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101.
The thermoplastic polymer blends of commercial interest generally need a phase compatibilization to reduce the interfacial tension, to stabilize the morphology, and to increment the interfacial adhesion. This work deals with the compatibilization of PP/PS blends by addition of a tailor‐made copolymer, which is prepared from the pure homopolymers by a Friedel‐Crafts reaction. This addition compatibilization process comes out as an economic alternative applicable to the recycling of mixed plastics from urban and industrial wastes. The influence of compatibilizer concentration and blending time on the emulsifying effect, morphology, and mechanical properties of the resulting blends are analyzed. The compatibilization process effectiveness is assessed through the improvement in phase adhesion, emulsification and ductility of the compatibilized with respect to the physical blends. An increase of three times in ductility is achieved using very low compatibilizer concentrations (0.5–0.7 wt%). No appreciable detriment in yield strength or modulus is observed in these compatibilized blends. POLYM. ENG. SCI. 46:329–336, 2006. © 2006 Society of Plastics Engineers 相似文献
102.
Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst 总被引:2,自引:0,他引:2
Teresa Valds-Solís Patricia Valle-Vign Sonia lvarez Gregorio Marbn Antonio B. Fuertes 《Catalysis communications》2007,8(12):2037-2042
Spinel ferrite MnFe2O4 nanoparticles were synthesized by means of a nanocasting technique using a low-cost mesoporous silica gel as a hard template. The magnetic nanoparticles, of <10 nm diameter and with a surface area of around 100 m2/g, were tested as a heterogeneous Fenton catalyst for the decomposition of hydrogen peroxide under neutral and basic conditions. This catalyst shows a much higher activity than previous heterogeneous catalysts reported in the literature, which is mainly ascribed to its small particle size. Furthermore, the magnetic catalyst can be easily separated from the reaction medium by means of an external magnetic field. The effects of residual silica and the purity of the catalyst (hematite formation) on catalytic activity have been studied and correlated. The results obtained show this catalyst to be a suitable candidate for the removal of pollutants in wastewaters by means of the Fenton heterogeneous reaction. 相似文献
103.
Henri Berthiaux Antonio Guttierrez Lavin Julio Bueno De Las Heras Marisol Muñiz Alvarez 《加拿大化工杂志》2007,85(2):158-170
Despite of its general use in industry, particle sedimentation is still a not well understood unit operation. Hydrodynamics is complex in essence, mainly because the possible volumes are depending on the operating conditions, which in turn has consequences on the stability of the equipment in unsteady state conditions. 相似文献
104.
Eduardo Arias-Marín Luis F. Ramos De Valle Oliverio Rodríguez-Fernndez Jesús Rodríguez-Velzquez 《乙烯基与添加剂工艺杂志》1995,1(4):217-222
The effect of elemental sulfur (S8) and tetramethyl thiuram disulfide (TMTD) on the chemical crosslinking of PVC is studied. The tensile strength, elongation at break, and gel content of crosslinked and uncrosslinked PVC molded samples, cured at different times in hot air, are evaluated. It was found that crosslinking PVC with TMTD improves its mechanical properties, and adding S8 produces a slight improvement. Also, the S8 presence accelerated the PVC/TMTD crosslinking reaction when the crosslinking reaction was carried out under shear forces, but not when the curing was done in hot air, where the S8 retards the process. 相似文献
105.
Antonio G. González Ignacio A. Jiménez Mercedes P. Núñez Angel G. Ravelo Isabel L. Bazzocchi Orlando M. Muñoz Marcelino A. Aguilar 《Journal of chemical ecology》1994,20(4):823-830
Three new dihydro--agarofuran sesquiterpenes from two species ofMaytenus were isolated and their structures were elucidated by means of1H and13C NMR studies. The differences and similarities noted in the chemical content of the dihydro--agarofuran sesquiterpenes from the fourMaytenus species from Chile are in line with the taxonomic characterization of these species; their geographical distribution is also given. 相似文献
106.
Electronic Markets - Robots are being implemented in many frontline services, from waiter robots in restaurants to robotic concierges in hotels. A growing number of firms in hospitality and tourism... 相似文献
107.
Massa Lucas Barbosa Adriano Oliveira Krerley Vieira Thales 《Multimedia Tools and Applications》2021,80(4):5517-5537
Multimedia Tools and Applications - Measuring and analyzing the flow of customers in retail stores is essential for a retailer to better comprehend customers’ behavior and support... 相似文献
108.
de Almeida Jhony Luiz Comunello Eros Sobieranski Antonio da Rocha Fernandes Anita Maria Cardoso Gabriel Schade 《Pattern Analysis & Applications》2021,24(3):907-914
Pattern Analysis and Applications - Digital holography is an imaging process able to recreate three-dimensional representations of objects from recording pattern interference among distinct waves.... 相似文献
109.
Gabriele Pisano Antonio Bonati Gianni Royer Carfagni 《Journal of the American Ceramic Society》2021,104(1):383-403
The probability of breakage in service lifetime of heat-tempered glass panes contaminated by nickel sulfide inclusions is estimated with a multiscale micromechanically motivated statistical theory, which considers the effects of the heat soak test (HST). Short and long HSTs differently affect the phase transformation of NiS of diverse chemical composition, whose increase in volume can break the glass. The main hypothesis, corroborated by experiments, is that there is a lower limit for the size of NiS stones below which no crack can be initiated from the volumetric expansion. The catastrophic propagation of nucleated fractures in the long term is modeled through a rescaled critical stress intensity factor, which accounts for the subcritical crack propagation and the slow phase transformation of NiS. A parametric analysis evidences how the failure probability is strongly affected by these parameters, depending on the holding time in the HST. Tailored experimental activity is suggested for the proper calibration of the model. 相似文献
110.
Kaio C. S. Rodrigues Ivan I. K. Veloso Marcelo P. A. Ribeiro Antonio J. G. Cruz Alberto C. Badino 《加拿大化工杂志》2021,99(1):401-409
Fast, simple, accurate, and inexpensive methods for obtaining analyte concentration data are desirable in the industrial sector. In the present study, the use of Fourier transform mid‐infrared (FT‐MIR) spectroscopy, combined with partial least squares (PLS) regression, was investigated as a tool for real‐time monitoring of processes of ethanol absorption in glycols. Calibration was performed using simple synthetic samples containing ethanol, water, and monoethylene glycol (MEG) or diethylene glycol (DEG). The PLS models presented excellent performance, with correlation coefficients (R2) close to unity and root‐mean‐square errors of cross‐validation (RMSECV) and prediction (RMSEP) lower than 2% of the calibration data ranges for both analytes (ethanol and water) in both absorbents (MEG and DEG). The monitoring technique developed has potential to be applied in absorption processes and could also be used in other large‐scale unit operations, providing information in real time and enhancing process control. 相似文献