烷基烷氧基硅烷的合成方法及其在涂料中的应用

介绍了烷基烷氧基硅烷的合成方法(包括烷基的引入方法和烷氧基的形成方法)、近几年来在涂料中的应用及其结构与性能的关系。     

烃类在三甘醇和四甘醇中无限稀释活度系数的测定与关联

用气相色谱法分别测定了苯、甲苯、乙苯、正庚烷、正辛烷、正壬烷和正癸烷在三甘醇和四甘醇中的无限稀释活度系数 ,测定温度范围为 5 0～ 13 0℃。用修正的UNIFAC模型 (Dortmund)对上述不同温度下的无限稀释活度系数实验数据进行关联 ,得到了三甘醇和四甘醇与其它基团的相互作用参数 ,并将计算结果与实测值进行了比较。     

智能温湿度测控仪

本文提出一种利用MCS-51系列单片机实现温湿度自动检测和控制的智能仪表,文中对仪器的工作原理、硬件组成和软件设计作了较为详细的介绍。     

Synthesis of ultrafine LiCoO2 powders by the sol-gel method

Ultrafine high-temperature (HT) LiCoO₂ powders were synthesized by the sol-gel method using polyacrylic acid (PAA) as a chelating agent. The decomposition process of the gel precursor was examined to determine the crystallization temperature and the dependence of the physicochemical properties of HT-LiCoO₂ powders on the PAA quantity was extensively investigated. Polycrystalline HT-LiCoO₂ powders, composed of very uniformly sized ultrafine particulates with an average particle size of 30–50 nm and a specific surface area of 2.3–17 m²g^–1, could be obtained at the lower calcination temperature of 550 °C and the shorter calcination time of 1 h compared to the solid-state reaction.     

CAD OF MILLIMETER WAVE OSCILLATORS WITH THE FDHB TECHNIQUE

In this paper the modelling, analysis and optimization of millimeter wave oscillatorsare investigated by using the a frequency-domain harmonic balance technique (FDHB), where theexternal-circuit impedances looking outside from the active device are calculated with a combinedtechnique of modes expansion, Galerkin, and collocation methods. The optimization results arein agreement with the experimental ones, which show the reliability of the presented model andoptimization.     

Silicon carbide-toughened zirconia ceramics

Tetragonal zirconia polycrystalline (TZP) ceramics containing SiC reinforcement in the form of fine particles (nano-scale), particles (micro-scale), whiskers and platelets were synthesized by hot-pressing. The effects of morphology and grain size of SiC reinforcement on the strength and fracture toughness at room temperature were investigated. The addition of SiC (in whatever form) caused decreases in strength and toughness at room temperature with the exception of whisker-reinforced materials. Toughness fell off with increasing temperature, but nevertheless retained about one-half of the room-temperature value for that particular SiC reinforcement. However, the whisker- and particle-reinforced materials had higher K _lc values at high temperature than fine particle- or platelet-reinforced materials, with values in excess of 7 MPa m^1/2 at 1000 °C. The microstructure was examined for SiC whisker-reinforced/TZP materials by TEM and HREM, to examine the nature of the whisker/zirconia interface.     

The inhibition of DMBA-induced carcinogenesis by neoxanthin in hamster buccal pouch

Neoxanthin, a major carotenoid pigment of spinach, is found in the Chloroplast membrane and has an unknown function in plants. Neoxanthin inhibited the production of superoxide anions in an artificial xanthine and xanthine oxidase system and depressed DNA synthesis in methylcholanthrene (MCA)-initiated C3H10T1/2 fibroblasts. in two-stage carcinogenesis experiments, neoxanthin at 0.2 micrograms/0.2 ml inhibited the formation of tumors that were induced sequentially by 7,12-dimethylbenz[a]anthracene (DMBA) and 12-O-tetradecanoylphorbol-13-acetate (TPA) in the buccal pouch of Syrian Golden hamsters. To assess the ongoing process of carcinogenesis, the activity of ornithine decarboxylase (ODC), required for cell proliferation, was analyzed. Neoxanthin inhibited the activity of ODC when animals were treated with neoxanthin one hour before the application of TPA in two-stage carcinogenesis. However, neoxanthin did not inhibit ODC activity when animals were treated with neoxanthin one hour before the application of DMBA in two-stage carcinogenesis, and there was no subsequent tumor formation. In a short-term anti-initiation experiment, neoxanthin inhibited the covalent binding of isotope-labeled DMBA to DNA by 53%. These results indicate that neoxanthin inhibits the initiation stage and the promotion stage in two-stage carcinogenesis. This suggests that neoxanthin may act as a potential chemopreventive agent.     

国外特种反坦克武器的发展动向

本文着重将目前国外比较活跃的几种新型反垣克武器；软杀伤反坦克弹药，末敏弹，反坦克地雷以及智能反坦克子弹药的基本原理，作战效能，装备情况作一介绍，并对其发展方向进行了预测。     

Knowledge-based diagnosis of drill conditions

One major bottleneck in the automation of the drilling process by robots in the aerospace industry is drill condition monitoring. This paper describes a system approach to solve this problem through the advancement of new machine design, sensor instrumentation, metal-cutting research, and intelligent software development. All drill failures can be detected and distinguished: chisel edge wear, flank wear, crater wear, margin wear, corner wear, breakage, asymmetry, lip height difference, and chipping at lips. However, in the real manufacturing environment, different workpiece materials, drill size, drill geometry, drill material, cutting speed, feed rate, etc. will change the criteria for judging the drill condition. The knowledge base used for diagnosing the drill failures requires a huge data bank and prior exhaustive testing. A self-learning scheme is therefore introduced to the machine in order to acquire the threshold history needed for automatic diagnosis by using the same new tool under the same drilling conditions.     

Analysis of culture fluorescence by a fiber-optic sensor inNicotiana tabacum plant cell culture

The on-line sensing of viable cell weight in plant cell culture process is applied to analysis and control of process. The fiber-optic fluorescence sensor was constructed to measure the NADH-dependent fluorescence inNicotiana tabacum plant cell culture and the analysis of fluorescence signal was done to be correlated with the viable cell weight. The structured kinetic model for cell growth was proposed to estimate the theoretical viable cell weight. The dimensional analysis was proposed for the interpretation of fluorescence signal, in which the path length, the inner filter effect and the hydrodynamic conditions were considered as the key factors on fluorescence signal. The dimensional analysis and empirical correlation of fluorescence signal to viable cell weight was applied to the interpretation of the detected fluorescence signal during cultivation. The proposed interpretation of fluorescence signal using dimensional analysis was well correlated with the viable cell weight estimated by the structured kinetic model as well as by empirical correlation.