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11.
1 INTRODUCTION donor due to the presence of the protonated carboxyl group; (d) it can form short bridges via one car- Coordination polymers are of great interest due to boxylato end or long bridges via the benzene ring[7]. their physical properties and potential applications in We believe that coordination functionality of isoph- functional materials[1~3]. Aromatic polycarboxylic acids thalate can lead to interesting structures. In this com- such as 1,2,4,5-benzenetetracarboxylic acid[4],… 相似文献
12.
微乳液法制备超细K2Ln2Ti3O10及其光催化活性研究 总被引:1,自引:4,他引:1
以钛酸四丁酯、氢氧化钾和镧系金属氧化物为原料。采用微乳液法制备了系列超细K2Ln2Ti3O10(Ln=La.Ce,Pr.Nd,Sm,Eu,Gd)光催化剂。并考察了其光催化活性。通过X射线衍射(XRD)、透射电镜(TEM)和紫外可见吸收光谱(UV—Vis)对其进行了表征。结果表明:用微乳液法制备催化剂可以在较低的温度下(900℃),用较短的烧结时间(3h)合成结晶度高、粒径较小(200Mm)的K2Ln2Ti3O10钙钛矿型层状结构化合物。催化剂在紫外光和可见光条件下均具有光催化降解甲基橙的活性。紫外光条件下可以明显提高光催化降解活性,降解率达到60%。 相似文献
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以TiO2为载体,N iB为诱导剂,粉末化学镀法制备了负载型纳米N i催化剂.通过TEM、HRTEM、XRD和ICP技术对催化剂物性进行了表征.结果表明,碱性镀液可使载体表面均匀负载微晶结构纳米N i团簇,尺度为35nm左右.该负载型纳米N i在对氯硝基苯选择加氢反应中表现出很高催化加氢活性,并能有效抑制脱氯,达到了工业骨架镍水平.由酸性镀液得到的负载型非晶态纳米N i-P合金具有较弱的催化对氯硝基苯加氢活性.反应温度对反应时间和脱氯率有明显影响. 相似文献
15.
LIU Langa JI Ya-Lia JIA Dian-Zenga② YU Kai-Beib a 《结构化学》2003,22(5):568-572
1 INTRODUCTION In recent years, investigations on the com- pounds containing hydrazide or hydrazone moieties have been increased considerably because of their potentially biological activities, especially as poten- tial inhibitors for many enzymes[1~5]. The presence of weak molecular interactions such as hydrogen- bonding controls the conformational and structural features which are important to the drug action[6, 7]. We have synthesized the photochromic compounds of pyrazolone thiosemi… 相似文献
16.
ZHAO Fengb LI Ganga② WU Jing-Xiaa ZHANG Zong-Peia a 《结构化学》2007,26(3):291-294
The ferrocenyl compound,N-phenylbis(ferrocenecarboxyl)imide (C28H23NO2Fe2,Mr=517.17),was synthesized and structurally characterized by means of X-ray single-crystal dif-fraction. It crystallizes in monoclinic,space group C2/c with a=21.374(14),b=10.430(7),c= 10.741(7) ,β=114.184(8)°,V=2184(2) 3,Z=4,Dc=1.573 g/cm3,F(000)=1064,μ(MoKα)= 1.355 mm–1,T=291(2) K,the final R=0.0548 and wR=0.1437 for 1524 observed reflections with I > 2σ(I). In this compound,the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative. 相似文献
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1 INTRODUCTION 2-Aminochromene is an important class of com- pounds found as the main compounds of many natu- rally occurring products employed as cosmetics and pigments and utilized as potential biodegradeable agro- chemicals[1~3]. In recent years, montmorillonite in natural and ex- changed forms has received considerable attention in different organic syntheses because of its environ- mental compatibility, low cost, high selectivity, reusa- bility and operational simplicity[4], such as … 相似文献
18.
XU Xing-Youa MA Wei-Xinga GAO Jiana LIU Qing-Liangb a 《结构化学》2002,21(5):473-476
1 INTRODUCTION Macrocyclic ligands and their metal complexes have received much attention due to their applications in ion transport, ion separation and as models in biomimic researches[1~7]. The synthetic methods of macrocyclic ligands and their metal complexes are mainly divided into three kinds[8]. The first one is synthesizing free ligand, then forming the metal complexes; the second is template synthesis; and the third is synthesizing the end-off or side-off precursor ligand, then c… 相似文献
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20.
1 INTRODUCTION Recently the series of compounds M3Ln(BO3)3 (M = Sr, Ba and Ln = LaLu, Sc, Y) with space group P63cm or -3R have been reported[1~5], and some of them exhibit interesting optical properties when doped with the active Cr3+ or Yb3+ ions as laser materials. For example, Yb3+-doped Sr3Y- (BO3)3 crystal is a promising laser material for both tunable and femtosecond laser applications[6~8]. The Ba3Y(BO3)3 crystal melts congruently at 1256 ℃ and has a phase transitio… 相似文献