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41.
Yukito Naitoh Akira Otomo Hideki Miki Isao Aoki Shiyosi Yokoyama 《Thin solid films》2008,516(9):2371-2375
We studied energy transfer between rhodamine B molecules centered in each corn-shaped dendrons that forms self-assembled monolayer (SAM) film on an Au substrate. A SAM film using dendron moiety as a spacer can change the distance between rhodamines depending on the size, so that the energy transfer from an initially photo-excited rhodamine to its surrounding molecules can be controlled. The absorption spectrum of a SAM film for each generation of dendron was measured to ascertain a linear correlation between the generation and the distance. Picosecond time-resolved fluorescence spectra showed clear differences in the fluorescence decay dynamics between third-generation (G3) and fourth-generation (G4) dendron SAM films. In addition, we found that “dry” or “wet” dendron SAM considerably influenced fluorescence behavior. As a result, the use of “wet” G4 SAM is suitable in preserving photo-excitation energy. This is because it gave almost equal dynamics to G4 dendron in the dilute solution and prevented deactivation by energy dissipation. 相似文献
42.
Yoshihiro Ichikawa Shigeki Obote Kenichi Kagoshima 《Wireless Personal Communications》2005,35(4):353-364
A tapped delayed line adaptive array antenna (TDL-AAA) and a space-temporal simultaneous processing equalizer (ST-SPE) are
proposed as simple space-temporal equalizers based on minimum mean square error (MMSE) criterion. The ST-SPE has a compact
hardware with a small number of taps compared to that of the TDL-AAA. The ST-SPE can reduce the computational complexity of
the space-temporal joint equalization and it works effectively under the minimum phase condition such as appeared at line-of-sight
(LOS) propagation environments at a high antenna height base station. However the ST-SPE cannot work under a non-minimum phase
condition caused under N-LOS (non-line-of-sight). On the other hand, the TDL-AAA whose reference signal is synchronized at
the center tap (TDL-AAAC) can work even in the non-minimum phase condition. In this paper, we propose a dual-mode space-temporal simultaneous processing
equalizer (Dual-mode ST-SPE) which has a simple configuration and also works in non-minimum phase condition. The Dual-mode
ST-SPE can reduce the computational complexity compared to the TDL-AAAC.
Yoshihiro Ichikawa received the B.E. degree in department of communication engineering, in National Defense Academy in 1995, and M.E. and D.E.
degree from Ibaraki University in 2001 and 2004, respectively. He joined the Japan Air Self Defense Force in 1995. His research
interests are an adaptive algorithm, an antenna design, and an adaptive array antenna.
Shigeki Obote received his B.E., M.E. and D.E. degrees in electrical and electronic engineering from Tottori University, Tottori, Japan,
in 1996, 1998 and 2000, respectively. Since 2000, he has been with department of media and telecommunications engineering,
faculty of engineering, Ibaraki University, Ibaraki, Japan, where he is currently a associate professor. His research interests
are in adaptive array antenna and wireless communications systems.
Kenichi Kagoshima received the B.E., M.E. and D.E. degrees in electronics engineering from the Tokyo Institute of Technology, Tokyo, Japan,
in 1969, 1971, and 1974, respectively. He joined the Nippon Telegraph and Telephone Corporation (NTT) Laboratory in 1974 and
researched and developed many kinds of radio communication antennas. Since 1997, he has been a professor at Ibaraki University,
Ibaraki, Japan. Dr. Kagoshima was a Secretary and Treasure, Vice Chairman, and Chairman of the IEEE AP-S Tokyo Chapter in
1992, 1993, and 1994, respectively. He was a chair of antennas and propagation professional group of IEICE in 1999 and 2000.
In 1973, he received the Yonezawa Prize for Young Engineers and 1998, best paper award from IEICE, respectively. 相似文献
43.
44.
Hiroyuki Sasakura Yoshiya Akagi Masashi Tanaka Shigeki Tsukui Motoaki Adachi 《Journal of Superconductivity and Novel Magnetism》2012,25(2):305-309
New Pb-based 1222 cuprates containing phosphorus have been synthesized in the (Pb0.75P0.25)Sr2- (RE2–x–y
Ce
x
Sr
y
)Cu2O
z
(RE = Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, and Y) systems. The almost-single phase samples are obtained for 0.5≤x≤1.0 and y=0.1 in the cases of RE = Nd, Dy, Ho, Er, Tm, Yb and Y, while for 0.3≤x≤1.0 and y=0.1 in the cases of RE = Sm, Eu and Gd. The samples crystallize in a tetragonal lattice, the lattice parameters a and c are decreasing with the decrease of the ionic radius of the RE element. Even after annealing under 143 atm O2 atmosphere at 400 °C, almost all the samples with the common values x=0.5 and y=0.1 are semiconductors with a transport process followed by three-dimensional variable range hopping. However, the samples
of RE = Sm, Eu and Gd, which are of almost single 1222 phase, even for x=0.3 and y=0.1, show superconductivity with the onsets at about 25 K, 20 K and 22 K, respectively. Through this study, we find very
important procedure for discovery of new superconducting 1222 compound. 相似文献
45.
Sequential anodic and cathodic pulse voltages were applied on anodised Al micro-electrodes in alkaline silicate electrolyte to explore the role of cathodic pulse in AC or bipolar plasma electrolytic oxidation (PEO) process. SEM observation was carried out to observe the sites of anodic and cathodic breakdown and their morphologies. The prior anodic breakdown accelerated the cathodic breakdown at ?50 V, and the acceleration was associated with the preferential cathodic breakdown at the anodic breakdown sites. However, the succeeding anodic breakdown during applying anodic pulse of 420 V for 2 ms was highly suppressed at the cathodic breakdown sites. This would randomise the anodic breakdown sites. Such role may contribute to the formation of rather uniform coatings on aluminium in this electrolyte without large discharge channels when larger cathodic current is applied with respect to the anodic current in AC PEO. 相似文献
46.
A simple capillary electrophoretic method was developed for the determination of glucosamine using in-capillary derivatisation. Glucosamine in commercial products was extracted with purified water. The CE separation was achieved on an uncoated fused-silica capillary using a 20 mM borate buffer (pH 9.2) containing 5 mM o-phthalaldehyde (OPA) and 5 mM 3-mercaptopropionic acid (MPA) at 25 kV, followed by UV detection at 340 nm. The detector response was linear (r2 > 0.999) in the concentration range 10–1000 μg/mL. The limit of detection (LOD) was 1.3 mg/g. Spiked glucosamine recoveries at 50 and 100 mg/g level were 95.1% and 104.3%, respectively. The method was applied to 16 commercial products. The concentrations of glucosamine were 109–705 mg/g, and the ratios of detected glucosamine content to the labelled value were 88.8–124%. No significant bias was observed (r2 = 0.989, p < 0.01), between results obtained by the proposed CE method and an official colorimetric method (Japanese Health Food & Nutrition Food Association). 相似文献
47.
Inside Cover: Biosynthetic Gene Cluster for Surugamide A Encompasses an Unrelated Decapeptide,Surugamide F (ChemBioChem 18/2016) 下载免费PDF全文
48.
Inhibitory Effect of 8‐Halogenated 7‐Deaza‐2′‐deoxyguanosine Triphosphates on Human 8‐Oxo‐2′‐deoxyguanosine Triphosphatase,hMTH1, Activities 下载免费PDF全文
Dr. Yizhen Yin Prof. Dr. Shigeki Sasaki Prof. Dr. Yosuke Taniguchi 《Chembiochem : a European journal of chemical biology》2016,17(7):566-569
hMTH1 (8‐oxo‐2′‐deoxyguanine triphosphatase) hydrolyzes oxidized nucleoside triphosphates; its presence is non‐essential for survival of normal cells but is required for survival of cancer cells. In this study, 8‐halogenated‐7‐deaza‐2′‐deoxyguanosine triphosphate (8‐halogenated‐7‐deazadGTP) derivatives were synthesized. Interestingly, these triphosphates were poor substrates for hMTH1, but exhibited strong competitive inhibition against hMTH1 at nanomolar levels. This inhibitory effect is attributed to slower rate of hydrolysis, possibly arising from enzyme structural changes, specifically different stacking interactions with 8‐halogenated‐7‐deazadGTP. This is the first example of using nucleotide derivatives to inhibit hMTH1, thus demonstrating their potential as antitumor agents. 相似文献
49.
50.
Yunosuke Abe Toshiki Aoki Hongge Jia Shingo Hadano Takeshi Namikoshi Yuriko Kakihana Lijia Liu Yu Zang Masahiro Teraguchi Takashi Kaneko 《Polymer》2012,53(11):2129-2133
A soluble and stable one-handed helical conjugated polymer without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer having two hydroxyl groups followed by desubstitution of the chiral groups in a solid membrane state. The reason for the success was the polymer reaction was carried out in the membrane state. This is an alternative method to obtain such a unique chiral polymer which was obtained only by the helix-sense-selective polymerization (HSSP) we reported before. In addition the efficiency of the chiral induction was higher than that of the HSSP. It is interesting that the “Membrane state” acted like as if a protecting group. 相似文献