Sol- gel synthesis of Ga2O3 nanorods and effect of precursor chemistry on their structural and morphological properties

Synthesis of mono-crystalline Ga₂O₃ Nanorods was done by sol-gel transformation of gallium(III) isopropoxide (Ga(OPrⁱ)₃). XRD studies were done to determine the planes and crystal structure of synthesized nanorods that showed the synthesis of β-Ga₂O₃(a). TEM studies of synthesized Ga₂O₃ confirmed the synthesis of monocrystalline β-Ga₂O₃ nanorods. To study the effect of precursor chemistry and to determine role of precursor structures on the crystal structure, phase and morphology of the Ga₂O₃, a new modified precursor complex was synthesized. The reaction of Ga(OPrⁱ)₃ with N-phenylsalicylaldimine, [C₆H₄(OH)CH=N(C₆H₅)] in 1:1?M ratio yielded [{(H₅C₆)N?=?CH-C₆H₄O}Ga(OPrⁱ)₂]. The newly synthesized complex was characterized by elemental analyses, molecular weight measurement, FT-IR and NMR (¹H and ¹³C) spectral studies. Spectral studies of the modified complex suggest the presence of bi-dentate mode of attachment of Schiff's base in the solution state. Sol-gel transformations of [{(H₅C₆)N?=?CH-C₆H₄O}Ga(OPrⁱ)₂] in organic medium, yielded γ-Ga₂O₃(b), as found by XRD studies. TEM image of the sample (a) revealed the formation of nano-rods of oxide with average diameter of ~100?nm whereas the TEM image of sample (b) showed presence of nano-sized particles of oxide with average particle size of 10?nm. Morphological and compositional studies of synthesized samples (a) and (b) were carried out using SEM and EDX. The method provides a possibility of large scale synthesis of dissimilar shaped and pure Ga₂O₃ nanoparticles.     

Synergetic effects of organic and inorganic additives on improvement in hydrophilicity and performance of PVDF antifouling ultrafiltration membrane for removal of natural organic material from water

Surrounding vegetation, animal, human and microbiological decomposition are the strong source of humic acid (HA) falling into the surface water bodies through rain runoff in the monsoon. HA contains various functional groups, such as carboxylic, phenolic, hydroxyl, and quinine, which are the major foulant. Contact of HA may have an adversarial health issue to human beings namely goiter, black foot, and cancer disease. The maximum permissible limit of HA in drinking water should be less than 2 ppm as per the Environmental Protection Agency (EPA). The membrane technology has prevailed a prominent place worldwide in chemical, water and wastewater treatment technologies. The proposed work is focused on the blending of organic-water soluble polymer polyethylene glycol 6000 as a pore-forming agent and inorganic salt lithium bromide (LiBr) as membrane morphology modifier with polyvinylidene fluoride host polymer in the N,N-Dimethylacetamide solvent. All fabricated membranes were characterized for functional groups and morphology. The total number of pores per unit surface area of membrane for membranes M-LiBr-0, M-LiBr-1, M-LiBr-2, and M-LiBr-3 are 2 × 10¹³, 2.3 × 10¹⁴, 2.7 × 10¹⁴ and 2.82 × 10¹⁴, respectively. The static water contact angle was decreased from 68.2° to 50.6° with an increase in the content of LiBr from 0 to 3 wt%. The order of pure water flux and hydraulic permeability of the membrane was M-LiBr-0 < M-LiBr-1 < M-LiBr-2 < M-LiBr-3. The HA rejection of the membrane was also increased from 90.13% to 96.24% with LiBr content due to a decrease in pore size of the membrane with the addition of LiBr content.     

Effect of matrix content on the performance of carbon paper as an electrode for PEMFC

Porous conducting carbon fiber‐based composite paper is used as an electrode backing in the fuel cell assembly. It not only acts as a channel through which the reactant and product gases pass to and from the bipolar plate and the catalyst site but also helps in the flow of electrons. In order to perform its role efficiently, it should have sufficient strength, high electrical conductivity, and ideal porous structure. Carbon paper has been fabricated, which builds up the required composite properties. Studies have been conducted to optimize the fiber/matrix ratio in the carbon paper, while ensuring the perfect combination of porosity, mechanical strength, and electrical conductivity for an electrode in a proton electrolyte membrane fuel cells. Detail physico‐mechanical and electrochemical characterizations further ascertain that the fiber/matrix ratio plays an important role in tuning the composite properties. The polarization curve of the unit proton exchange membrane (PEM) fuel cell (with an effective electrode area 4 cm²) shows a peak power density of 916 mW/cm² for the sample with fiber/matrix ratio of 65:35, which is almost the same as the commercially available sigracet gas diffusion layer (SGL) carbon paper tested under similar conditions. Further, proportionally enlarging the electrode area to 100 cm² shows that the carbon paper not only shows almost repeatable results in a given set up but also scales up.     

Frame selection for OCR from video stream of book flipping

Multimedia Tools and Applications - Optical Character Recognition (OCR) in video stream of flipping pages is a challenging task because flipping at random speed causes difficulties in identifying...     

Application Layer Scheduling in Cloud: Fundamentals,Review and Research Directions

The cloud computing paradigm facilitates a finite pool of on-demand virtualized resources on a pay-per-use basis. For large-scale heterogeneous distributed systems like a cloud, scheduling is an essential component of resource management at the application layer as well as at the virtualization layer in order to deliver the optimal Quality of Services (QoS). The cloud scheduling, in general, is an NP-hard problem due to large solution space, thus, it is difficult to find an optimal solution within a reasonable time. In application layer scheduling, the tasks are mapped to logical resources (i.e., virtual machines), aiming to optimize one or more QoS parameters, and conforming to several constraints. Various algorithms have been proposed in the literature for application layer scheduling, where each of them is based on some fundamental design techniques like simple heuristics, meta-heuristics, and most recently hybrid heuristics. Although ample literature survey exists for cloud scheduling algorithms, none of them present their study exclusively for the application layer. In this survey paper, we present a study on task scheduling algorithms used only at the application layer of the cloud. We classify our study according to various fundamental techniques used in designing such scheduling algorithms. One of the main features of our study is that it covers numerous application type e.g., a set of independent tasks, simple workflow, scientific workflow, and MapReduce jobs. We also provide a comparative analysis of existing algorithms on various parameters like makespan, cost, resource utilization, etc. In the end, research directions for future work have been provided.     

Performance improvement of 60‐GHz wireless optical systems with reverse‐parallel hybrid modulation scheme

This paper improves the performance of 60‐GHz wireless optical system including radio over fibre (RoF) and radio over free space optics (RoFSO), based on novel reverse‐parallel (RP) hybrid modulation scheme. This scheme combines the chromatic dispersion compensation technique of parallel modulation with energy efficiency manipulation technique of reverse modulation. Superior functioning of RoFSO is provided with reverse modulation compared with normal modulation. Comparative investigations are performed by loading 60‐GHz RF signal with 2.5 and 10‐Gbps data and modulating it with both reverse and hybrid modulators. Hybrid modulation performed better with improved BER of 10^?23 at distance of 51 km for 2.5‐Gbps data compared with reverse modulation with BER of 10^?7.     

A trust computed framework for IoT devices and fog computing environment

Wireless Networks - In this paper, we have demoralized the transmission processing concerns of fog nodes and IoT device layer attack during the handoff (mobility) of IoT devices in the fog...     

Design of a compact protrudent‐shaped ultra‐wideband multiple‐input‐multiple‐output/diversity antenna with band‐rejection capability

In this endeavor, a new multiple‐input‐multiple‐output antenna with a sharp rejection at wireless local area network (WLAN) band is designed and practically examined for portable wireless ultra‐wideband applications. The intended diversity antenna possess a small size of 15 mm × 26 mm and two inverted L‐strip are loaded over the conventional rectangular patch antenna to form protrudent‐shaped radiator that acts as a radiating element. The sharp band‐rejection capability at WLAN is established by incising the L‐shaped slits at the decoupling structure. More than ?21 dB isolation is accomplished for the complete working band (ie, 2.87 ‐17 GHz). Degradation in the antenna efficiency at the center frequency of band rejection corroborates the good interference rejection capability. The working capabilities of the intended antenna are tested by using the isolation between the ports, total efficiency, gain, envelope correlation coefficient, radiation pattern, mean effective gain, and total active reflection coefficient.     

Quantization based multiple medical information watermarking for secure e-health

Multimedia Tools and Applications - In this paper, an improved wavelet based medical image watermarking algorithm is proposed. Initially, the proposed technique decomposes the cover medical image...     

Topical delivery of tetrahydrocurcumin lipid nanoparticles effectively inhibits skin inflammation: in vitro and in vivo study

Tetrahydrocurcumin (THC) also referred to as ‘white curcumin’, is a stable colorless hydrogenated product of curcumin with superior antioxidant and anti-inflammatory properties. The present study is an attempt to elevate the topical bioavailability of THC, post-incorporation into a nano-carrier system with its final dosage as a hydrogel. Lipid nanoparticles of THC (THC-SLNs) prepared by microemulsification technique were ellipsoidal in shape (revealed in transmission electron microscopy) with a mean particle size of 96.6?nm and zeta potential of ?22?mV. Total drug content and entrapment efficiency of THC-SLNs was 94.51%?±?2.15% and 69.56%?±?1.35%, respectively. Differential scanning calorimetry and X-ray diffraction studies confirmed the formation of THC-SLNs. In vitro drug release studies showed the drug release from THC-SLNs gel to follow Higuchi’s equation revealing a Fickian diffusion. Ex vivo permeation studies indicated a 17 times (approximately) higher skin permeation of THC-SLNs gel as compared with the free THC gel. Skin irritation, occlusion, and stability studies indicated the formulation to be nonirritating, and stable with a desired occlusivity. Pharmacodynamic evaluation in an excision wound mice model clearly revealed the enhanced anti-inflammatory activity of THC-SLNs gel and was further confirmed using biochemical and histopathological studies. It is noteworthy to report here that THC-SLNs gel showed significantly better (p?≤?0.001) activity than free THC in gel. As inflammation is innate to all the skin disorders, the developed product opens up new therapeutic avenues for several skin diseases. To the best of our knowledge, this is the first paper elaborating the therapeutic usefulness of white curcumin-loaded lipidic nanoparticles for skin inflammation.