Nanocellulose-Carboxymethylcellulose Electrolyte for Stable,High-Rate Zinc-Ion Batteries

Aqueous Zn ion batteries (ZIBs) are one of the most promising battery chemistries for grid-scale renewable energy storage. However, their application is limited by issues such as Zn dendrite formation and undesirable side reactions that can occur in the presence of excess free water molecules and ions. In this study, a nanocellulose-carboxymethylcellulose (CMC) hydrogel electrolyte is demonstrated that features stable cycling performance and high Zn²⁺ conductivity (26 mS cm⁻¹), which is attributed to the material's strong mechanical strength (≈70 MPa) and water-bonding ability. With this electrolyte, the Zn-metal anode shows exceptional cycling stability at an ultra-high rate, with the ability to sustain a current density as high as 80 mA cm⁻² for more than 3500 cycles and a cumulative capacity of 17.6 Ah cm⁻² (40 mA cm⁻²). Additionally, side reactions, such as hydrogen evolution and surface passivation, are substantially reduced due to the strong water-bonding capacity of the CMC. Full Zn||MnO₂ batteries fabricated with this electrolyte demonstrate excellent high-rate performance and long-term cycling stability (>500 cycles at 8C). These results suggest the cellulose-CMC electrolyte as a promising low-cost, easy-to-fabricate, and sustainable aqueous-based electrolyte for ZIBs with excellent electrochemical performance that can help pave the way toward grid-scale energy storage for renewable energy sources.     

A comparative study of the use of colorimetric assays in the assessment of biocompatibility

A panel of colorimetric assays was assessed for sensitivity, reproducibility, and performance in the investigation of the biocompatibility of a representative range of orthopædic biomaterials, using a commercially available human osteosarcoma-derived cell line. The MTT assay was the most sensitive, with a detection limit of 4×10² cells per well against background, while the NR assay was the least sensitive, with no colour change until the cell density reached 2×10⁴ per well. All of the assays investigated showed a highly significant edge effect when within-plate reproducibility was examined; between-plate reproducibility was good for all assays except the MTT assay. When the assays were tested on cells adherent on biomaterials, there was a wide variation in the results obtained; in particular, the MTS assay showed poor reproducibility in the presence of materials. The MTT and BrdU assays both showed sufficient precision to detect cells on two of the materials studied. The study demonstrates that colorimetric assays are potentially useful in biocompatibility assessment but must be fully validated for the application chosen.     

Predictors of user perceptions of web recommender systems: How the basis for generating experience and search product recommendations affects user responses

One critical question suggested by Web 2.0 is as follows: When is it better to leverage the knowledge of other users vs. rely on the product characteristic-based metrics for online product recommenders? Three recent and notable changes of recommender systems have been as follows: (1) a shift from characteristic-based recommendation algorithms to social-based recommendation algorithms; (2) an increase in the number of dimensions on which algorithms are based; and (3) availability of products that cannot be examined for quality before purchase. The combination of these elements is affecting users’ perceptions and attitudes regarding recommender systems and the products recommended by them, but the psychological effects of these trends remain unexplored. The current study empirically examines the effects of these elements, using a 2 (recommendation approach: content-based vs. collaborative-based, within)×2 (dimensions used to generate recommendations: 6 vs. 30, between)×2 (product type: experience products (fragrances) vs. search products (rugs), between) Web-based study (N=80). Participants were told that they would use two recommender systems distinguished by recommendation approach (in fact, the recommendations were identical). There were no substantive main effects, but all three variables exhibited two-way interactions, indicating that design strategies must be grounded in a multi-dimensional understanding of these variables. The implications of this research for the psychology and design of recommender systems are presented.     

Microfluidic immobilization and subcellular imaging of developing <Emphasis Type="Italic">Caenorhabditis elegans</Emphasis>

Caenorhabditis elegans has been an essential model organism in the fields of developmental biology, neuroscience, and aging. However, these areas have been limited by our ability to visualize and track individual C. elegans worms, especially at the subcellular scale, over the course of their lifetime. Here we present a microfluidic device to culture individual C. elegans in parallel throughout post-embryonic development. The device allows for periodic mechanical immobilization of the worm, enabling 3D imaging at subcellular precision. The immobilization is sufficient to enable fluorescence recovery after photobleaching (FRAP) measurements on organelles and other substructures within the same specific cells throughout larval development, without the use of chemical anesthetics. Using this device, we measure FRAP recovery of two nucleolar proteins in specific intestinal cells within the same worms during larval development. We show that these proteins exhibit different fluorescence recovery as the worm grows, suggesting differential protein interactions during development. We anticipate that this device will help expand the possible uses of C. elegans as a model organism, enabling its use in addressing fundamental questions at the subcellular scale.     

Biochemical and behavioral evidence foe hybridization between fire ants,Solenopsis invicta andSolenopsis richteri (Hymenoptera: Formicidae)

Behavioral and biochemical evidence is presented for hybridization between the fire ants,Solenopsis richteri andS. invicta. The response of the two species to extracts of their trail pheromones presented as a point source is clearly species-specific; however, hybrid workers responded to parental Dufour's gland extracts and parental workers responded to Dufour's gland extracts of the hybrid. The behavioral evidence for hybridization was confirmed by gas Chromatograph comparison of the Dufour's gland extracts of the three fire ant forms, which showed a pattern for the hybrid that was intermediate to the two parental species.     

Distributed Job Scheduling in Rings

We give a distributed approximation algorithm for job scheduling in a ring architecture. In contrast to many other parallel scheduling models, the model we consider captures the influence of the underlying communications network by specifying that task migration from one processor to another takes time proportional to the distance between those two processors in the network. As a result, our algorithm must balance computational load and communication time. The algorithm is simple, requires no global control, and yields schedules of length at most 4.22 times optimal. We also give a lower bound on the performance of any distributed algorithm and the results of simulation experiments which suggest better performance than does our worst-case analysis.     

The averaged periodogram estimator for a power law in coherency

We prove the consistency of the averaged periodogram estimator (APE) in two new cases. First, we prove that the APE is consistent for negative memory parameters, after suitable tapering. Second, we prove that the APE is consistent for a power law in the cross‐spectrum and therefore for a power law in the coherency, provided that sufficiently many frequencies are used in estimation. Simulation evidence suggests that the lower bound on the number of frequencies is a necessary condition for consistency. For a Taylor series approximation to the estimator of the power law in the cross‐spectrum, we consider the rate of convergence and obtain a central limit theorem under suitable regularity conditions.     

Progressively Censored Samples in Life Testing

In life and dosage-response studies, progressively censored samples arise when at various stages of an experiment, some though not all of the surviving sample specimens are eliminated from further observation. The sample specimens remaining after each stage of censoring are continued under observation until failure or until a subsequent stage of censoring. In this paper maximum likelihood estimators of the distribution parameters are derived for the normal, and for the exponential distribution when samples are progressively censored.