Polymeric organogel as an effective approach for eradication of heavy metal ions As,Pb, Cd,and Cr from the surface of groundwater through adsorption stratagem

Excess metal pollutant has affected and caused serious havoc in the lives of terrestrial as well as aquatic beings. The core of this work revolves around eradicating highly toxic heavy metal ions from underground water systems using a cost-effective, high removal efficiency polymeric adsorbent capable of adsorbing and removing ionic metals whose backbone is composed of a bio-degradable polymer, polyvinyl alcohol. The obtained adsorbent was characterized using FT-IR, HNMR, and P-XRD. Morphological studies were carried out using SEM. Detection and adsorption of metal ions were performed using SEM–EDX and AAS; wherein the adsorbent was found to remove nearly 80% of arsenic ions, 70.5% and 70.7% for lead and chromium ions while 60.7% for cadmium ions, respectively. Further, the kinetics of adsorption along with intraparticle diffusion studies were also performed to determine the mechanism alongside observing the isothermal influence of the sorbent. The adsorption capacity was seen to be highest in arsenic at around 570.42 mg g⁻¹ thus acting as a potential and effective adsorbent for the removal of heavy metal ions from groundwater.     

Activity of a melimine derived peptide Mel4 against Stenotrophomonas,Delftia, Elizabethkingia,Burkholderia and biocompatibility as a contact lens coating

Purpose

To determine the antimicrobial activity of the melimine derived peptide Mel4 against Delftia, Stenotrophomonas, Elizabethkingia, Burkholderia and to investigate biocompatibility of Mel4 as an antimicrobial coating on contact lenses in animals and humans.

Ratcheting Behavior of a Non-conventional Stainless Steel and Associated Microstructural Variations

Ratcheting fatigue behavior of a non-conventional stainless steel X12CrMnNiN17-7-5 has been investigated with varying combinations of mean stress (σ_m) and stress amplitude (σ_a) at room temperature using a servo-hydraulic universal testing machine. X-ray diffraction profile analysis has been carried out for assessing possible martensitic phase transformation in the steel subjected to ratcheting deformation. The results indicate that ratcheting strain as well as volume fraction of martensite increases with increasing σ_m and/or σ_a; the phenomenon of strain accumulation is considered to be governed by the associated mechanics of cyclic loading, increased plastic damage as well as martensitic transformation. A correlation between strain produced by ratcheting deformation and martensitic transformation has been established.     

Fe-Zn Alloy Coating on Galvannealed (GA) Steel Sheet to Improve Product Qualities

Galvannealed steel sheets (GA) have become the mainstream steel sheet for automobile applications because of their superior corrosion resistance, paintability, and weldability. To impart specific properties, different coatings on GA steel sheet were reported to improve properties further. In this context, we have developed an electroplating process (flash coating) for bright and adherent Fe-Zn alloy coating on GA steel sheet to enhance performances such as weldability, frictional behavior, phosphatability, and defect coverage. A comparative study with bare GA steel sheet was carried out for better elastration. The electroplating time was reduced below 10 s for practical applicability in an industrial coating line by modulating the bath composition. Electroplating was performed at current density of 200-500 A/m² which yielded with higher cathode current efficiency of 85-95%. The performance results show that Fe-10 wt.% Zn-coated GA steel sheet (coating time 7 s) has better spot weldability, lower dynamic coefficient of friction (0.06-0.07 in lubrication), and better corrosion resistance compared to bare GA steel sheet. Uniform phosphate coating with globular crystal size of 2-5 µm was obtained on Fe-Zn flash-coated GA steel sheet. Hopeite was the main phosphate compound (77.9 wt.%) identified along with spencerite (13.6 wt.%) and phosphophyllite (8.5 wt.%).     

Pass-by-pass stress evolution in multipass welds

In multipass welding, each successive thermal cycle will introduce local melting, solid state phase transformations, grain growth, grain refinement, recrystallisation and recovery, all of which lead to a complicated stress state. Most stress measurements performed on multipass welded components represent the final residual stress state. Information concerning stress evolution on a pass-by-pass basis is difficult to find. In this investigation, six pass welds were made on high strength quenched and tempered steel sections, and depth resolved strain measurements in two orthogonal directions were carried out after each weld pass using energy dispersive synchrotron X-ray diffraction. The residual stresses were calculated using biaxial Hooke’s law. A thermal–metallurgical–mechanical welding model was constructed and validated with temperature and pass-by-pass stress measurements, which improves the reliability of the model. Cross-sectional stress distributions are presented after each pass, revealing the weld stress development in multipass welds.     

Will capacity building training interventions given to street food vendors give us safer food?: A cross-sectional study from India

Successful food hygiene training and the consent of safe food handling practices learnt during training are critical elements in the control of food-borne illnesses throughout the world. It is true for food handlers and vendors belonging to all sectors. But, it is all the more urgent for street vendors because they are more exposed to environmental hazards and are predominantly from much weaker socio-economic backgrounds and yet cater to the general mass. Using a cross-sectional study design a sample of 80 street food vendors were selected and provided with training to evaluate the existing Knowledge, Attitude and Practice (KAP) regarding food safety and hygiene and the change of the same after training interventions. Responses regarding KAP on food safety and hygiene before and after training revealed that there was a significant change in their perception to food safety knowledge and also practices. The knowledge level of the food vendors increased from an average 24.35%–66.2% after training interventions. The overall performance rating of full adoption of good hygiene practices by the vendors ranged from 37.5% to 50.8% in post-training period.     

Understanding the swelling of poly (N-isopropyl acrylamide) gels through the study of free volume hole size distributions using positron annihilation spectroscopy

Poly (N-isopropyl acrylamide) gels were prepared by UV polymerization with different degree of cross-linking in different solvents. Ethylene glycol dimethacrylate and penta-erythritol tetra-acrylate were used as cross-linkers, and methanol and dimethyl formamide (DMF) were used as solvents for gel preparation. The free volume fraction and hole size distribution in the dry gels were measured using positron annihilation lifetime spectroscopy. The equilibrium swelling of the samples in water was measured at room temperature. Both swelling properties of gels and the free volume distributions were seen to be sensitive to the amount, type, and functionality of cross-linkers as well as solvent medium used for synthesis. The gels prepared in DMF showed poor swelling properties than those prepared in methanol. The mean free volume hole size was higher while the variance of hole size distribution was smaller in the gels prepared in DMF medium compared to those prepared in methanol. The free volume fractions in the gels were found to be inversely correlated to the extent of equilibrium swelling for similar chemical compositions. The possible reasons are discussed.     

Photoluminescence and Raman Spectroscopy of Polycrystalline ZnO Nanofibers Deposited by Electrospinning

The technique of electrospinning offers the advantage of growing nanowires in bulk quantities in comparison with traditional methods. We report optical studies of polycrystalline zinc oxide (ZnO) nanofibers (∼100 nm thick and 5 μm long) deposited by electrospinning. Photoluminescence from the nanofibers shows a near-ultraviolet (near-UV) peak corresponding to near-band-edge emission and a strong broad peak in the visible region from oxygen antisite and interstitial defects. Temperature-dependent photoluminescence spectroscopy reveals that different carrier recombination mechanisms are dominant at low temperature. Our Raman spectroscopy results demonstrate that characterization of the quasimodes of longitudinal optical (LO) and transverse optical (TO) phonons present in an ensemble of polycrystalline nanofibers tilted at various angles in addition to the dominant E ₂(high) mode provides a promising technique for assessing the quality of such randomly oriented nanowires.