were converted to β-SiAlON:Eu²⁺ phosphors by pyrolysis under flowing N₂ or NH₃ at 1000°C, followed by heat treatment at 1800°C under an N₂ gas pressure at 980 kPa. By varying the molar ratio of the chemical modifiers, β-SiAlON:Eu²⁺ with the compositions close to the theoretical ones expressed as Si_6−zAl_zO_z−2yN_8−z+2y:yEu²⁺ were synthesized, where the z values and Eu²⁺ contents were controlled in the ranges of .44–.78 and .35–1.48 mol%, respectively. The polymer-derived β-SiAlON:Eu²⁺ phosphors exhibited green emission under excitation at 460 nm attributed to the 4f⁷–4f⁶(7f³)5d¹ transition of dopant Eu²⁺. High-angle annular dark-field-scanning transmission microscopy analysis confirmed that the doped-Eu²⁺ existed interstitially within the channels along the c axis of host β-SiAlON. Compared with the conventional powder metallurgy route, the polymer-derived ceramic route in this study offers some advantages in the grain growth of host β-SiAlON and photoluminescence properties in terms of green emission intensity under excitation at 460 nm, and the highest intensity was achieved for the polymer-derived β-SiAlON:Eu²⁺ with z = .64 and .37 mol% Eu²⁺.     

Application of microalgae hydrolysate as a fermentation medium for microbial production of 2-pyrone 4,6-dicarboxylic acid

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