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81.
环戊烯催化氧化合成戊二醛及其动力学 总被引:6,自引:0,他引:6
对在非水溶剂存在下过氧化氢一步催化氧化环戊烯制备戊二醛过程中的催化体系进行了研究。考察了具有脱水功能的B2O3的作用及用量,确立了具有优良催化性能的催化体系WO3-B2O3;实验测定了反应动力学数据,采用非线性回归Powel共扼法求得了反应动力学方程。在推荐的催化剂体系和工艺条件下,环戊烯转化率67%,戊二醛收率63%,选择性91%。 相似文献
82.
氧和氮在炭分子筛上的吸附与扩散 总被引:1,自引:0,他引:1
用重量法研究了氧、氮在两种空分用炭分子筛上的吸附与扩散。结果表明,氧和氮在炭分子筛中的扩散是活化扩散,该过程可用双孔模型进行描述。求得了氧、氮的扩散系数。 相似文献
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86.
滴定分析法测定铜的改进 总被引:1,自引:0,他引:1
提出在NH4HF2介质中,有SCNˉ存在下,以Iˉ3—淀粉为指示剂,硫代硫酸钠滴定铜的分析方法 相似文献
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88.
8-Hydroxyqunioline end-capped polystyrene was prepared through atom transfer free radical polymerization (ATRP) with 8-(5-chloromethyl) quinolyl acetate as initiator. The results indicated that this polymerization is a first order reaction with respect to monomer conversion. The molecular weight increased linearly with monomer consumption and very narrow distribution of molecular weight was obtained (polydispersity index less than 1.2). The FT-IR and NMR results show that the 8-hydroxyquinloine group was chemically bonded to the polymer end and there is nearly one 8-hydroxyquinoline group in per polymer chain. All those data show that polymerization of styrene at such conditions displayed living characters. The polymer with 8-hydroxyqquinoline end group reacted with triethylaluminum to form polymeric light-emitting complex and single layer LED was prepared by common spin-coating method. The peak wavelength of LED based on synthesized polymeric complex was around 570 nm. 相似文献
89.
Polypyrrole (PPY) and PPY/SBA‐15 host–guest composite materials have been prepared using chemical synthesis route and characterized by XRD, IR, N2 adsorption–desorption isotherms, and SEM. The humidity sensitive properties (HSP) of this kind of materials have been studied by analyzing the variation curve of impedance as a function of relative humidity. It was found that the PPY/SBA‐15 host–guest composites materials exhibit better HSP than that of the corresponding pure PPY. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3301–3305, 2006 相似文献
90.
Social networks often demonstrate a hierarchical organization, with communities embedded within other communities; moreover, nodes can be shared between different communities, i.e. communities in social networks may be overlapping. In this paper, we define a hierarchical overlapping community structure to present overlapping communities of a social network at different levels of granularity. Discovering the hierarchical overlapping community structure of a social network can provide us a deeper understanding of the complex nature of social networks. We propose an algorithm, called D-HOCS, to derive the hierarchical overlapping community structure of social networks. Firstly, D-HOCS generates a probability transition matrix by applying random walk to a social network, and then trains a Gaussian Mixture Model using the matrix. Further D-HOCS derives overlapping communities by analyzing mean vectors of the Gaussian mixture model. Varying the number of components, D-HOCS repeatedly trains the Gaussian mixture model, detecting the overlapping communities at different levels of granularity. Organizing the overlapping communities into a hierarchy, D-HOCS can finally obtain the hierarchical overlapping community structure of the social network. The experiments conducted on synthetic and real dataset demonstrate the feasibility and applicability of the proposed algorithm. We further employ D-HOCS to explore Enron e-mail corpus, and obtain several interesting insights. For example, we find out a coordinator who coordinated many sections of the Enron Corporation to complete an important task during first half of 2001. We also identify a community that corresponds to a real organization in Enron Corporation. 相似文献