Impedance spectroscopy of ultrafine-grain SnO2 ceramics with a variable grain size

The impedance spectra of nanocrystalline SnO₂ ceramics with an average grain size d ranging from 3 to 43 nm were investigated in the frequency range 1–10⁶ Hz at temperatures from 25 to 300°C in a dry oxygen atmosphere. Analysis of the experimental data by the graphoanalytical method made it possible to separate the contributions of grain bulk and grain boundaries to the conductivity. It is shown that the samples investigated can be arbitrarily divided into two groups with respect to the character of their conductivity. For the samples with an average grain size d < 25 nm, the charge transfer processes are almost completely determined by the grain boundaries. In samples with a larger grain size, the contribution of grain bulk to the conductivity is comparable with that of grain boundaries.     

Distribution of investments in the stock market, information types, and algorithmic complexity

For a simplest mathematical model of a stock market, the problem of optimal distribution of investments among different securities (stocks, bonds, etc.) is considered. Our results, which are obtained in terms of algorithmic complexity, allow to discuss heuristically the properties of sufficiently complex security portfolios in the conditions of daily changing return rates. All considerations are given in the combinatorial framework and do not use any probabilistic models.     

Uncertain fuzzy models and their applications: III. Optimal estimation

The quality-estimation and decision-making criteria based on the values of error possibility likelihood measures, error necessity likelihood, error possibility confidence, and error necessity confidence are considered. The criteria are formulated for the adequacy of an uncertain fuzzy (UF) model and conclusions based on the UF model for the object under investigation and the UF observation model.     

New technology for manufacturing gold smalto

A new technology for manufacturing gold smalto using a “liquid” gold preparation has been developed. Glasses with different hues for use as substrates in preparing smalto have been synthesized in the alkali-boro-silicate system. This has made it possible to expand the range of gold smalto. __________ Translated from Steklo i Keramika, No. 3, p. 36, March, 2007.     

Making combination drawing methods more efficient by controlling tool microroughness

Results are presented from extensive comparison studies of drawing operations performed with the use of drawplates whose working surfaces have an irregular or regular microroughness. Regularizing the microroughness of the working part of the drawplate makes it possible to control the dimensional accuracy of the resulting products within broad ranges of values.     

Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

Basics of synthesis and application of pseudohomogeneous coal and petroleum feedstock hydrogenation catalysts

The mechanism of formation and properties of emulsion-synthesized globular pseudoheterogeneous catalysts are considered. The results of application of these catalysts to coal hydrogenation and other industrial-chemistry processes are reported.