Crystallography of solid–liquid interface and evolution of texture during directional solidification of Tb0.3Dy0.7Fe1.95 alloy

The effect of growth texture on the magnetostriction of ternary Tb_0.3Dy_0.7Fe_1.95 was studied by conducting unidirectional solidification experiments using a zoning set-up. Detailed texture evolutions were studied using X-ray diffraction on samples obtained by varying growth rates from 18 to 72 cm/h, under a temperature gradient of 100 °C/cm. The estimated texture co-efficient and pole figures of the samples indicate that during the onset of the solidification, <110> and <331>/‘rotated <110>’ texture components nucleate and grow in all the samples. However, as the solidification progresses, <112> texture component becomes dominant at higher growth rate. This results in an improvement of magnetostriction from 1000 to 1300 microstrains for samples grown at growth rates of 18 and 72 cm/h respectively. The transition of preferred growth direction occurs through intermediate orientations <123>. An attempt has been made in this paper to explain the occurrence of different growth texture by considering the stability of growing interface, its planar packing fraction and atomic stacking sequence of several low index planes.     

The effect of ternary addition of silicon on the structure and microstructure of rapidly solidified equiatomic TiNi alloys

The influence of a small amount of silicon (up to 6 at %) on the structure and microstructure of rapidly solidified equiatomic TiNi alloys is reported. It is shown that a small amount of silicon suppresses the B2 TiNi formation and promotes a competitive nucleation of Ti2Ni phase. Further additions of silicon promote the formation of glass. The behaviour of the ternary replacement of both titanium and nickel by silicon has been studied. It is shown that replacement of titanium increases the tendency for the formation of silicide phases while the latter is absent when silicon replaces the nickel atoms. This revised version was published online in November 2006 with corrections to the Cover Date.     

The effects of reverse micelles on the reaction mechanism of alpha-chymotrypsin

Reverse micelles were employed to test the accuracy of the widely accepted mechanism for alpha-chymotrypsin in a highly structured aqueous system similar to intracellular conditions. Results yielded from spectrophotometrical assays of the alpha-chymotrypsin catalyzed hydrolysis of both p-nitrophenyl acetate (p-NPA) and p-nitrophenyl trimethylacetate (p-NPTA) were kinetically analyzed to determine constants typical of the proposed mechanistic model. This was accomplished through the establishment of a control, i.e. the well studied buffer system, for comparison between the reverse micellular environment and a bulk aqueous solution. Control group results yielded kinetic constants in favor of the proposed mechanism (Km = 1.55 x 10(-5) +/- 1.40 x 10(-6) M for p-NPA and a Km = 4.97 x 10(-6) +/- 2.29 x 10(-7) M, Km(app) = 4.92 x 10(-6) +/- 2.33 x 10(-8) M, k2 = 4.34 x 10(-3) +/- 1.31 x 10(-3), k(cat) = 1.96 x 10(-3) +/- 2.47 x 10(-4), and Ks = 1.60 x 10(-5) +/- 4.61 x 10(-6) M for p-NPTA). In contrast, similar reactions of the enzyme in a reverse micellular system produced kinetic constants atypical to that representative of the textbook mechanism. (Km = 1.59 x 10(-4) +/- 2.70 x 10(-5) M, Ks = -8.67 x 10(-5) +/- 4.46 x 10(-5) M and Km(app) = -4.80 x 10(-5) +/- 7.05 x 10(-5) M for p-NPA and Km = 1.95 x 10(-4) +/- 9.28 x 10(-5) M, Km(app) = -1.79 x 10(-4) +/- 2.36 x 10(-5) M, and Ks = -3.95 x 10(-4) +/- 1.18 x 10(-4) M for p-NPTA). In addition to negative kinetic constants, alpha-chymotrypsin seemed to display characteristics indicative of super-activity and a hysteretic response. Overall, the widely accepted mechanism for alpha-chymotrypsin appeared to fail within the confines of reverse micelles, due to the direct influence of the system's highly structured form.     

Local oscillator chain for 1.55 to 1.75THz with 100-/spl mu/W peak power

We report on the design and performance of a fix-tuned /spl times/2/spl times/3/spl times/3 frequency multiplier chain that covers 1.55-1.75THz. The chain is nominally pumped with 100mW at W-band. At 120K the measured output power is larger than 4/spl mu/W across the band with a peak power of 100/spl mu/W at 1.665THz. A similar chain operated at room temperature produced a peak power of 21/spl mu/W. These power levels now make it possible to deploy multipixel heterodyne imaging arrays in this frequency range.     

Performance of neural networks for predicting yarn properties using principal component analysis

In recent years, neural networks have been used as a tool for modeling an industrial process. An improvement in their performance may be expected either by divining more efficient training algorithms or by intelligently manipulating the data set. The second method is examined. The problem chosen is one of predicting the properties of cotton yarn from the fiber properties. When the input data are known to correlate with each other, principal component analysis can be used to improve the performance of neural networks. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1746–1751, 2004     

Time of flight (TOF) spectrometer for accurate measurement of mass and angular distribution of fission fragments in heavy ion induced fission reactions

The performance of a dual time of flight (TOF) spectrometer using two 24 cm×10 cm area X–Y position sensitive Multi-Wire Proportional Counters (MWPC) is reported. Good separation of compound nuclear fission channel from elastic, quasi-elastic and non-compound fission channels have been achieved. Time calibration of the spectrometer using a technique, dependent on the detector independence of the mass or kinetic energy distributions gave a three times better mass resolutions compared to the conventional calibration technique using elastically scattered projectiles in a heavy ion induced fission reaction. Detail experimental methods in determining fission fragment mass and angular distribution have been presented and discussed.     

Interaction of relativistic electrons with ultrashort laser pulses:generation of femtosecond X-rays and microprobing of electron beams

The interaction of relativistic electrons with terawatt femtosecond laser pulses is reviewed with emphasis on how the scattering process can be used as a source of ultrashort X-ray pulses and as a time-resolved diagnostic for measuring transverse and longitudinal phase space distributions of an electron beam with microns spatial and subpicosecond temporal resolution. Recent experimental results are presented in which 90° Thomson scattering was utilized to generate 300 fs duration pulses of X-rays with peak energy of 30 keV. It is shown that, through analysis of the scattered X-ray beam properties, transverse and longitudinal distributions of the electron beam can be obtained     

Optical Measurements of SuperSpec: A Millimeter-Wave On-Chip Spectrometer

SuperSpec is a novel on-chip spectrometer we are developing for (sub)millimeter wavelength astronomy. Our approach utilizes a filterbank of moderate resolution ( \(R \sim 500{)}\) channels, coupled to lumped element kinetic inductance detectors (KIDs), all integrated onto a single silicon chip. The channels are half-wave resonators formed by lithographically depositing segments of superconducting transmission line, and the KIDs are titanium nitride resonators. Here we present optical measurements of a first generation prototype, operating in the 180–280 GHz frequency range. We have used a coherent source to measure the spectral profiles of 17 channels, which achieve linewidths corresponding to quality factors as high as \(Q_\mathrm {filt} = 700{,}\) consistent with the designed values plus additional dissipation characterized by \(Q_i \approx 1440{.}\) We have also used a Fourier Transform Spectrometer to characterize the spectral purity of all 72 channels on the chip, and measure typical out of band responses \({\sim }30\) dB below the peak response.     

Design and Performance of SuperSpec: An On-Chip,KID-Based,mm-Wavelength Spectrometer

SuperSpec is an ultra-compact spectrometer-on-a-chip for mm and submm wavelength astronomy. Its very small size, wide spectral bandwidth, and highly multiplexed detector readout will enable construction of powerful multi-object spectrometers for observations of galaxies at high redshift. SuperSpec is a filter bank with planar, lithographed, superconducting transmission line resonator filters and lumped-element kinetic inductance detectors made from Titanium Nitride. We have built an 81 detector prototype that operates in the 195–310 GHz band. The prototype has a wide-band metal feed horn with a transition to microstrip that feeds the filter bank. The prototype has demonstrated optical filter bank channels with a range of resolving powers from 300 to 700, measured fractional frequency noise of \(10^{-17} \mathrm{Hz}^{-1}\) at \(1\,\) Hz.