Treatment of Chlorophenols by UV-Based Processes: Correlation of Oxidation By-Products, Wastewater Parameters, and Toxicity

The aim of the study was to evaluate the toxicity and biodegradability of para-chlorophenol (p-CP) model wastewater when treated by UV and UV/H2O2 processes. We investigated the correlations between the toxicity and the concentration of p-CP and its oxidation by-products, as well as other parameters—summarizing characteristics which potentially indicate hazardous water components, e.g., AOX (adsorbable organic halides), TOC (total organic carbon), and COD and BOD5 (chemical and biochemical oxygen demand). Biodegradability is estimated by the BOD5/COD ratio. The toxic effects were investigated on luminescent bacteria Vibrio fischeri, determining the EC50 value. The correlation between each data pair was estimated using a statistical approach calculating the Spearman rank coefficients. The biodegradability of the p-CP model wastewater was improved by the UV/H2O2 process; the BOD5/COD ratio increased from 0.37 to 0.73 after a 1-h treatment (F = 1243??mJ?cm-2). According to the calculated Spearman rank coefficient, the highest correlation with toxicity data among all monitored parameters was obtained for hydroquinone and benzoquinone, as by-products of p-CP degradation, as well as for the BOD5/COD ratio.     

EVE: A Flexible SIMD Coprocessor for Embedded Vision Applications

In this paper we introduce EVE (embedded vision/vector engine), with a FlexSIMD (flexible SIMD) architecture highly optimized for embedded vision. We show how EVE can be used to meet the growing requirements of embedded vision applications in a power- and area-efficient manner. EVE’s SIMD features allow it to accelerate low-level vision functions (such as image filtering, color-space conversion, pyramids, and gradients). With added flexibility of data accesses, EVE can also be used to accelerate many mid-level vision tasks (such as connected components, integral image, histogram, and Hough transform). Our experiments with a silicon implementation of EVE show that it performs many low- and mid-level vision functions with a 3–12x speed advantage over a C64x+DSP, while consuming less power and area. EVE also achieves code size savings of 4–6x over a C64x+DSP for regular loops. Thanks to its flexibility and programmability, we were able to implement two end-to-end vision applications on EVE and achieve more than a 5× application-level speedup over a C64x+. Having EVE as a coprocessor next to a DSP or a general purpose processor, algorithm developers have an option to accelerate the low- and mid-level vision functions on EVE. This gives them more room to innovate and use the DSP for new, more complex, high-level vision algorithms.     

Engineering highly thermostable xylanase variants using an enhanced combinatorial library method

A new directed evolution method was used to enhance the thermostability of the wild-type GH11 xylanase 2 (known as BD-11) from Hypocrea jecorina (Trichoderma reesei). Both Look-Through Mutagenesis (LTM?), which is a method for rapidly screening selected positions in the protein sequence for amino acids that introduce favorable properties, and Combinatorial Beneficial Mutagenesis (CBM?), which is a method for identifying the best ensemble of individual mutations, were employed to enhance the stability of an enzyme that has been thoroughly engineered by various means during the past 20 years. A diverse set of novel mutations was discovered, including N71D, Y73G, T95G and Y96Q. When these mutations were combined into a single construct (Hjx-81), the purified protein was active even after heating at 100°C for 20 min. This time-effective method should be generally applicable for quickly improving the physico-chemical properties of other industrial and therapeutic enzymes in only several months time.     

Photooxidation of benzene-structured compounds: influence of substituent type on degradation kinetic and sum water parameters

The combined influence of substituent type and UV/H₂O₂ process parameters on the degradation of four aromatic water pollutants was investigated using modified 3³ full factorial design and response surface methodology. Degradation kinetics was described by the quadratic polynomial model. According to the applied ANOVA, besides pH and [H₂O₂], model terms related with the pollutant structure are found to be significant. Different optimal operating conditions and values of observed degradation rate constants were determined for each of the pollutants indicating that the type of substituent influences the overall process effectiveness over structurally defined degradation pathway. Biodegradability (BOD₅/COD) and toxicity (TU) were evaluated prior to the treatment and at the reference time intervals t_1/2(P), t_3/4(P), t_1/4(OC) and t_1/2(OC) corresponding to the real time required to reduce the concentration of parent pollutant and organic content for 1/2, 3/4, 1/4 and 1/2 of initial amount. The observed differences are correlated to the structural differences of studied aromatics.     

Antioxidant, antimicrobial and anticancer activities of three Parmelia species

BACKGROUND: Lichens are symbiotic organisms consisting of algae and fungi. They are used for human and animal nutrition and in the production of colours, perfumes and alcohol. Lichens have also been used in traditional medicine to treat diseases such as jaundice, pulmonary, stomach and cranial diseases. In this study the acetone extracts of three lichens, Parmelia caperata, Parmelia sulcata and Parmelia saxatilis, were tested for their antioxidant, antimicrobial and anticancer potential. RESULTS: Of the lichens tested, P. saxatilis had the highest free radical‐scavenging activity (55.3% inhibition). Moreover, all tested extracts showed effective reducing power and superoxide anion radical scavenging. Strong relationships between total phenolic and flavonoid contents and antioxidant effects of the tested extracts were observed. The extract of P. sulcata was most active in terms of antimicrobial ability, with minimum inhibitory concentration values ranging from 0.78 to 12.5 mg L^?1. All extracts were found to have strong anticancer activity, with IC₅₀ values ranging from 9.55 to 22.95 µg mL^?1. CONCLUSION: The present study showed that the tested lichen extracts exhibited strong antioxidant, antimicrobial and anticancer effects. This suggests that lichens may be used as possible natural antioxidant, antimicrobial and anticancer agents. Copyright © 2012 Society of Chemical Industry     

Mechanical and thermal properties of UV cured mixtures of linear and hyperbranched urethane acrylates

The properties of urethane acrylate resin mixtures based on the linear and hyperbranched aliphatic polyesters were examined. Linear polyester was synthesized from neopentil glycol and adipic acid. Hyperbranched polyester of the third generation was synthesized from 2,2-bis(hydroxymethyl)propionic acid and di-trimethylol propane. The modification of 60% of hyperbranched aliphatic polyester OH end groups was carried out with isononanoic acid or with soybean fatty acids. Two hyperbranched urethane acrylates, with the same degree of acrylation, and one linear urethane acrylate were obtained by reaction of appropriate polyester and isophorone diisocyanate and 2-hydroxyethyl acrylate. The influence of added amount of HUA and nature of non-acrylic end groups on the rheological, mechanical and thermal properties of the uncured and UV cured mixtures diluted with 20 wt.% hexanediol diacrylate was examined. The nature of non-acrylic end groups have great effect on the interaction between linear and hyperbranched urethane acrylates, which further has a crucial influence on the examined properties of uncured and UV cured mixture samples.     

An improved non-adiabatic FEM model of a line-to-earth fault in buried power cables

It is shown in this paper that the non-adiabatic nature of phase-to-earth fault thermodynamics in buried power cables can be modelled in an even more precise manner by using the FEM. The nonlinear FEM model has been created on the basis of an authentic case of fault caused by a previous mechanical damage of the cable sheath and insulation, as well as heat sources, thermo-physical and electrical material properties as functions of temperature and time. The proposed model is applicable to power cables of all voltage levels with different polymer insulations laid in soils with changeable moisture content, as well as to the dry arc tracking or wet arc tracking phenomena in PVC-insulated cables.