Uptake of Tritiated Liquids by Individual Breakfast Cereal Flakes

ABSTRACT: Surface liquid adhesion (SLA) and liquid absorption (LA) of tritiated liquids, including water and skim, low-fat, whole, and fat-enriched milks, by cornflakes (CF) and frosted flakes (FF) were determined by scintillation counting using water-[³H] at 0.5 μCi/mL. SLA or the liquid adhering to individual flakes after a short immersion period was the same for CF and FF in the case of water (approximately 0.011 μL mm⁻² of flake) but were always higher for CF than for FF and increased as the fat content in milks augmented. LA of individual flakes, followed for 300 s of soaking, increased with time and was always higher for CF than for FF (for the same liquid), however, data did not follow a regular pattern. Flakes showed quite compact outer surfaces and an internal porous matrix composed of air cells of various sizes separated by dense walls of different thicknesses. This heterogeneous microstructure of individual flakes may be the cause of the lack of a simple kinetics during the soaking process. Previous results obtained by soaking a mass of flakes overestimated the uptake of fluid by individual because they included the liquid occluded between the flakes.     

CEA and AREVA R&D on HTR fuel fabrication and presentation of the CAPRI experimental manufacturing line

In the framework of the French V/HTR fuel development and qualification program, the Commissariat à l’Energie Atomique (CEA) and AREVA are conducting R&D projects covering the mastering of UO₂ coated particle and fuel compact fabrication technology. To fulfill this task, a review of past knowledge, of existing technologies and a preliminary laboratory-scale work program have been conducted with the aim of retrieving the know-how on HTR coated particle and compact manufacture:

• The different stages of UO₂ kernel fabrication GSP process have been reviewed, reproduced and improved.

• The experimental conditions for the chemical vapor deposition of coatings have been defined on dummy kernels and development of innovative characterization methods has been carried out.

• Former CERCA compacting process has been reviewed and updated.

In parallel, an experimental manufacturing line for coated particles, named GAIA, and a compacting line based on former CERCA compacting experience have been designed, constructed and are in operation since early 2005 at CEA Cadarache and CERCA Romans, respectively. These two facilities constitute the CAPRI line (CEA and AREVA PRoduction Integrated line).The major objectives of the CAPRI line are:

• to recover and validate past knowledge,

• to produce representative HTR TRISO fuel meeting industrial standards,

• to permit the optimization of reference fabrication processes for kernels and coatings defined previously at a laboratory-scale and the investigation of alternative and innovative fuel design (UCO kernel, ZrC coating),

• to test alternative compact process options and

• to fabricate and characterize fuel required for irradiation and qualification purpose.

This paper presents the status of progress of R&D conducted on HTR fuel particles and compact manufacture by early 2005 and the potential of the laboratory-scale HTR fuel CAPRI line.     

Satellite-derived parameters for biological modelling in coastal waters: Illustration over the eastern continental shelf of the Bay of Biscay

In biological modelling of the coastal phytoplankton dynamics, the light attenuation coefficient is often expressed as a function of the concentrations of chlorophyll and mineral suspended particulate matter (SPM). In order to estimate the relationship between these parameters over the continental shelf of the northern Bay of Biscay, a set of in situ data has been gathered for the period 1998-2003 when SeaWiFS imagery is available. These data comprise surface measurements of the concentrations of total SPM, chlorophyll, and irradiance profiles from which is derived the attenuation coefficient of the photosynthetically available radiation, K_PAR. The performance of the IFREMER look-up table used to retrieve the chlorophyll concentration from the SeaWiFS radiance is evaluated on this new set of data. The quality of the estimated chlorophyll concentration is assessed from a comparison of the variograms of the in situ and satellite-derived chlorophyll concentrations. Once the chlorophyll concentration is determined, the non living SPM, which is defined as the SPM not related to the dead or alive endogenous phytoplankton, is estimated from the radiance at 555 nm by inverting a semi-analytic model. This method provides realistic estimations of concentrations of chlorophyll and SPM over the continental shelf all over the year. Finally, a relationship, based on non living SPM and chlorophyll, is proposed to estimate K_PAR on the continental shelf of the Bay of Biscay. The same formula is applied to non living SPM and chlorophyll concentrations, observed in situ or derived from SeaWiFS radiance.     

A Cost-Regular Based Hybrid Column Generation Approach

Constraint Programming (CP) offers a rich modeling language of constraints embedding efficient algorithms to handle complex and heterogeneous combinatorial problems. To solve hard combinatorial optimization problems using CP alone or hybrid CP-ILP decomposition methods, costs also have to be taken into account within the propagation process. Optimization constraints, with their cost-based filtering algorithms, aim to apply inference based on optimality rather than feasibility. This paper introduces a new optimization constraint, cost-regular. Its filtering algorithm is based on the computation of shortest and longest paths in a layered directed graph. The support information is also used to guide the search for solutions. We believe this constraint to be particularly useful in modeling and solving Column Generation subproblems and evaluate its behaviour on complex Employee Timetabling Problems through a flexible CP-based column generation approach. Computational results on generated benchmark sets and on a complex real-world instance are given.A preliminary version of this paper appeared as [7]. This research was supported by the Mathematics of Information Technology and Complex Systems (MITACS) Internship program in association with Omega Optimisation Inc. (CA).     

Tight LP bounds for resource constrained project scheduling

The best lower bound for the Resource Constrained Project Scheduling Problem is currently based on the resolution of several large Linear Programs (Brucker & Knust, EJOR, 107: 272-288, 1998). In this paper, we show that (1) intensive constraint propagation can be used to tighten the initial formulation of the linear programs and (2) we introduce several sets of valid cutting planes. These improvements allow us to close 16 new instances of the PSPLIB with 60 activities and to improve the best known lower bounds of 64 instances.Correspondence to:Philippe BaptisteThe authors would like to thank Peter Brucker and Sigrid Knust for providing their source code as well as Christian Artigues, Jacques Carlier and Philippe Michelon for enlightening discussions on project scheduling.     

Diffusional fluorescence quenching of aromatic hydrocarbons

The quenching of the fluorescence of five aromatic hydrocarbons by three halogenated organics and by molecular oxygen has been measured. Both fluorescence intensity and fluorescence lifetime measurements have been employed to validate results and interpretation; linear Stern-Volmer analyses are shown to apply throughout. The fluorescence quenching rate constant of molecular oxygen for the five aromatic hydrocarbons is essentially equivalent to the diffusion rate constant independent of the fluorophore excitation energy. The halogenated organic-fluorophore rate constants vary by a factor of 965 and are shown to correlate roughly with the energy difference between the quencher and fluorophore excited electronic states in accord with a standard model of quantum two-level mixing. The value of the coupling interaction energy is approximately 2500 cm(-1).     

Current state of the art of biphasic calcium phosphate bioceramics

We have developed 15 years ago, with the collaboration of Lynch, Nery, and LeGeros in the USA, a bioactive concept based on biphasic calcium phosphate (BCP) ceramics. The concept is determined by an optimum balance of the more stable phase of HA and more soluble TCP. The material is soluble and gradually dissolves in the body, seeding new bone formation as it releases calcium and phosphate ions into the biological medium. The bioactive concept based on the dissolution/transformation processes of HA and TCP has been applied to both Bulk, Coating and Injectable Biomaterials. The events at the calcium phosphate (CaP) biomaterial/bone interface represent a dynamic process, including physico-chemical processes, crystal/proteins interactions, cells and tissue colonization, bone remodeling, finally contributing to the unique strength of such interfaces. An important literature and numerous techniques have been used for the evaluation of the fundamental physico chemical and biological performance of BCP concept. This type of artificial bone used from a long time in preclinical and in clinical trial, revealed the efficiency for bone filling, performance for bone reconstruction and efficacy for bone ingrowth at the expense of the micro macroporous BCP bioceramics.     

High pass filter with above IC integrated SrTiO3 high K MIM capacitors

This paper describes realization and characterization of SrTiO₃ (STO) high K MIM capacitors above BiCMOS integrated circuit (IC). These capacitances are connected to IC and are used as coupling capacitors in order to realize a high pass filter. Surface capacitance achieved is 10 nF/mm² with capacitance value of 1.2 nF. The process for STO MIM fabrication does not exceed 400 °C, which is compatible with interconnections. Typical K and dielectric losses values obtained are, respectively 110% and 2%. Yield obtained reaches 83% for capacitors. A functional high pass filter using these STO capacitors was realized in this study. It exhibits a cut-off frequency at 6.5 kHz and a constant gain at higher frequencies of −1.3 dB.     

Optimization of LED‐based light blendings for object presentation

This study looks at the perceived quality of light‐emitting diode (LED)‐based lighting of various colors. The objective was to find out whether LEDs could provide better (i.e., more relevant and acceptable) lighting than that which is obtained with standard halogen or fluorescent sources. The perception of objects was assessed under different lighting schemes. Subjects were invited to add red, cyan and/or amber to white LED‐based light to match the halogen and fluorescence rendering on specific targets: a color chart and a painting. They were also asked to rate the difference between the two, and to express their preference. The results obtained for the perception of LED‐based lighting were quite positive. Color blendings of LED light were found to provide illuminated situations similar to halogens or fluorescent sources. These blendings were well accepted, and indeed often preferred, although the color rendering index (CRI) was always low. This indicates that the CRI as it stands is inadequate to characterize the color rendering of solid‐state light sources, and needs to be updated. LED‐based lighting systems seem to have considerable potential for use in shops and display units, where they may well outperform existing lighting systems. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 310–320, 2009