Origin of visible photoluminescence from porous silicon as studied by Raman spectroscopy

In this paper we discuss the different models proposed to explain the visible luminescence in porous silicon (PS). We review our recent photoluminescence and Raman studies on PS as a function of different preparation conditions and isochronal thermal annealing. Our results can be explained by a hybrid model which incorporates both nanostructures for quantum confinement and silicon complexes (such as SiH _x and siloxene) and defects at Si/SiO₂ interfaces as luminescent centres.     

On joint transmitter and receiver optimization formultiple-input-multiple-output (MIMO) transmission systems

The problem of joint transmitter and receiver optimization for MIMO systems under the mean-squared error (MSE) criterion is revisited. We address the general problem of N (number of users) ≠M (number of channel inputs) ≠P (number of channel outputs) when the system is Nyquist bandlimited and obtain analytical solutions for the optimal transmit-receive pair. Next, we demonstrate how the above result is directly applicable to the problem where the system has excess bandwidth, thereby generalizing the results of Salz (1985). In conclusion, several numerical examples are included to demonstrate the performance gains obtainable with jointly optimized MIMO systems vis-a-vis systems based only on receiver optimization     

Classification of life distributions in multivariate models

In reliability theory, lifetimes of systems and components are frequently studied through univariate concepts of ageing. By considering suitable multivariate generalizations of the univariate ageing properties, some multivariate ageing classes of life distributions are defined. Properties of these classes with their equivalent definitions and chain of implications are presented along with a few characterizing properties. These results are useful for obtaining reliability bounds (when component lives are independent) at the early stage of product design. Also for model selection, characterization results can be important. Moreover, the underlying mathematical treatment is univariate when viewed through conditional distributions     

Subspace-based blind channel estimation for OFDM by exploiting virtual carriers

Reliable channel estimation is indispensable for orthogonal frequency-division multiplexing (OFDM) systems employing coherent detection and adaptive loading in order to achieve high data rate communications. Several options exist in practical OFDM systems-including training symbols, cyclic prefix, virtual carriers, pilot tones, and receiver diversity-to facilitate channel estimation. In this paper, a subspace blind channel estimation method based on exploiting the presence of virtual carriers is proposed for OFDM systems over a time-dispersive channel. The method can be applied to conventional OFDM systems with cyclic prefix as well as OFDM systems with no cyclic prefix. The reduction/elimination of cyclic prefix thereby provides the OFDM systems the potential to achieve higher channel utilization than most previously reported cyclic prefix based estimators. Sufficient channel identifiability condition is developed as well. Comparison with two other recently reported subspace methods is presented via computer simulations to support the effectiveness of the proposed method.     

Insulin-like growth factor I activates the invasion suppressor function of E-cadherin in MCF-7 human mammary carcinoma cells in vitro

The calcium-dependent cell-cell adhesion molecule E-cadherin has been shown to counteract invasion of epithelial neoplastic cells. Using three monoclonal antibodies, we have demonstrated the presence of E-cadherin at the surface of human MCF-7/6 mammary carcinoma cells by indirect immunofluorescence coupled to flow cytometry and by immunocytochemistry. Nevertheless, MCF-7/6 cells failed to aggregate in a medium containing 1.25 mM CaCl2, and they were invasive after confrontation with embryonic chick heart fragments in organ culture. Treatment of MCF-7/6 cells with 0.5 microgram ml-1 insulin-like growth factor I (IGF-I) led to homotypic aggregation within 5 to 10 min and inhibited invasion in vitro during at least 8 days. The effect of IGF-I on cellular aggregation was insensitive to cycloheximide. However, monoclonal antibodies that interfered with the function of either the IGF-I receptor (alpha IR3) or E-cadherin (HECD-1, MB2) blocked the effect of IGF-I on aggregation. The effects of IGF-I on aggregation and on invasion could be mimicked by 1 microgram ml-1 insulin, but not by 0.5 microgram ml-1 IGF-II. The insulin effects were presumably not mediated by the IGF-I receptor, since they could not be blocked by an antibody against this receptor (alpha IR3). Our results indicate that IGF-I activates the invasion suppressor role of E-cadherin in MCF-7/6 cells.     

Studies on the synthesis of SAPO-5

Silicoaluminophosphate (SAPO-5) molecular sieves have been synthesised from reaction mixtures having a molar composition of: 0.7–1.0 Al₂O₃:0.7–1.0 P₂O₅:0.01–2.0 SiO₂:xR:40 H₂O (where R = (C₂H₃)₃N or (C₂H₃)₄NOH and x = 1.5–2.5 for (C₂H₅)⁵N and 0.5 for (C₂H₅)₄NOH, at 473 K using various sources of alumina and silica. The effects of (i) varying the crystallinity of the alumina source (boehmite) and (ii) the use of different silica sources such as freshly prepared silica either from sodium silicate or paddy husk extract, silica gel from commercial water-glass, and tetraethyl orthosilicate have been studied. The crystallinity of boehmite has been found to have a strong effect on its reactivity towards the formation of SAPO-5. The activity of boehmite for SAPO-5 formation increased with a decrease in its crystallinity (or with increase in its moisture content). Any silica source devoid of sodium ions could be employed for the synthesis of SAPO-5. The process of crystallisation started as early as within 1.5 h of reaction and incorporation of silicon into the AlPO₄ framework has been noted at this stage. Formation of some tridymite phase as impurity has been observed under conditions such as (i) SiO₂ concentration > 1.7 mole and (ii) x > 2.0 when R = (C²H₅)₃N.     

A distributed approach for access and visibility task with a manikin and a robot in a virtual reality environment

This paper presents a new method, based on a multi-agent system and on a digital mock-up technology, to assess an efficient path planner for a manikin or a robot for an access and visibility task taking into account ergonomic constraints or joint and mechanical limits. In order to solve this problem, the human operator is integrated in the process optimization to contribute to a global perception of the environment. This operator cooperates, in real time, with several automatic local elementary agents. The result of this work validates solutions through the digital mock-up; it can be applied to simulate maintainability and mountability tasks.     

High‐Tg Carbazole Derivatives as Blue‐Emitting Hole‐Transporting Materials for Electroluminescent Devices

A series of dicarbazolyl derivatives bridged by various aromatic spacers and decorated with peripheral diarylamines were synthesized using Ullmann and Pd‐catalyzed C–N coupling procedures. These derivatives emit blue light in solution. In general, they possess high glass‐transition temperatures (T_g > 125 °C) which vary with the bridging segment and methyl substitution on the peripheral amine. Double‐layer organic light‐emitting devices were successfully fabricated using these molecules as hole‐transporting and emitting materials. Devices of the configuration ITO/HTL/TPBI/Mg:Ag (ITO: indium tin oxide; HTL: hole‐transporting layer; TPBI: 1,3,5‐tris(N‐phenylbenzimidazol‐2‐yl)benzene) display blue emission from the HTL layer. The EL spectra of these devices appear slightly distorted due to the exciplex formation at the interfaces. However, for the devices of the configuration ITO/HTL/Alq₃/Mg:Ag (Alq₃ = tris(8‐hydroxyquinoline)aluminum) a bright green light from the Alq₃ layer was observed. This clearly demonstrates the facile hole‐transporting property of the materials described here.