Reinforcement of graphene nanoplatelets on plasticized poly(lactic acid) nanocomposites: Mechanical,thermal, morphology,and antibacterial properties

Plasticized poly(lactic acid) (PLA)‐based nanocomposites filled with graphene nanoplatelets (xGnP) and containing poly(ethylene glycol) (PEG) and epoxidized palm oil (EPO) with ratio 2 : 1 (2P : 1E) as hybrid plasticizer were prepared by melt blending method. The key objective is to take advantage of plasticization to increase the material ductility while preserving valuable stiffness, strength, and toughness via addition of xGnP. The tensile modulus of PLA/2P : 1E/0.1 wt % xGnP was substantially improved (30%) with strength and elasticity maintained, as compared to plasticized PLA. TGA analysis revealed that the xGnP was capable of acting as barrier to reduce thermal diffusion across the plasticized PLA matrix, and thus enhanced thermal stability of the plasticized PLA. Incorporation of xGnP also enhanced antimicrobial activity of nanocomposites toward Escherichia coli, Salmonella typhimurium, Staphylococcus aureus, and Listeria monocytogenes. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41652.     

Synthesis,Characterization, and Investigation of Inhibitor Release of the Anticorrosion Sol–Gel Hybrid Nanocomposite Coatings

Protection of Metals and Physical Chemistry of Surfaces - Corrosion protective coatings were developed on 1050 aluminum alloy through the sol–gel process using...     

Vibration of antisymmetric angle-ply composite annular plates of variable thickness

Journal of Mechanical Science and Technology - Based on first order shear deformation theory, free vibrational behaviour of antisymmetric angle-ply composite annular plate is investigated. The...     

Shape sensitivity analysis of composites in contact using the boundary element method

This paper presents the application of the boundary element method to the shape sensitivity analysis of two-dimensional composite structures in contact. A directly differentiated form of boundary integral equation with respect to geometric design variables is used to calculate shape design sensitivities for anisotropic materials with frictionless contact. The selected design variables are the coordinates of the boundary points either in the contact or non-contact area. Three example problems with anisotropic material properties are presented to validate the applications of this formulation.     

Effect of precipitation on the geological development of badlands in arid regions

The main objective of this paper was to study the effect of precipitation on the geological development of badlands in arid regions. Field observations and laboratory investigations were carried out to characterize the surface soils of the Avonlea badlands in southern Saskatchewan, Canada, which is currently experiencing a rapid development in infrastructure. Three distinct surface sediments were identified: an upper slope of cemented sandstone, a mid-slope on weathered mudrock and a relatively flat basal pediment. Each of these soils reacts differently to rainfall events. Precipitation results in grain size reduction which, together with the consistency limits, explains the water sensitivity of the soils; the fines increased by 16% in the cemented sandstone, 78% in the weathered mudrock and 33% in the basal pediment. Erosion susceptibility was highest in the basal pediment (2% clays) followed by cemented sandstone (cementation by 6% active clays) and then by weathered mudrock (cohesion due to the 40% clay).     

An efficient extraction and clean‐up procedure for pesticide determination in olive oil

This work reports a simple, rapid, and effective extraction method based on liquid–liquid extraction (LLE) followed by matrix solid‐phase dispersion‐sonication for detection, identification and quantification of multiclass pesticides in virgin olive oil using liquid chromatography mass spectrometry (LC‐QTOF‐MS). LLE to extract pesticide residues in virgin olive oil was performed in order to study the centrifugation efficiency to obtain high recovery yield and low co‐extract fat residue in the final extract. Different suitable parameters of MSPD procedure were evaluated, such as nature of dispersing phase, clean‐up adsorbent, and volume of eluting solvent (acetonitrile) in different extraction conditions, with or without sonication. The best results were obtained using 5 g of virgin olive oil, 2 g of PSA as dispersant sorbent, 2 g of Florisil/GCB (70:30 w/w) as clean‐up sorbent, and 15 mL of acetonitrile as eluting solvent under conditions of 15 min ultrasonic bath at RT. Method validation was performed in order to study sensitivity, linearity, precision, and accuracy. Average recoveries ranged between 73.7 and 104.2% with relative SDs 5.3–13.4% at three concentration levels (25, 50, and 100 µg/kg). Detection and quantification limits ranged from 1.5 to 5 µg/kg and 3 to 9 µg/kg, respectively.     

DOE applied to multi-response optimisation study on performance,combustion and emission characteristics of a VCR diesel engine

There are various parameters which may influence the IC engine performance. The trial and error method is a technique used to identify the best parameters. However, this method demands extensive experimental work and results in a great waste of time and resources. Thus, the design of experiments (DOEs) developed by Taguchi is employed. The multi-responses which need to be maximised are brake thermal efficiency, mechanical efficiency, cylinder pressure and cumulative heat release rate, whereas the responses which are to be minimised are specific fuel consumption, oxides of nitrogen and carbon monoxide. In the present study, an optimised DOE(L9) orthogonal array based on the Taguchi statistical method was formulated and a series of experiments were conducted under controlled supervision by considering three different injection operating pressures (IOPs) (200, 220 and 240 bar) and three different compression ratios (CRs) (16.5, 17.5 and 18.5). The main objective of this paper is to find the best suited IOP and CR values which obtain higher performance, better combustion and lower emissions.     

Contemporary challenges of soot build-up in IC engine and their tribological implications

Confronted with the contemporary challenges of maximising energy efficiency with minimal impact on the environment, the automotive industry has developed various technologies to tackle them. Most of these technologies, however, have wider implications on the tribological performance of the automotive engines due to resultant soot build-up. This paper reviews the effects that attempts by stakeholders to satisfy requirements for reduced fuel consumption, reduced emissions and extended service intervals have had on increasing soot levels to an extent that can lead to engine component failure. Three areas have been identified that have either not been explored or not widely explored in the study of automotive soot namely: numerical simulation and modelling of soot wear, soot effects on wear of actual engine components and the wear and friction performance of non-metallic materials used in internal combustion engines. A paper-grading system is also utilised to present an overview of how sooty oil-related research covers various areas.     

Synthesis and Characterization of Molecularly Imprinted Polymer Membrane for the Removal of 2,4-Dinitrophenol

Molecularly imprinted polymers (MIPs) were prepared by bulk polymerization in acetonitrile using 2,4-dinitrophenol, acrylamide, ethylene glycol dimethacrylate, and benzoyl peroxide, as the template, functional monomer, cross-linker, and initiator, respectively. The MIP membrane was prepared by hybridization of MIP particles with cellulose acetate (CA) and polystyrene (PS) after being ground and sieved. The prepared MIP membrane was characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. The parameters studied for the removal of 2,4-dinitrophenol included the effect of pH, sorption kinetics, and the selectivity of the MIP membrane. Maximum sorption of 2,4-nitrophenol by the fabricated CA membrane with MIP (CA-MIP) and the PS membrane with MIP (PS-MIP) was observed at pH 7.0 and pH 5.0, respectively. The sorption of 2,4-dinitrophenol by CA-MIP and PS-MIP followed a pseudo–second-order kinetic model. For a selectivity study, 2,4-dichlorophenol, 3-chlorophenol, and phenol were selected as potential interferences. The sorption capability of CA-MIP and PS-MIP towards 2,4-dinitrophenol was observed to be higher than that of 2,4-dichlorophenol, 3-chlorophenol, or phenol.