Scratch and wear resistance of polyamide 6 reinforced with multiwall carbon nanotubes

While carbon nanotubes have been used for a variety of purposes, it was not known whether they can improve tribological properties of polymers. Polyamide 6 (PA6) has been reinforced with 0.2, 0.5 and 1.0 wt% of multiwall carbon nanotubes (MWCNTs) by melt mixing process and characterized by scanning electron microscopy (SEM), transmission electron microscopy, thermogravimetric analysis (TGA), scratching, sliding wear and tensile testing. TGA results for the air atmosphere show that MWCNTs shift the onset of thermal degradation to higher temperatures. Sliding wear tests show that the penetration depth decreases as the concentration of carbon nanotubes increases. However, the viscoelastic healing is hampered by the MWCNTs presence and the residual depths increase at the same time. Narrower scratch groove widths are seen in SEM for composites with MWCNTs, and scratch hardness increases. Tensile tests show an increase of 27% in the Young modulus value upon addition of 1.0% of MWCNTs. The stress at yield is also higher for the nanocomposites.     

Kinetics of extracted bioactive components from mushrooms in artificial digestive juices

This article presents a study on fruiting bodies of Boletus badius, Boletus edulis, Cantharellus cibarius, Lactarius deliciosus, Leccinum scabrum, Suillus bovinus, Suillus luteus, Pleurotus ostreatus, Tricholoma equestre, Armillaria mellea, Agaricus bisporus, and Auricularia polytricha. The amounts of their health-promoting bioelements and physiologically significant indole and phenolic compounds were determined. The significance of edible mushrooms in the human diet and in disease prevention were also established. The high-performance liquid chromatography was used to assess the contents of indole compounds and phenolic acids. The atomic absorption spectroscopy was applied to determine bioelements. In all samples, the content of 5-hydroxy-L-tryptophan was studied. The highest extraction amount of serotonin was found for P. ostreatus species. Phenolic compounds were determined in the conditions described in the present study for the first time. Additionally, protocatechuic, p-hydroxybenzoic, syringic, and gallic acids were determined.     

New or lesser known cultivar selection as a tool for sensory and nutritional value enhancement of osmo-convectively dried sour cherries

Taking into consideration the economic importance of sour cherry growing in Europe as well as the arising perspective of novel sour cherry product development, an investigation outlining the processing usefulness of some promising sour cherry cultivars that could lead to a better final product quality was undertaken. Nine new or lesser popular cultivars of sour cherries were compared to ‘English Morello’ with particular consideration given to processing suitability for osmo-convective drying. The quality of raw material was characterized taking into account fruit size, soluble solids content, acidity and pro-health properties. To assess the quality trait stability of individual cultivars, standard deviations were calculated. As a measure of ascertaining the fruits' suitability for drying, the sensory properties of osmo-dried products produced by the examined cultivars were considered. The gathered data demonstrates high seasonal variations in quality traits of the most investigated cultivars, which could well restrict their processing usefulness, especially for osmo-drying, as this product was found highly sensitive to fluctuation of raw material uniformity. Among the tested cultivars ‘Nefris’ emerged the most suitable for processing purposes. Fruits of this cultivar gave high quality dried product of repeatable sensory attributes characterized by significantly better pro-health properties than that of ‘English Morello’.     

The emerging principles of mammalian prion propagation and transmissibility barriers: Insight from studies in vitro

Self-perpetuating conformational conversion of the cellular prion protein PrP(C) into the beta-sheet-rich "scrapie" conformer (PrP(Sc)) is believed to be the central molecular event in pathogenesis of a group of diseases known as transmissible spongiform encephalopathies. Recent advances provide growing support for the notion that a misfolded protein alone might act as an infectious agent. Furthermore, findings regarding the mechanism of prion protein structural rearrangement, the role of folding intermediates in conformational conversion, and "conformational adaptability" in the propagation of prion amyloids in vitro yield molecular-level insight into such phenomena as inherited prion diseases, prion transmission barriers, and prion strains.     

A granular description of ECG signals

In this paper, we develop a general framework of a granular representation of ECG signals. The crux of the approach lies in the development and ongoing processing realized in the setting of information granules-fuzzy sets. They serve as basic conceptual and semantically meaningful entities using which we describe signals and build their models (such as various predictive schemes or classifiers). A comprehensive two-phase scheme of the design of the information granules is proposed and described. At the first phase, we discuss the temporal granulation through a series of temporal windows (granular windows) and an aggregation of the values of signal by means of fuzzy sets. To address this issue, offered is a detailed method of building a fuzzy set based on numeric data and a certain optimization criterion that strikes a balance between the highest experimental relevance of the fuzzy set supported by numeric data and its substantial specificity. At the next phase of the granular design, a collection of information granules is further summarized with the use of fuzzy clustering (Fuzzy C-Means). The resulting prototypes (centroids) formed by this grouping process serve as elements of the granular vocabulary. We discuss ways of using these vocabularies in the knowledge-based representation, modeling, and classification of ECG beats.     

Effects of glass fibers and polypropylene/glass fiber hybrid fibers on the kinetics and mechanical properties of epoxy composites

Curing reactions of diglycidyl ether of bisphenol F (DGEBP‐F) and pre‐catalyzed methyltetrahydrophthalic anhydride (MTHPA) with benzyl triethyl ammonium chloride (BTEAC) were studied and effects of glass fibers evaluated. The influence on the kinetics of glass fibers and a hybrid blend of maleated polypropylene + glass fibers is studied. Isothermal and dynamic kinetic parameters are determined by differential scanning calorimetry (DSC). Applicability of the autocatalytic model is investigated. The model serves well in the range of degrees of conversion between 25 and 80%. At high conversion rates the diffusion control becomes apparent. Glass fibers accelerate the curing, shortening the time needed to reach the maximum reaction rate; this is reflected in lower activation energies for curing in comparison to the neat resin. The effects observed can be explained by a reaction between the amine group present on the fiber surfaces and the epoxy glycidyl groups. The result of both isothermal and non‐isothermal curing of resin + glass fibers commingled with polypropylene are close to those for the neat resin. The reinforcement increases the elastic modulus 12 times, the tensile strength 2 times, and the impact strength 285 times. The glass fibers + commingled polypropylene reinforcement provides comparable mechanical properties as glass fibers alone when normalized with respected to the density fraction of the fibers.     

An Association between Diet and MC4R Genetic Polymorphism,in Relation to Obesity and Metabolic Parameters—A Cross Sectional Population-Based Study

The melanocortin-4 receptor (MC4R) gene harbours one of the strongest susceptibility loci for obesity and obesity-related metabolic consequences. We analysed whether dietary factors may attenuate the associations between MC4R genotypes and obesity and metabolic parameters. In 819 participants genotyped for common MC4R polymorphisms (rs17782313, rs12970134, rs633265, and rs135034), the anthropometric measurements, body fat content and distribution (visceral and subcutaneous adipose tissue, VAT and SAT, respectively), and blood glucose, insulin, total-, LDL-, HDL-cholesterol, triglycerides concentrations, and daily macronutrient intake were assessed. ANOVA or Kruskal–Wallis tests were used, and multivariate linear regression models were developed. We observed that the CC genotype carriers (rs17782313) presented higher VAT, VAT/SAT ratio, fasting blood glucose and triglyceride concentrations when they were stratified to the upper quantiles of protein intake. An increase in energy derived from proteins was associated with higher BMI (Est. 5.74, R² = 0.12), body fat content (Est. 8.44, R² = 0.82), VAT (Est. 32.59, R² = 0.06), and VAT/SAT ratio (Est. 0.96, R² = 0.05). The AA genotype carriers (rs12970134) presented higher BMI, body fat, SAT and VAT, fasting blood glucose, triglycerides and total cholesterol concentrations. An increase in energy derived from proteins by AA carriers was associated with higher VAT (Est.19.95, R² = 0.06) and VAT/SAT ratio (Est. 0.64, R² = 0.05). Our findings suggest that associations of the common MC4R SNPs with obesity and its metabolic complications may be dependent on the daily dietary intake, which may open new areas for developing personalised diets for preventing and treating obesity and obesity-related comorbidities.     

The effects of feeding conjugated linoleic acid (CLA) on rat growth performance,serum lipoproteins and subsequent lipid composition of selected rat tissues

Four groups of 12 albino rats (six males and six females), at 4 weeks of age, were fed for 60 days a semi‐synthetic diet containing graded amounts of conjugated linoleic acid (CLA; 0.0, 0.5, 1.0 and 1.5%) to determine its effect on growth performance and serum lipoprotein profiles and its incorporation into abdominal and muscle lipids. Rats fed CLA responded by significantly improved body mass gains; however, this effect was observed only with the 1.0% CLA‐supplemented diet. It was also true for feed conversion efficiency. The changes in serum total cholesterol (TC) and HDL cholesterol concentrations were insignificant and showed an opposite pattern. However, the resulting HDL cholesterol/TC ratio was significantly (P ≤ 0.01) increased. At the same time, serum triacylglycerol (TAG) concentrations were significantly (P ≤ 0.01) elevated, thus counteracting the potential antiatherogenicity of the improved HDL cholesterol/TC ratio. Feeding CLA to rats resulted in its substantial incorporation into both abdominal and muscle lipids. Generally, tissue lipids were enriched with CLA at the expense of long‐chain polyunsaturated fatty acids, eg linoleate and arachidonate. This effect is likely to correspond with reduction of arachidonate‐derived eicosanoid synthesis. These data together suggest that CLA has a potent effect on lipid transport and metabolism in rats. Also, they confirm the potential of nutritional methods to provide CLA‐enriched functional animal products, especially meat, for human consumption. © 2000 Society of Chemical Industry     

Effects of γ radiation on fiber‐reinforced polymer concrete

Composites were made from 30% unsaturated polyester resin + 70% calcium bentonite and marble as aggregates, as well as 0.3 and 0.4 vol% of nylon fibers. The fiber‐containing polymer concretes (PCs) were subjected to 5, 10, 50, and 100 kGy applied radiation doses. The compressive strength values depend on both the fiber concentration and the irradiation dose applied. Moreover, the polyester‐based PCs containing two mineral aggregates, calcium carbonate and marble, have lower compressive strength values than those reported earlier for PCs containing only either silica sand or CaCO₃. However, significant improvement of the compressive strain and the compression modulus of elasticity are achieved when nylon fibers are added. Both these properties go symbatically with the radiation dose. Mechanical characteristics can be related to the morphological features observed by scanning electron microscopy. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers     

Clustering revealed in high‐resolution simulations and visualization of multi‐resolution features in fluid–particle models

Simulating natural phenomena at greater accuracy results in an explosive growth of data. Large‐scale simulations with particles currently involve ensembles consisting of between 10⁶ and 10⁹ particles, which cover 10⁵–10⁶ time steps. Thus, the data files produced in a single run can reach from tens of gigabytes to hundreds of terabytes. This data bank allows one to reconstruct the spatio‐temporal evolution of both the particle system as a whole and each particle separately. Realistically, for one to look at a large data set at full resolution at all times is not possible and, in fact, not necessary. We have developed an agglomerative clustering technique, based on the concept of a mutual nearest neighbor (MNN). This procedure can be easily adapted for efficient visualization of extremely large data sets from simulations with particles at various resolution levels. We present the parallel algorithm for MNN clustering and its timings on the IBM SP and SGI/Origin 3800 multiprocessor systems for up to 16 million fluid particles. The high efficiency obtained is mainly due to the similarity in the algorithmic structure of MNN clustering and particle methods. We show various examples drawn from MNN applications in visualization and analysis of the order of a few hundred gigabytes of data from discrete particle simulations, using dissipative particle dynamics and fluid particle models. Because data clustering is the first step in this concept extraction procedure, we may employ this clustering procedure to many other fields such as data mining, earthquake events and stellar populations in nebula clusters. Copyright © 2003 John Wiley & Sons, Ltd.