Hydroformylierung einfach und mehrfach ungesättigter Fettstoffe mit heterogenisierten Cobaltcarbonyl- und R

Hydroformylation of mono and multiple unsaturated fatty substances with heterogenized cobaltcarbonyl and rhodiumcarbonyl catalysts. Heterogenized cobalt and rhodiumcarbonyl catalyst systems can be used for the hydroformylation of mono and polyunsatured fatty substances in a technically simple and satisfying manner to useful chemical intermediates. The used solid tert. phosphane complex ligands have a silicate matrix and therefore they are also suitable for the cobalt catalyzed hydroformylation which is best performed at temperatures of 160–180^oC. The cobalt catalyzed reaction gives with polyunsaturated fatty substances almost only products with monofunctionalized fatty acid chains. Whereas, the rhodium catalyzed reaction gives with linolic acid compounds inhomogeneous mixtures of mono- and diformyl derivatives of these fatty substances. The heterogenized rhodium carbonyl catalyst systems therefore seem to be more suitable for the hydroformylation of monounsaturated compounds. This is also true for rhodiumcarbonylsupported aqueous phase-catalysts which give likewise mixtures of mono and diformyl derivatives in the hydroformylation of polyunsaturated fatty substances. In batch process after the complete conversion of the olefin and reduction of the CO/H₂-pressure the loss of catalyst metal from the support is negligible and in most cases below the detection limit (<1 ppm).     

解线性及二次型规划问题增广的神经网络

本文提出了一个解线性及二次型规划问题的神经网络模型，证明了该网络是全局稳定于平衡点，而平衡点就是线性及二次型规划问题的解，该网络的优点是能够实时获得问题的精确解，且可以同时获得带等式不式约束的对偶问题解，该网络易于电路实现。     

Bisensors for amino acids

Two kinds of biosensors for amino acids (one with nonspecific enzyme as bioelement, the other with specific enzyme(s) as bioelement), including their principles, applications, recent researches and future trends were discussed in detail. 61 references were given. A part of work for gaining Ph. D in chemical and biochemical application at FPMs (Mons, Belgique) Synopsis of the first author Xia Jinlan, Male, born in 1963, now at Facult’e Polytechnique de Mons, Belgique     

半绝缘砷化镓中碳含量对热稳定性的影响

本文报导了LEC法半绝缘砷化镓单晶中含碳量对SI-GaAs热稳定性的影响。在800℃以上退火,发现当晶体中C含量大于1.5×10~(16)cm~(-3)时,SI-GaAs的热稳定性变差;而C含量小于5×10~(15)cm~(-3)时,通常表现出良好的热稳定性。     

电流模精密整流电路

由电压型运算放大器组成的精密整流电路要严格地匹配电阻才能获得精密全波整流波形．本文给出一种具有CCⅡ电路特性由运算放大器AD844所构成的电流模精密整流电路．无需匹配电阻就可输出良好的精密全波整流波形．且具有输入电压范围大，频带宽等特点．     

开发PROFIBUS-DP智能从站

简单介绍了PROFIBUS－DP现场总线，同时讨论了利用89C52单片机和PROFIBUS－DP从站芯片SPC3开发PROFIBUS－DP智能从站的软硬件设计方法。     

油田勘探数据中心及辅助支持系统研究

文章简要介绍胜利油田近年来致力于勘探数据中心建设及辅助支持系统研究的背景、主要研究内容及进展情况,探讨了石油勘探行业在信息化时代利用先进的数据管理理念和技术对勘探工作提供数据支持和应用支持的尝试,对于其它油田勘探行业具有一定的借鉴意义。     

水利工程施工测量的探讨与研究

探讨水利工程施工过程中测量工作所起的作用，并对控制测量和施工放样各个过程中的细节以及技术问题进行了探讨和研究。     

PP-g-MAH对PA6/PP/TLCP三元共混物的增容改性作用

研究了PP-g-MAH对PA6／PP／TLCP三元共混体系的增容作用以及对共混物流变性能和力学性能的影响。通过共混物的DSC、SEM、POM、流变性能和力学性能测试，结果表明，PP－g-MAH对共混体系有明显的增容作用，共混物的力学性能（拉伸强度和冲击强度）得到提高；由于TLCP的加入，共混物的熔体粘度大大低于PA6的熔体粘度。