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61.
Electro-rheological (ER) effect of a blend composed of two liquid crystalline materials with different molecular weights is described in this article. The results indicated that ER effect of the blend was observed at the temperature range where each neat sample did not show ER effect. Furthermore, both storage modulus (G′) and loss modulus (G″) decreased drastically at the temperature range for the blend in dynamic viscoelastic measurements. We show that steady ER effect could be obtained by using a blend made up of two liquid crystalline components, whereas remarkable increment in shear stress was not observed for each component under applied electric field. 相似文献
62.
Shingo Hirano Masaru Yoshinaka Ken Hirota Osamu Yamaguchi 《Journal of the American Ceramic Society》1996,79(1):171-176
In the ZrO2 -Cr2 O3 system, metastable t -ZrO2 solid solutions containing up to 11 mol% Cr2 O3 crystallize at low temperatures from amorphous materials prepared by the hydrazine method. The lattice parameter c decreases linearly from 0.5149 to 0.5077 nm with increased Cr2 O3 content, whereas the lattice parameter a is a constant value ( a = 0.5077 nm) regardless of the starting composition. At higher temperatures, transformation (decomposition) of the solid solutions proceeds in the following way: t (ss)→ t (ss) + m + Cr2 O3 → m + Cr2 O3 . Above 11 mol% Cr2 O3 addition, c-ZrO2 phases are formed in the presence of Cr2 O3 . The t -ZrO2 solid solution powders have been characterized for particle size, shape, and surface area. They consist of very fine particles (15–30 nm) showing thin platelike morphology. Dense ZrO2 (3Y)-Cr2 O3 composite ceramics (∼99.7% of theoretical) with an average grain size of 0.3 μm have been fabricated by hot isostatic pressing for 2 h at 1400°C and 196 MPa. Their fracture toughness increases with increased Cr2 O3 content. The highest K Ic value of 9.5 MPa·;m1/2 is achieved in the composite ceramics containing 10 mol% Cr2 O3 . 相似文献
63.
The complexation between poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) was made by using double the molar quantity of either polymer component at pH 2 where the resulting complex completely precipitates. After the removal of the precipitate, PEO or PAA remaining in the supernatant was subjected to gel permeation chromatography to investigate the change in the molecular weight distribution (MWD) caused by the complexation. No remarkable difference is observed in the MWD curves for PEO[1] (Mw=1.37 × 104) before and after the complexation with PAA[1] (Mw=1.10 × 103) and PAA[2] (Mw=4.16 × 105). However, the MWD curves of PEO[2] (Mw=1.26 × 105) and PAA[2] become shortened and shift to the low molecular weight side after the complexation with PAA[1] or [2] and PEO[2], respectively. This tendency is enhanced by increasing the complexation temperature. From these results, it is indicated that the complexation between PEO and PAA deals with an equilibrium reaction, and the equilibrium constant is dependent on the chain length of both polymer components and also on the complexation temperature. 相似文献
64.
1 INTRODUCTION Since Cu-ZSM-5 was reported as an effective catalyst for the selective catalytic reduction (SCR) of NO by hydrocarbons in the presence of excess oxygen, the SCR of NOx has received much attention as a kind of potential technology for cleaning NOx in various oxygen-rich exhausts of diesel engine, lean burning gasoline engine and gas engine. Although a number of catalysts have been tested, to date, it still seems to be difficult to find a catalyst that is completely suit… 相似文献
65.
Yamauchi Toshihiro Akao Yohei Yoshitani Ryota Nakamura Yuichi Hashimoto Masaki 《International Journal of Information Security》2021,20(4):461-473
International Journal of Information Security - Cyberattacks, especially attacks that exploit operating system vulnerabilities, have been increasing in recent years. In particular, if administrator... 相似文献
66.
Combustion, Explosion, and Shock Waves - Zero-dimensional computations of nanosecond-order ignition using a nanosecond discharge are performed with two constraints. The effects of these constraints... 相似文献
67.
Gabriela Brunosi Medeiros Paulo Ricardo de Souza Karina Miyuki Retamiro Celso Vataru Nakamura Edvani Curti Muniz Elisângela Corradini 《应用聚合物科学杂志》2021,138(36):50898
The production of polymer fibers from the combination of zein and PEO might have great potential in the field of biomaterial. Zein/PEO fibers were obtained in this work through solution electrospinning. An experimental design, 24-1, was used for evaluating the influences of PEO content in the blend, distance from the needle tip to the collector, applied electric voltage and solution flow for average fiber diameter and relative-yield process. Beyond this, the relationship between PEO content in the blend and the fiber properties were evaluated through FTIR, DSC, TG, tensile tests, and cytotoxic tests. The factor that exerts the greatest effect on the average fiber diameter response was the electrical voltage. The increase in PEO content in the blend decreased the thermal stability and increased the degree of the fibers' crystallinity. The mechanical tests showed that fibers with higher elongation were obtained at richer PEO blends. The fibers presented cytocompatible characteristics. 相似文献
68.
Y. Sakamoto T. Hisamoto M. Ura R. Nakamura T.B. Flanagan 《Journal of Alloys and Compounds》1993,200(1-2):141-146
Thermodynamic quantities were determined for the absorption of hydrogen in Pd-5.5at.%Li and Pd-7.2at.%Li alloys, the latter alloy being in the two-phase field of saturated -Pd(Li,s) solid solution and the ordered Pd7Li phase. Data were also determined for the Pd-10.6at.%Li alloy which consists only of the ordered Pd7Li phase. The data were determined from measurements of pressure-composition isotherms at temperatures between 273 K and 463 K and hydrogen pressures up to 1000 Torr. The Pd---Li alloys dissolve considerable amounts of hydrogen and form a more stable hydride phase than Pd despite the lattice contraction which occurs on alloying Pd with Li. The hydrogen solubility in the ordered Pd7Li phase alone is a little smaller than that in the two-phase mixture. The large hydrogen absorption of Pd---Li alloys, which does not depend on the presence of ordered Pd7Li, may be attributed to (i) an attractive H---Li pair interaction, (ii) a decrease in the strain energies necessary for hydrogen occupation of the interstices, because of the similar lattice parameters of the -Pd(Li,s) and ordered Pd7Li phases, and the large compressibility of Pd---Li alloys, and (iii) the valence of 1 of Li in Pd compared with 3 for, for example, Y in Pd. 相似文献
69.
S. Nakashima Y. Ikeda S. Hirose H. Nakamura T. Ito 《Journal of Materials Engineering and Performance》1992,1(2):211-218
Kawasaki Steel Corporation and Kawatetsu Mining Co., Ltd. have developed a new refining process to extract iron oxide from
iron ore to meet the increase in demand for iron oxide for high- grade hard ferrites. This article discusses the quality of
iron oxides and the characteristics of the hard ferrite magnets produced from them. 相似文献
70.
As anthropogenic impacts on riverine ecosystems expand, both aquatic and terrestrial ecosystems are influenced over large spatiotemporal scales. We predicted how riparian bird communities changed in response to long‐term changes in floodplain landscapes such as woodland expansion (i.e. rapid increases in vegetation cover on gravel bars and the progress of vegetation succession due to a decrease in the frequency and magnitude of flood disturbance). To test the hypothesis that woodland expansion after dam construction reduces the abundance of gravel bar‐nesting birds and increases the abundance of forest‐nesting birds, we estimated historical changes between past and present bird abundances using species distribution models across multiple rivers that were either unregulated or regulated by dams. We created past and present vegetation maps from remote sensing images and used habitat quantities as explanatory variables in the species distribution models. As we hypothesized, the estimated abundance of gravel bar‐nesting birds decreased and that of forest‐nesting birds increased because of woodland expansion in some regulated rivers. This suggests that anthropogenic alterations of riverine conditions (e.g. dam construction) can affect terrestrial ecosystems (e.g. riparian bird communities) through changes in floodplains (e.g. woodland expansion). In addition, our findings highlight the efficacy of combining spatial and temporal analyses when examining long‐term ecological dynamics. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献