On-line H NMR spectroscopic investigation of hydrogen bonding in supercritical and near critical CO2–methanol up to 35 MPa and 403 K

On-line NMR spectroscopy can beneficially be applied to studies of supercritical and near-critical fluids as an alternative to optical spectroscopy. Up to now high pressure NMR experiments are predominantly accomplished using custom made NMR batch reactors. The authors present a novel high pressure cell with displacement plunger for on-line NMR experiments on compressible fluids which can be used in conjunction with commercially available SCF NMR flow probes. The on-line technique offers advantages compared to stopped flow techniques such as enhanced control of mixture composition and reaction parameters as well as the facility of engagement into the reaction. The new apparatus is used for NMR studies on hydrogen bonding of methanol in near critical and supercritical carbon dioxide up to 403 K and 35 MPa for which data on the chemical shift of the hydroxyl group and methyl group are reported and interpreted.     

Internalization of interpersonal process in time-limited dynamic psychotherapy.

[Correction Notice: An erratum for this article was reported in Vol 31(3) of Psychotherapy: Theory, Research, Practice, Training (see record 2009-17141-002). This article contained, as Figure 1, an SASB model. The authorship and copyrights for the model were not acknowledged. The following acknowledgement should have been included: "Adapted from Benjamin (1984). Principles of Prediction using Structural Analysis of Social Behavior (SASB). In R. A. Zucker, J. Aronoff, and A. J. Rabin (Eds.), Personality and the Prediction of Behavior (pp. 121- 174). New York: Academic." An apology is offered to the author, Dr. Lorna Smith Benjamin. The particular version used in the article was developed in collaboration with Clinton W. McLemore.] Investigated the internalization of positive aspects of therapist–patient (TP) interactions among 70 patients and their 16 therapists who participated in a 5-yr study (H. H. Strupp et al, unpublished) of time-limited dynamic psychotherapy. Patients sought help for anxiety, depression, or other problems with a clear interpersonal component and qualified for an Axis I or Axis II diagnosis on the Diagnostic and Statistical Manual of Mental Disorders-III (DSM-III). Instruments included the Structural Analysis of Social Behavior and outcome measures of depression, anxiety, and psychological functioning. Patients' intrapsychic functioning became more similar to interpersonal activity in the TP relationship over the course of psychotherapy. Intrapsychic movement toward interpersonal activity in the TP relationship was associated with positive outcome on measures of depression, anxiety, and on independent clinician ratings of patient psychological functioning. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Impurity Distribution Behavior in Caprolactam Extraction with Environmentally Benign Mixed Solvents

In a previous study a solvent mixture of heptane containing 40 mass % heptanol was selected as an alternative in the industrial extraction of caprolactam to replace benzene, toluene, or chlorinated hydrocarbons. This work reports the equilibrium distribution ratio of caprolactam and four model impurities of organic nature, namely, cyclohexanone, aniline, n‐methylcaprolactam, and cyclohexane‐carboxamide, comparing the mixed solvents with toluene as a reference. The resulting phase equilibria were interpreted using the equilibrium stage model. Based on these calculations it was found that, compared to toluene, the co‐extracted fraction of cyclohexanone and aniline was higher, that of n‐methylcaprolactam was comparable, and that of cyclohexane‐carboxamide was lower using the mixed solvent. Overall, the mixed solvent reduced the fraction of co‐extracted impurities by almost 10 %.     

Learned stimulation in space and motion perception.

Argues that in the perception of distance, depth, and visual motion, a single property is often represented by 2 or more stimuli. Two instances of such redundant stimulation are discussed: (a) the various stimuli that represent visual motion and (b) the 2 forms of stimulation by which binocular parallax evokes stereoscopic depth perception. In the case of visual motion, simultaneous operation of redundant stimulation has raised questions concerning the basis of experienced motion and the conditions under which different motion processes are combined. Experiments are described that suggest that some redundant stimuli owe their existence to simple associative learning. Evidence is reviewed that shows that binocular parallax causes stereoscopic depth by means of 2 different perceptual processes. (20 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Formation of pearlitic banded structures in ferritic-pearlitic steels

The conditions for ferrite and pearlite banding in strip and plate made of structural steels were investigated. Factors found to influence the formation of banded structures were the cooling rate during the γ/α-transformation, the former austenite grain size, and the work-hardened condition of the former austenite. Analyses with the aid of an electron beam microprobe made it possible to demonstrate that the carbon-rich bands correspond locally with banded manganese enrichments, yet that they do not form before the course of the γ/α-transformation as a result of secondary segregation. It was possible to explain the mechanism of action of the influencing factors on the basis of this model.     

Schätzung der modalen Parameter unter Berücksichtigung systematischer Fehler der Frequenzgänge

Zusammenfassung Aufgrund von Eingangs- und Ausgangsst?rungen des Me?systems sowie einer endlichen Frequenzaufl?sung treten stets systematische (Bias-) und zuf?llige Fehler bei gemessenen Frequenzg?ngen und deren Varianzen auf. Auf solchen Frequenzg?ngen und Varianzen beruhende Sch?tzungen der modalen Parameter sind damit ebenfalls systematisch verzerrt. Um die Genauigkeit und Sicherheit der modalen Parameter zu erh?hen, wird ein Sch?tzverfahren vorgestellt, in dem der Einflu? der Biasfehler auf die Sch?tzung n?herungsweise in einer diagonalen Wichtungsmatrix berücksichtigt wird. Es wird gezeigt, da? die systematischen Fehler Einflu? auf die Absch?tzung der statistischen Sicherheit der modalen Parameter haben. Anhand zweier Beispiele wird die Wirksamkeit des Sch?tzverfahrens demonstriert. Prof. Dr.-Ing. Dr.-Ing. E.h.H.K. T?nshoff: Dipl.-Ing.Z. Liu, Institut für Fertigungstechnik und Spanende Werkzeugmaschinen (IFW), Universit?t Hannover.     

Infra-red and Raman spectroscopic study on the thermal stability and high temperature transformation of hydroazafullerene C59HN

Hydroazafullerene C₅₉HN was studied by vibrational infra-red and Raman spectroscopy and its thermal stability was examined. Fingerprints modes were identified and unambiguously differentiate it from bisazafullerene. At 700 K full transformation to bisazafullerene occurred, while an intermediate metastable phase was identified at 540 K showing different spectra where the splitting of most of the lines is strongly reduced.     

Role Models for Radical Innovations in Times of Open Innovation

In this paper, we study the influence of innovator roles in highly innovative ventures. In order to obtain a differentiated picture we take into account the degree of innovativeness as a moderating variable. To test our hypotheses we use a sample of 146 highly innovative new product development projects. We choose a rigorous sampling design and apply state‐of‐the‐art measures for the degree of innovativeness. Furthermore, we apply multi‐trait‐multi‐method methodology (MTMM) to enhance the validity of our study. The results show that innovator roles have a strong influence on innovation success but these influences are positively and negatively moderated by innovativeness. The moderating influences depend on the type of innovativeness. Remarkably, with increasing technological innovativeness innovator roles which create inter‐organizational links with the outside world appear to be more important than intra‐organizational linker roles, and support from high‐ranked organizational members turns out to have a significant negative effect on project success with higher degrees of technological innovativeness. Possible explanations for these findings are discussed and consequences for innovation research and innovation management are shown.     

Comparative study of self-assembling of multilayers using reactive sputter deposition and mass selective ion beam deposition

While experimenting with the growth of metal-containing amorphous carbon (a-c:Me) thin films using two different growth processes, self-assembled multilayered structures were observed. One of the processes is a reactive magnetron sputter deposition process. The other process is a mass selective ion beam deposition process. Despite of the differences in the growth method and the growth condition, self-assembled multilayered thin films, consisting of alternating dark layer and bright layer, were obtained in both processes. Based on the consideration of energy for atomic diffusion in the thin films, the growth mechanism is discussed.