A polymerizable photoredox initiation system for vinyl photopolymerization

A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP–DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.     

巧点火锅鸳鸯谱

北风起．火锅热。户外寒气逼人，屋内热气腾腾．鲜红的肉片。翠生生的青菜．在或红或白滚烫的锅中上下飞舞，仅是这灵动的姿态就让人禁受不住媚惑，抬手、举箸．一番狼吞虎咽，于是热气从心底缓缓升起，寒冷顿时一扫而空。[编者按]     

永州市抗御"碧利斯"台风的实践与思考

受2006年第四号台风“碧利斯”的影响,永州市出现了持续的强降雨过程,部分地区出现了大暴雨,引发了严重的洪涝灾害,成为近年来影响较为严重的一次台风暴雨。永州市在抗御这次台风暴雨过程中,高度警惕,充分准备,周密部署,科学调度,全力以赴抗灾救灾,将灾害损失降到了最低程度,全市没有垮一库一坝,没有因山洪灾害发生人员伤亡。文章总结了永州市的防灾抗灾经验,并针对防御台风暴雨存在的问题,探讨了进一步减轻台风暴雨灾害损失的对策。     

微波等离子体化学气相沉积的 a-Si∶H 性能研究

本文着重对微波等离子体化学气相沉积法高速沉积的 a-Si∶H 膜的物理性能进行评价研究.测量了沉积膜的光电性能、暗电导激活能、光禁带宽度、光吸收特性、沉积膜中悬键态密度以及氢含量等,并讨论沉积条件对膜性能的影响.结果表明,在沉积速率高达30～90(?)/s 情况下,膜的光电导(光照强度10~5Lux)与暗电导比值可达10~3～10~5,暗电导率从10~(-3)到10~(-11)((?)cm)~(-1),其激活能在0.23～0.88eV 之间(0～200℃温度范围内),光禁带宽度为1.40～2.20eV,氢含量约为2～20%.     

Structure Development Study of Pb (Zr, Ti)O3 Thin Films by an Optical Method

Lead zirconate titanates (Pb (Zr_xTi_1–x)O₃ or PZT) are well-known materials with useful ferroelectric properties for nonvolatile memory applications. The device applications usually require processes which form the ferroelectric perovskite phase at low temperatures. Understanding the various aspects of structure development of PZT films is the key to develop low-temperature processes. An effective, versatile, and nondestructive optical method was developed for the study of the structure development in PZT films. Also, models for the structure development were proposed and were verified by this optical method. Using this method, the characteristic temperatures at which both pyrochlore phase and perovskite phase are initiated and completed were identified. The pyrochloreperovskite transformation was initiated at lower temperature and completed faster for the films on the titanium-rich side than those on the zirconium-rich side. In addition, the volume fractions of the perovskite phase were obtained as a function of annealing temperature by this optical method.     

Can Robots Manifest Personality?: An Empirical Test of Personality Recognition,Social Responses,and Social Presence in Human–Robot Interaction

Personality is an essential feature for creating socially interactive robots. Studies on this dimension will facilitate enhanced human–robot interaction (HRI). Using AIBO, a social robotic pet developed by Sony, we examined the issue of personality in HRI. In this gender-balanced 2 (AIBO personality: introvert vs. extrovert) by 2 (participant personality: introvert vs. extrovert) between-subject experiment (N = 48), we found that participants could accurately recognize a robot's personality based on its verbal and nonverbal behaviors. In addition, various complementarity attraction effects were found in HRI. Participants enjoyed interacting with a robot more when the robot's personality was complementary to their own personalities than when the robot's personality was similar to their own personalities. The same complementarity attraction effect was found in participants' evaluation of the robot's intelligence and social attraction. Participants' feelings of social presence during the interaction were a significant mediator for the complementarity attraction effects observed. Practical and theoretical implications of the current study for the design of social robots and the study of HRI were discussed.     

Thermo-acoustic instability in the horizontal Rijke tube

The instability curve of a Rijke tube system was obtained accurately by following different paths of heat power and flow-rate for three regions and by defining its locus from the criterion based on the measured sound pressure levels. The unstable limits in the region of flow-rate lower than that at the minimal power are compared with previous data. To observe the effect of turbulence on the unstable limits, inflow turbulence was introduced by placing a bundle of circular cylinders upstream of the heating part (50< Re_d< 700). The large-amplitude inflow fluctuation may delay the transition of the chamber acoustic mode to the unstable zone even at a sufficient power.     

变权组合预测模型在大坝安全监测中的应用

简要介绍了组合预测模型的基本原理，该模型改进了单一模型考虑因素的片面性，但常规的组合预测模型的权系数是固定的。考虑到各种模型的预测精度的变化，以及大坝安全监测数据存在的突变、时效等因素，固定权系数的组合预测模型有待进一步改进。文中提出了变权系数组合预测模型，并将其用于实际的大坝安全监测工程。结果表明，变权组合预测模型的预报精度高于其他模型。是一种值得推广的方法。     

远洋山水居住区(西区)"九年一贯制"学校

远洋山水居住区（西区）的教育优势突出，在居住区的西南角规划设计了一所36班的“九年一贯制”示范学校。其中，小学部24班，初中部12班。该学校隶属于石景山教委，主要招生服务对象为远洋山水居住区（西区）和周边社区的居民。学校占地3.6ha，总建筑面积约23800m^2。     

防御超强台风的实践与思考

超强台风具有巨大的破坏力,如何防御超强台风并降低其灾害损失是一重大课题。浙江省在防御“桑美”超强台风的实践中认为,要取得防台抗灾的胜利,未雨绸缪、常备不懈是基础,以人为本、有效避险是关键。同时,针对“桑美”登陆后暴露出的各种问题,今后还要从4个方面加强工作,即建立集中与分散相结合的避险体系;加强电力、通信等应急基础保障能力建设;全面建成监测预警体系;加强超强台风研究,进一步完善防台风预案。