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21.
22.
In the present work, the chemical characterization of the oils obtained from liquefaction of different coals with sugar cane bagasse oil and also from the liquefaction of coal with monoethanolamine are presented. Characterization of the oil samples was done with the add of spectroscopic and chromatographic techniques, including UV-vis, FTIR, NMR, preparative liquid chromatography (PLC) and high resolution gas chromatography (HRGC). 相似文献
23.
Reda Karoum Antonio de Lucas-Consuegra Fernando Dorado Jose Luis Valverde Alain Billard Philippe Vernoux 《Journal of Applied Electrochemistry》2008,38(8):1083-1088
The electrochemical promotion of catalysis (EPOC) of propene combustion was investigated using Pt sputtered thin film on an
O2− conductor, 8 mol% Y2O3-stabilized-ZrO2 (YSZ). In order to separate the influence of the thermal migration of the O2− oxide ions from the electrolyte to the catalyst surface and the impact of an electrical polarization on the catalytic activity,
several light-off experiments (cool down and heat up procedures) were successively performed under different polarizations,
i.e. OCV, +2 and −2 V. These experiments have clearly shown that the presence of O2− (thermally or electrochemically induced) inhibits the catalytic activity of the platinum for the propene deep oxidation.
These results demonstrate the importance to define a normalized rate enhancement ratio, ρ
n
, from a reference value of the catalytic rate corresponding to a Pt surface state free of O2− ions. 相似文献
24.
Anuradh Gunawardena Sandun Fernando Filip To 《International journal of molecular sciences》2008,9(10):1893-1907
Saccharomyces cerevisiae present in common Baker’s yeast was used in a microbial fuel cell in which glucose was the carbon source. Methylene blue was used as the electronophore in the anode compartment, while potassium ferricyanide and methylene blue were tested as electron acceptors in the cathode compartment. Microbes in a mediator-free environment were used as the control. The experiment was performed in both open and closed circuit configurations under different loads ranging from 100 kΩ to 400Ω. The eukaryotic S. cerevisiae-based fuel cell showed improved performance when methylene blue and ferricyanide were used as electron mediators, rendering a maximum power generation of 146.71±7.7 mW/m3. The fuel cell generated a maximum open circuit voltage of 383.6±1.5 mV and recorded a maximum efficiency of 28±1.8 % under 100 kΩ of external load. 相似文献
25.
26.
R. L. Keith A. J. Gandolfi L. C. McIntyre Jr. M. D. Ashbaugh Q. Fernando 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》1997,130(1-4):358-361
Industrial wastes consigned to disposal sites frequently contain substantial amounts of heavy metals. We have successfully applied proton induced X-ray emission analysis (PIXE) in the conduct of heavy metal (Hg, Cd, Cr, As) toxicity studies using precision cut rabbit renal cortical slices. The large beam diameter (4000 μm) of the proton macroprobe at The University of Arizona Ion Beam Analysis facility allowed an overall concentration of the metal(s) of interest in the samples to be determined, but lacked the ability to resolve point concentrations in the tissue. The ability to locate these areas has now been made available to us with the addition of a rastering microprobe (μ-PIXE) to the facility. Studies now being conducted in our laboratory using this micro-technique include analysis of renal tissue taken from rabbits injected intraperitoneally with HgCl2, K2Cr2O7, and NaAsO2. The small beam size (3 μm) and the ability to raster this beam over areas of up to 125 μm × 125 μm has allowed regional mapping of endogenous and non-endogenous metal concentrations and revealed trends in heavy metal deposition in in vivo treated renal tissue, significantly increasing the amount of information obtained from these animal studies using PIXE alone. The combination of small beam size, high resolution, and multi-element detection makes μ-PIXE a powerful tool for investigating the impact of non-endogenous metals on the kidney. 相似文献
27.
Suely P. Freitas Fernando C. Da Silva Regina C. A. Lago & Raad Y. Qassim 《International Journal of Food Science & Technology》1996,31(4):319-325
Shear rate vs. shear stress data were obtained on avocado pulp in water emulsions using a concentric cylinder rheometer and fitted to a power law model. Dilution, as volume fraction of water, had a pronounced effect on the apparent viscosity of the pulp emulsions and the Richardson equation, (ηR = exp.( a φ) for the emulsion viscosity fitted the data well. A mean slope coefficient, a , of 4.57 can be used as a first approximation. Enzymatic treatment (40°C, 1 h), is slightly more effective than thermal treatment (65°C, 1 h), in reducing the initial apparent viscosity of the pulp-water emulsions 相似文献
28.
Image segmentation towards new image representation methods 总被引:1,自引:0,他引:1
Diogo Cortez Paulo Nunes Manuel Menezes de Sequeira Fernando Pereira 《Signal Processing: Image Communication》1995,6(6):485-498
Very low bit-rate video coding has recently become one of the most important areas of image communication and a large variety of applications have already been identified. Since conventional approaches are reaching a saturation point, in terms of coding efficiency, a new generation of video coding techniques, aiming at a deeper “understanding” of the image, is being studied. In this context, image analysis, particularly the identification of objects or regions in images (segmentation), is a very important step. This paper describes a segmentation algorithm based on split and merge. Images are first simplified using mathematical morphology operators, which eliminate perceptually less relevant details. The simplified image is then split according to a quad tree structure and the resulting regions are finally merged in three steps: merge, elimination of small regions and control of the number of regions. 相似文献
29.
Dr Fernando Leal 《AI & Society》1995,9(1):29-42
This paper first illustrates what kind of ethical issues arise from the new information, communication and automation technology. It then argues that we may embrace the popular idea that technology is ethically neutral or even ambivalent without having to close our eyes to those issues and in fact, that the ethical neutrality of technology makes them all the more urgent. Finally, it suggests that the widely ignored fact of normal responsible behaviour offers a new and fruitful starting point for any future thinking about such issues. 相似文献
30.
Nowadays, cities are the most relevant type of human settlement and their population has been endlessly growing for decades. At the same time, we are witnessing an explosion of digital data that capture many different aspects and details of city life. This allows detecting human mobility patterns in urban areas with more detail than ever before. In this context, based on the fusion of mobility data from different and heterogeneous sources, such as public transport, transport‐network connectivity and Online Social Networks, this study puts forward a novel approach to uncover the actual land use of a city. Unlike previous solutions, our work avoids a time‐invariant approach and it considers the temporal factor based on the assumption that urban areas are not used by citizens all the time in the same manner. We have tested our solution in two different cities showing high accuracy rates. 相似文献