环十二烷空气催化氧化制环十二醇及酮

研究了以偏硼酸为催化剂的环十二烷常压空气氧化制环十二醇、酮的反应规律,采用鼓泡搅拌釜作为反应器,在间歇操作方式下,通过改变通氧速率、搅拌转速、反应温度、催化剂用量,测定了反应液中烷、醇、酮的浓度随反应时间的变化关系,得到了醇、酮选择性与烷转化率的关系,确定了适宜的工艺操作条件。在连续操作方式下,通过改变烷的进料速度,测得了反应产物中烷、醇、酮的浓度随空时的变化关系,并与间歇操作获得的实验结果进行了比较。     

面向中文专利文献的单层并列结构识别

结合条件随机场与伯克利句法分析器对中文专利文献中的单层并列结构进行识别。在经过分词和词性标注的中文专利语料的基础上,分别运用条件随机场和伯克利句法分析器对专利语料中的单层并列结构进行识别,提取两种机器模型相同的和识别结果中满足相应规则的并列结构识别结果。实验结果表明,该方法有效的识别了专利文献中的单层并列结构,取得了73.09%的F值。     

并列结构在依存句法分析中的应用

本文利用中文专利语料库,对中文专利文献中的并列结构进行了分析,主要分析了中文专利文献中并列结构的依存特征。根据中文专利文献中并列结构的依存特征,总结出并列结构依存处理规则,并根据并列结构依存处理规则对中文专利文献的依存分析结果进行了规则后处理,规则处理后提高了识别的准确率。     

石英陶瓷注凝成型影响因素的研究

介绍了熔融石英陶瓷的注凝成型机理及其工艺过程,分析讨论了影响熔融石英陶瓷注凝成型的主要因素,通过研究确定了合理的制备工艺参数.     

Identification of organochlorines and organobromines in coals

Four Chinese bituminous coals were extracted with CS₂, n-hexane, benzene, methanol, acetone, tetrahydrofuran (THF) and THF/methanol (1: 3 vol/vol) mixed solvent sequentially. The resulting 28 extracts were analyzed with GC/MS. Six organochlorines (OCs) and two organobromines (OBs) were identified in eight extracts from the coals. Our experiments provide, for the first time, the information on the molecular structure of OCs and OBs in coals.     

浅析城市的水资源保护与节水

本文简述了我国城市水资源的现状。辩证分析了城市水资源保护的重要性，提出了在城市发展中节水与养水所采取的措施。     

用CCD摄像法测量下喷环流反应器内的气泡行为

本文开发了一种集高速视频分析系统和计算机数字图像处理技术于一体的具有普适性的动态高速ＣＣＤ摄像系统，并利用该系统测定了两相三维下喷环流反应气内的环境气泡行为，考察了不同喷咀和操作条件对气泡行为及平均传质比表面积的影响。     

Synthesis and properties of an alkoxysilane dye containing three electronic donor groups for nonlinear optical applications

In order to obtain an efficient hybrid inorganic–organic nonlinear optical (NLO) materials, an azo-dye containing three electronic donor groups 2,5-dimethyl-4-(4′-nitrophenylazo)phenol (DMNPAP) was synthesized and reacted with 3-isocyanatopropyl triethoxysilane (ICTES) to give an alkoxysilane dye (ICTES–DMNPAP). Molecular structural characterizations for DMNPAP and ICTES–DMNPAP were investigated by elemental analysis, ¹H NMR, FTIR, UV–visible spectra and differential scanning calorimetry (DSC). The alkoxysilane dye could be hydrolyzed and polymerized in the presence of water, and then transparent hybrid films could be fabricated by spin coating on the indium–tin-oxide (ITO) glass substrates. Compared with the dye 4-nitro-4′-hydroxy-azobenzene (NHA) containing only one hydroxyl as donor group, DMNPAP exhibited larger β_CTμ_g value measured by solvatochromic method, and second harmonic generation (SHG) measurement of the hybrid films was in agreement with the result.     

有机硫加氢(HDS)催化剂的预硫化

预硫化是HDS、HDN过程中决定催化剂活性的最重要环节。在分析催化剂硫化反应原理、硫化条件、硫化与还原的关系等基础上进一步指出了在工业过程中预硫化的一些原则。