Virtual plasma equipment model: a tool for investigating feedbackcontrol in plasma processing equipment

As microelectronics device feature sizes continue to shrink and wafers continue to increase in size, it is necessary to have tighter tolerances during the fabrication process to maintain high yields. Feedback control has, therefore, become an important issue in plasma processing equipment design; comprehensive plasma equipment models linked to control algorithms would greatly aid in the investigation and optimal selection of control strategies. This paper reports on a numerical plasma simulation tool, the virtual plasma equipment model (VPEM), which addresses this need to test feedback control strategies and algorithms on plasma processing equipment. The VPEM is an extension of the hybrid plasma equipment model which has been augmented by sensors and actuators, linked together through a programmable controller. The sensors emulate experimental measurements of species densities, fluxes, and energies, while the actuators change process parameters such as pressure, inductive power, capacitive power, electrode voltages, and mole fraction of gases. Controllers were designed using a response surface based methodology. Results are presented from studies in which these controllers were used to compensate for a leak of N₂ into an Ar discharge, to stably control drifts in process parameters such as pressure and power in Ar and Ar/Cl₂, and to nullify the effects of long term changes in wall conditions in Cl₂ containing plasmas. A new strategy for improving the ion energy flux uniformity in capacitively coupled discharges using feedback control techniques is also explored     

Probabilistic stability of uncertain composite plates and stochastic irregularity in their buckling mode shapes: A semi-analytical non-intrusive approach

In this study, the mechanical properties of the composite plate were considered Gaussian random fields and their effects on the buckling load and corresponding mode shapes were studied by developing a semi-analytical non-intrusive approach. The random fields were decomposed by the Karhunen−Loève method. The strains were defined based on the assumptions of the first-order and higher-order shear-deformation theories. Stochastic equations of motion were extracted using Euler–Lagrange equations. The probabilistic response space was obtained by employing the non-intrusive polynomial chaos method. Finally, the effect of spatially varying stochastic properties on the critical load of the plate and the irregularity of buckling mode shapes and their sequences were studied for the first time. Our findings showed that different shear deformation plate theories could significantly influence the reliability of thicker plates under compressive loading. It is suggested that a linear relationship exists between the mechanical properties’ variation coefficient and critical loads’ variation coefficient. Also, in modeling the plate properties as random fields, a significant stochastic irregularity is obtained in buckling mode shapes, which is crucial in practical applications.     

A Novel Hexahedral Interface Element for Nonlinear Crack Analysis

Existence of a crack in structures would lead to a sudden failure and damage. Establishing a precise analytical model for the cracked element would be a powerful tool to achieve the right answers in the analysis of the structure. The main aim of this article is to formulate a hexahedral interface element for use in nonlinear crack analysis. In this investigation, the kinematics of the discontinuous displacement field along with the virtual work principle, for a body with an internal discontinuity, is utilized. Based on the suggested interpolation functions for the discrete segments, and also the element displacement field, the element stiffness matrix is calculated. The proposed element can be used for modeling of the discrete cracks in three-dimensional problems, such as a concrete dam. Several numerical examples are analyzed for the accuracy test and a few of them are presented here. The results indicated that utilizing sufficient elements yields suitable answers.     

The influence of gender on cough reflex sensitivity

BACKGROUND: The more common occurrence in women of cough due to angiotensin-converting enzyme inhibitors raises the possibility of gender-related differences in the sensitivity of the cough reflex. Of two recent studies that evaluated cough response to inhaled capsaicin in normal subjects, one demonstrated heightened sensitivity of the cough reflex in women compared with men, while the other revealed no gender-related differences. To further investigate this question, we reviewed our experience with cough challenge testing in normal volunteers. STUDY OBJECTIVE: To compare cough reflex sensitivity in healthy adult female and male subjects. DESIGN: Retrospective data analysis. SETTING: Academic medical center. PARTICIPANTS: One hundred healthy volunteers (50 male, 50 female). Interventions: Subjects inhaled capsaicin in ascending, doubling concentrations until the concentration inducing five or more coughs (C5) was reached. In addition, the concentration inducing two or more coughs (C2; cough threshold) was measured. Results: Mean log C5 was significantly lower in women than in men: 1.02+/-0.09 (SEM) microM vs 1.41+/-0.08 microM, respectively (p=0.002). Log C2 (cough threshold) was also significantly lower in female subjects: 0.534+/-0.068 microM vs 0.870+/-0.065 microM in male subjects (p=0.00058). CONCLUSION: Healthy women have a more sensitive cough reflex than do healthy men. The reasons for this significant gender difference remain to be elucidated, but may involve a heightened sensitivity, in women, of the sensory receptors within the respiratory tract that mediate cough.     

Styrene butadiene rubber/epoxidized natural rubber/carbon filler nanocomposites: microstructural development and cure characterization

Microstructural development of elastomeric nanocomposites based on (50/50 wt%) styrene butadiene rubber (SBR) and epoxidized natural rubber (50 mol% epoxidation, ENR50) as the rubber matrix including two types of carbon fillers, carbon black (CB) and functionalized multiwall carbon nanotube (NH₂-MWCNT), which were prepared through melt mixing, was studied. The results from FTIR analysis show that there is interaction between functional groups on MWCNT surface and the rubber chains. The AFM analysis also indicates good dispersion of filler particles in the rubber phases. FESEM images from cryo-fractured surface of samples have revealed that nanotubes were rarely pulled out of matrix and their diameter increased, resulting from good interaction between MWCNTs and rubber chains. The DMA results confirm good interfacial interaction between them. Furthermore, the reduced difference between the two T_gs of phases (ΔT_g) shows that the incorporation of 3 phr MWCNT into the blend leads to increment in rubber phase compatibility but at higher MWCNT content (5 phr) due to lower Mooney viscosity of SBR phase, MWCNTs tend to remain in this phase. The bound rubber was adopted to characterize the polymer–filler interaction, showing that bound rubber content has an increasing trend with increasing in fillers content. The cure rheometric studies reveal that MWCNTs accelerate the cure process due to the presence of amine groups on the nanotube surface. In addition, the mechanical properties of samples show an increasing trend by increasing nano-filler content.

     

Prolonged drug release using PCL–TMZ nanofibers induce the apoptotic behavior of U87 glioma cells

In situ prolonged delivery of drugs at the site of tumor can be satisfactorily accelerated patient recovery. We compared the effect of temozolomide while incorporated by polycaprolactone nanofibers on the apoptotic behavior of U87 glioma cells. After biocompatibility evaluation of nanofibers by scanning electron microscope and 3-(4,5-dimethylthiazolyl-2)-2,5-diphenyltetrazolium bromide analysis, the apoptosis of U87 cells was evaluated using p53, Bcl2 and Bax genes expression. It was found that nanofiber-temozolomide group showed a greater ability to induce apoptosis as well as have a significantly diminished initial burst release of drug compared with other groups and have promising potential in treating cancer.     

Perovskite SrFe1-xTixO3-δ (x < = 0.1) cathode for low temperature solid oxide fuel cell

Stable and compatible cathode materials are a key factor for realizing the low-temperature (LT, ≤600?°C) operation and practical implementations of solid oxide fuel cells (SOFCs). In this study, perovskite oxides SrFe_1-xTi_xO_3-δ (x?< = 0.1), with various ratios of Ti doping, are prepared by a sol-gel method for cathode material for LT-SOFCs. The structure, morphology and thermo-gravimetric characteristics of the resultant SFT powders are investigated. It is found that the Ti is successfully doped into SrFeO_3-δ to form a single phase cubic perovskite structure and crystal structure of SFT shows better stability than SrFeO_3-δ. The dc electrical conductivity and electrochemical properties of SFT are measured and analysed by four-probe and electrochemical impedance spectra (EIS) measurements, respectively. The obtained SFT exhibits a very low polarization resistance (R_p), .01 Ωcm² at 600?C. The SFT powders using as cathode in fuel cell devices, exhibit maximum power density of 551?mW?cm^?2 with open circuit voltage (OCV) of 1.15?V at 600?C. The good performance of the SFT cathode indicates a high rate of oxygen diffusion through the material at cathode. By enabling operation at low temperatures, SFT cathodes may result in a practical implementation of SOFCs.     

Heavy Water Additive in Formamidinium: A Novel Approach to Enhance Perovskite Solar Cell Efficiency

Heavy water or deuterium oxide (D₂O) comprises deuterium, a hydrogen isotope twice the mass of hydrogen. Contrary to the disadvantages of deuterated perovskites, such as shorter recombination lifetimes and lower/invariant efficiencies, the serendipitous effect of D₂O as a beneficial solvent additive for enhancing the power conversion efficiency (PCE) of triple-A cation (cesium (Cs)/methylammonium (MA)/formaminidium (FA)) perovskite solar cells from ≈19.2% (reference) to 20.8% (using 1 vol% D₂O) with higher stability is reported. Ultrafast optical spectroscopy confirms passivation of trap states, increased carrier recombination lifetimes, and enhanced charge carrier diffusion lengths in the deuterated samples. Fourier transform infrared spectroscopy and solid-state NMR spectroscopy validate the N–H₂ group as the preferential isotope exchange site. Furthermore, the NMR results reveal the induced alteration of the FA to MA ratio due to deuteration causes a widespread alteration to several dynamic processes that influence the photophysical properties. First-principles density functional theory calculations reveal a decrease in PbI₆ phonon frequencies in the deuterated perovskite lattice. This stabilizes the PbI₆ structures and weakens the electron–LO phonon (Fröhlich) coupling, yielding higher electron mobility. Importantly, these findings demonstrate that selective isotope exchange potentially opens new opportunities for tuning perovskite optoelectronic properties.