Interface quality and thermal stability of laser-deposited metal/MgO multilayers

Metal/MgO multilayers (metal of Fe, Ni80Nb20, and Ti) with bilayer periods in the range 1.2-3.0 nm have been prepared by pulsed laser deposition and characterized by both hard and soft-x-ray reflectometry. The interface roughness is found to be < or = 0.5 nm in all the samples and is nearly independent of the total number of deposited bilayers. The interface roughness, however, depends on the absolute thickness of the individual layers and increases from approximately 0.3 nm for a 3.0-nm period to approximately 0.5 nm for a bilayer period of 1.2 nm. The multilayers are found to be highly stable up to temperatures as high as 550 degrees C. The hard-x-ray reflectivity of the multilayers decreases for T > 300 degrees C, whereas the layered structure is stable up to 550 degrees C. The reflectivity in the water window region of soft x rays, lambda = 3.374 nm, was found to be 0.4% at an angle of incidence of approximately 54 degrees for multilayers with 60 bilayers at a period of approximately 2.1 nm.     

Fourier transform infrared-probed O(3P) microreactor: demonstration with ethylene reactions in argon matrix

To demonstrate the development of an oxygen atom microreactor in the form of liquid-helium-cooled solid argon matrix deposited on an infrared (IR) window, the oxidation of ethylene by mobile O atoms has been investigated. O atom diffusion through the argon matrix is confirmed and used to examine ethylene-oxygen atom reactions. In a bench-scale matrix isolation system probed with a Fourier transform infrared (FT-IR) spectrometer, matrices of solid Ar at 8-10 K doped with NO2 and ethylene have been prepared on a ZnSe window within an evacuated cryostat. The matrices have been photolyzed using 350-450 nm photons, and the reaction products resulting from the reaction of O(3P), one of the photolysis products of NO2, with ethylene have been identified using FT-IR and a Gaussian 98W simulation program. These products include oxirane, acetaldehyde, ethyl nitrite radical, and ketene. The temperature effect in the range of 10-30 K on the products formed has also been investigated. The reaction mechanisms are discussed and the viability of the solid Ar matrix being a low temperature microreactor to examine reaction mechanisms of mobile oxygen atoms is elaborated.     

Water-related matrix isolation phenomena during NO2 photolysis in argon matrix

Photolysis (350-450 nm) of NO(2) molecules trapped in argon matrices at 10 K has been studied using Fourier transform infrared (FTIR) spectroscopy to examine the mobility of the photolysis products, O((3)P) and NO, and their subsequent reactions. The formation of N(2)O(5) and N(2)O(3) from reactions of these mobile species with immobilized NO(2) and N(2)O(4) is confirmed. Water molecules from the background gases in the vacuum have been found to be isolated in the argon matrix during deposition of diluted NO(2) in Ar. The entrapped water molecules along with some of their NO(2) adducts have been characterized. Exposure of the matrix to photons to photolyze NO() resulted in not only internal matrix reactions, but also an enhanced deposition of ice over the surface of the argon matrix. This is caused by photodesorption of water molecules from the walls of the matrix isolation chamber and their subsequent condensation on the matrix surface. This ice overlayer has been found to give a very significant dangling OH band and a substantial librational band in the FT-IR spectra, indicating substantial surface area and internal porosity, respectively. The potential of using photodesorbed water to establish high surface area ice interfaces with dangling OH groups for heterogeneous photoreaction studies is discussed.     

Optimisation of processing variables in the preparation of sweet potato chips using response surface methodology

Models capable of predicting the product quality of sweet potato chips have been developed using response surface methodology and used to determine the optimum processing conditions. Moisture loss, oil uptake, crispness (measured using a bending-snapping test in the TA.XT2 Texture Analyser), and sensory attributes such as colour, flavour, and texture were used to assess the product quality in the preparation of sweet potato chips. The optimum conditions which were attained for maximum moisture loss (11.65% on wet basis), minimum oil uptake (2.57%), crispness (794.37 g), colour score (7), flavour score (7) and texture score (7) were: frying temperature, 174.7 °C; salt concentration, 0.45%; citric acid concentration, 0.37%; potassium metabisulphite concentration, 0.65%; and frying time, 26 s.     

Optimal Design of a Stable Trapezoidal Channel Section Using Hybrid Optimization Techniques

A cost effective channel section for a specified flow rate, roughness coefficients, longitudinal slope, and various cost parameters can be determined using an optimization technique. However, the derived optimal channel section may not be feasible for construction because of in situ conditions. The local soil conditions may not support the optimal side slope of the channel and if constructed, the slope may fail. It is therefore necessary to also incorporate the criteria for side slope stability in designing an optimal open channel section. In this paper, a new methodology has been developed to design a stable and optimal channel section using hybrid optimization techniques. A genetic algorithm based optimization model is developed initially to determine the factor of safety of a channel slope for given soil parameters. This optimization model is then externally linked with a separate sequential quadratic programming based optimization model to evaluate the parameters of the stable and optimal channel section. Solution for various example problems incorporating different soil parameters are illustrated to demonstrate the applicability of the developed methodology.     

Dielectric studies of tin based chalcogenide glasses

The dc conductivity and dielectric parameters of glassy system of a-Se₇₀Te_30−x Sn _x (x = 0, 2, 4, 6, 8 and 10) glasses have been investigated. Frequency and temperature dependence of dielectric constants (ε′) and dielectric loss (ε′′) are studied in the frequency range 120–100 kHz and temperature range 300–390 K. Dielectric dispersion is observed when Tin (Sn) is incorporated to a-Se–Te system in the entire temperature range. These results explain that the dc conduction loss is dominated in the present system. From dc conductivity studies it is observed that the dc conductivity and activation energy increases with increasing tin concentration in the present system.     

Hydrothermally Oxidized Single‐Walled Carbon Nanotube Networks for High Volumetric Electrochemical Energy Storage

Improving volumetric energy density is one of the major challenges in nanostructured carbon electrodes for electrochemical energy storage device applications. Herein, a simple hydrothermal oxidation process of single‐walled carbon nanotube (SWNT) networks in dilute nitric acid is reported, enabling simultaneous physical densification and chemical functionalization of the as‐assembled randomly‐packed SWNT films. After the hydrothermal oxidation process, the density of the SWNT films increases from 0.63 to 1.02 g cm^?3 and a considerable amount of redox‐active oxygen functional groups are introduced on the surface of the SWNTs. The functionalized SWNT films are used as positive electrodes against Li metal negative electrodes for potential Li‐ion capacitors or Li‐ion battery applications. The functionalized SWNT electrodes deliver high volumetric as well as gravimetric capacities, 154 Ah L^?1 and 152 mAh g^?1, respectively, owing to the surface redox reactions between the introduced oxygen functional groups and Li ions. In addition, these electrodes exhibit a remarkable rate‐capability by retaining its high capacity of 94 Ah L^?1 (92 mAh g^?1) at a high discharge rate of 10 A g^?1. These results demonstrate the simple hydrothermal oxidation process as an attractive strategy for improving the volumetric performance of nanostructured carbon electrodes.     

Modelling social norms in multiagent systems

Social norms are cultural phenomena that naturally emerge in human societies and help to prescribe and proscribe normative patterns of behaviour. In recent times, the discipline of multi-agent systems has been used to model social norms in an artificial society of agents. In this paper we review norms in multi-agent systems and then explore a series of norms in a simulated urban traffic setting. Using game-theoretic concepts we define and offer an account of norm stability. Particularly in small groups, a relatively small number of individuals with cooperative attitude are needed for the norm of cooperation to evolve and be stable. In contrast, in larger populations, a larger proportion of cooperating individuals are required to achieve stability.     

Classification of pulsed eddy current GMR data on aircraft structures

This paper presents a technique to automatically detect third-layer cracks at rivet sites in aircraft structures using the response signals collected by giant magneto-resistive (GMR) sensors. The inspection system uses pulsed waveform as the excitation source of a multi-line coil and captures the transient fields associated with the induced eddy currents via a GMR sensor, which was developed to detect cracking and corrosion in multi-layer aircraft structures. An automatic scan of the region around the rivet generates C-scan image data that can be processed to detect cracks under the rivet head. Using a 2-D image of each rivet head, feature extraction and classification schemes based on principal component analysis and the k-means algorithm have been successfully developed to detect cracks of varying size located in the third layers at a depth of up to 10 mm below the surface.