Design and fabrication of miniature compliant hinges for multi-material compliant mechanisms

Multi-material molding (MMM) enables the creation of multi-material mechanisms that combine compliant hinges, serving as revolute joints, and rigid links in a single part. There are three important challenges in creating these structures: (1) bonding between the materials used, (2) the ability of the hinge to transfer the required loads in the mechanism while allowing for the prescribed degree(s) of freedom, and (3) incorporating the process-specific requirements in the design stage. This paper presents the approach for design and fabrication of miniature compliant hinges in multi-material compliant mechanisms. The methodology described in this paper allows for the concurrent design of the part and the manufacturing process. For the first challenge, mechanical interlocking strategies are presented. For the second challenge, the development of a simulation-based optimization model of the hinge is presented, involving functional and manufacturing constrains. For the third challenge, the development of hinge positioning features and gate positioning constraints is presented. The developed MMM process is described, along with the main constraints and performance measures. This includes the process sequence, the mold cavity design, gate selection, and runner system development. A case study is presented to demonstrate the feasibility of creating multi-material mechanisms with miniature hinges serving as joints through MMM process. The approach described in this paper was utilized to design a drive mechanism for a flapping wing micro air vehicle. The methods described in this paper are applicable to any lightweight, load-bearing compliant mechanism manufactured using multi-material injection molding.     

Redox doping behaviour of poly(3,4-ethylenedithiothiophene) - The counterion effect

Poly(3,4-ethylenedithiothiophene) - PEDTT, an alkylene sulphur derivative of PEDOT, presents itself as an interesting polymer with a number of disparate redox and chromic properties compared to its close analogue - PEDOT. In this study we present the results of an investigation into the electrochemical doping process of PEDTT, using four different electrolyte solutions, differing in anion content of the chosen salt. The results show that the anion identity plays a key role in the redox reactions accompanying these processes in what could be interpreted as anion ionochromism. In situ UV-Vis spectroelectrochemical experiments reveal an intriguing double electrochromic transition of PEDTT films during their oxidative doping, going from golden-yellow through green to pomegranate - a quality not so common within the family of electroactive conjugated polymers. The evolution of each UV-Vis spectrum over a potential range indicates that different redox states of the polymer are responsible for the chromatic changes. In the reduction half-cycle, the dedoping process of PEDTT appears to follow a path dissimilar to the p-doping one, featuring only one, direct electrochromic transition of the film’s colour, bypassing the green state, and a distinct two-step bleaching process of doping-induced charge carrier bands. The observed electrochemical and spectral phenomena have been accredited to the specific redox behaviour of doping-induced radical cation and cationic defect states interacting with the dithioalkylene sulphur atom.     

Effect of the design parameters on the in vitro wear performance of total shoulder arthroplasties

The loosening of the glenoid component is the main reason for the failure of a total shoulder arthoplasty. It may be caused either by high tensile stresses or by osteolysis of the surrounding bone in response to the presence of particle debris. This failure might be associated with the wear of the implant as occurs with replacement hip and knee joints.The paper reports the findings of a study of the in vitro performance of the currently used total shoulder prostheses to determine the effects of implant geometry on the wear of the polyethylene components and the friction conditions operating within the shoulder prosthesis.The wear performance of the implants was evaluated using a self-developed tribotester, simulating the physiological conditions of a shoulder joint. This study revealed that significantly different wear occurred with conforming and non-conforming articulation and revealed the influence of the thickness of the polyethylene glenoid on the wear and friction occurring in the joint. In this preliminary study significant wear of the polyethylene glenoid component occurred, estimated to be up to 19 mm³/year, which is similar to that found in retrieved implants. The conforming implants demonstrated significantly greater wear than the non-conforming implants (p < 0.05). A significantly lower friction factor, about 0.05 ± 0.01 (p < 0.05), was obtained for the less conforming implants.     

Monolithic ZnTe-based pillar microcavities containing CdTe quantum dots

Micropillars of different diameters have been prepared by focused ion beam milling out of a planar ZnTe-based cavity. The monolithic epitaxial structure, deposited on a GaAs substrate, contains CdTe quantum dots embedded in a ZnTe λ-cavity delimited by two distributed Bragg reflectors (DBRs). The high refractive index material of the DBR structure is ZnTe, while for the low index material a short-period triple MgTe/ZnTe/MgSe superlattice is used. The CdTe quantum dots are formed by a novel Zn-induced formation process and are investigated by scanning transmission electron microscopy. Micro-photoluminescence measurements show discrete optical modes for the pillars, in good agreement with calculations based on a vectorial transfer matrix method. The measured quality factor reaches a value of 3100.     

Ortho‐ vs Bay‐Functionalization: A Comparative Study on Tetracyano‐Terrylenediimides

In this paper n‐type semiconductors synthesized via selective fourfold cyanation of the ortho‐ and bay‐positions (2,5,10,13‐ and 1,6,9,14‐positions respectively) of teyrrylenediimides are reported. A detailed study about the impact of the diverse functionalization topologies on the optoelectronic properties, self‐organization from solution, solid‐state packing, and charge carrier transport in field‐effect transistors is presented. The ortho‐substitution preserves the planarity of the core and favors high order in solution processed films. However, the strong intermolecular interactions lead to a microstructure with large aggregates and pronounced grain boundaries which lower the charge carrier transport in transistors. In contrast, the well‐soluble bay‐functionalized terrylenediimide forms only disordered films which surprisingly result in n‐type average mobilities of 0.17 cm²/Vs after drop‐casting with similar values in air. Processing by solvent vapor diffusion enhances the transport to 0.65 cm²/Vs by slight improvement of the order and surface arrangement of the molecules. This mobility is comparable to highest n‐type conductivities measured for solution processed PDI derivatives demonstrating the high potential of TDI‐based semiconductors.     

An Overlooked Hepcidin–Cadmium Connection

Hepcidin (DTHFPICIFCCGCCHRSKCGMCCKT), an iron-regulatory hormone, is a 25-amino-acid peptide with four intramolecular disulfide bonds circulating in blood. Its hormonal activity is indirect and consists of marking ferroportin-1 (an iron exporter) for degradation. Hepcidin biosynthesis involves the N-terminally extended precursors prepro-hepcidin and pro-hepcidin, processed by peptidases to the final 25-peptide form. A sequence-specific formation of disulfide bonds and export of the oxidized peptide to the bloodstream follows. In this study we considered the fact that prior to export, reduced hepcidin may function as an octathiol ligand bearing some resemblance to the N-terminal part of the α-domain of metallothioneins. Consequently, we studied its ability to bind Zn(II) and Cd(II) ions using the original peptide and a model for prohepcidin extended N-terminally with a stretch of five arginine residues (5R-hepcidin). We found that both form equivalent mononuclear complexes with two Zn(II) or Cd(II) ions saturating all eight Cys residues. The average affinity at pH 7.4, determined from pH-metric spectroscopic titrations, is 10^10.1 M⁻¹ for Zn(II) ions; Cd(II) ions bind with affinities of 10^15.2 M⁻¹ and 10^14.1 M⁻¹. Using mass spectrometry and 5R-hepcidin we demonstrated that hepcidin can compete for Cd(II) ions with metallothionein-2, a cellular cadmium target. This study enabled us to conclude that hepcidin binds Zn(II) and Cd(II) sufficiently strongly to participate in zinc physiology and cadmium toxicity under intracellular conditions.     

Progressive Virtual Beam Lights

A recent technique that forms virtual ray lights (VRLs) from path segments in media, reduces the artifacts common to VPL approaches in participating media, however, distracting singularities still remain. We present Virtual Beam Lights (VBLs), a progressive many‐lights algorithm for rendering complex indirect transport paths in, from, and to media. VBLs are efficient and can handle heterogeneous media, anisotropic scattering, and moderately glossy surfaces, while provably converging to ground truth. We inflate ray lights into beam lights with finite thicknesses to eliminate the remaining singularities. Furthermore, we devise several practical schemes for importance sampling the various transport contributions between camera rays, light rays, and surface points. VBLs produce artifact‐free images faster than VRLs, especially when glossy surfaces and/or anisotropic phase functions are present. Lastly, we employ a progressive thickness reduction scheme for VBLs in order to render results that converge to ground truth.     

Werner-type metal complexes of potato starch

It was shown that potato starch formed Werner‐type complexes. In these complexes a metal atom is ligated by the lone electron pairs of hydroxyl groups from d ‐glucose units and phosphate groups in starch. Acetate, chloride and nitrate were counter‐ions to the transition metal atoms. The metal cations bound preferentially to the phosphoric acid moiety of amylopectin, but secondarily they were co‐ordinated by the hydroxyl groups of the d ‐glucose units. This resulted in the formation of clathrate cages in which a significant number of the water molecules were trapped. Such structures were able to co‐ordinate further metal cations. Only Mn(II) and Co(II) ions, with acetate counter‐ions, neither formed clathrate cages nor were co‐ordinated by the hydroxyl groups of the d ‐glucose of starch.     

Studies of oxygen uptake on O2 scavengers ­prepared from different iron‐containing ­parent substances

Temperature‐programmed reduction (TPR) measurements were performed for iron oxalates, iron(III) hydroxide (both pure and with additives) and iron(II, III) oxide. On the ground of TPR curves, reduction temperatures of the iron‐containing parent substances were chosen followed by oxygen uptake determination. Comparison of oxygen uptakes points to the use of Fe(OH)₃ and Fe₃O₄ as more advantageous than that of iron oxalates. Co‐precipitation from a mixed solution of iron and manganese salts results in a product which is more resistant to particle agglomeration at elevated temperatures than that obtained by­precipitation from solution of iron salt alone. Copyright © 2002 John­Wiley & Sons, Ltd.     

Study of the thermal stability of phases in the Mg-Al system

A part of the Al-Mg phase diagram was studied in the range of composition between 48 and 61 at.% Al by DSC and SEM/EDS methods. The temperature ranges of stability of the β, γ, and ɛ phases were considered. It was found that the congruent melting temperature of the β phase was 450±1 °C. The Al content in that phase was determined to be 61±1 at.% Al at 420 °C. The upper temperature limit of the stability of the ɛ phase was established to be 427±1 °C. The Al content changed from 54 at.% at 390 °C to 56 at.% at 420 °C. The lower temperature limit of the ɛ phase formation was not determined, as a result of a slow ɛ=β+γ reaction. The hypothetical λ or ζ phases were not found, but it was observed that decomposition of oxides might produce extra thermal effects.