裂解气相色谱-质谱法分析裂解气压缩机垢样的组成

采用裂解气相色谱-质谱联用技术对大庆石化公司裂解气压缩机EC301不同压缩段的垢样进行分析。实验使用了RJ-1型管炉式裂解器,在500℃下对垢样进行裂解,色谱柱为60 m DB-1型毛细管色谱柱,质谱采用电子轰击电离源,电离能70 eV。研究表明,垢样的形成与环戊二烯密切相关。裂解气相色谱-质谱法可以作为分析该垢样成因的有效手段。     

Continuous-wave and Q-switched performance of an Yb:YAG/YAG composite thin disk ceramic laser pumped with 970-nm laser diode

Using front face-pumped compact active mirror laser （CAMIL） structure, we have demonstrated an Yb：YAG/YAG composite ceramic disk laser with pumping wavelength at 970 nm. The laser has been operated in both continuous-wave （CW） and Q-switching modes. Under CW operation, laser output power of 1.05 W with 2% transmission output coupler was achieved at the wavelength of 1031 nm. Q- switched laser output was gotten by using an acousto-optic Q-switch. The repetition rate ranged from 1 to 30 kHz and the pulse width varied from 166 to 700 ns.     

Sustained and Extended Release with Structural and Activity Recovery of Lysozyme from Complexes with Sodium (Sulfamate Carboxylate) Isoprene/Ethylene Oxide Block Copolymer

The complexation of lysozyme and sodium (sulfamate carboxylate) isoprene/ethylene oxide (SCIEO) at pH = 7.4 and the release of lysozyme from the complexes in the presence of NaCl were investigated. Through electrostatic and hydrophobic interactions, lysozyme and SCIEO form stable complex nanoparticles. The complexation partially disturbs the structure of lysozyme. Some of the hydrophobic residues of lysozyme are exposed to bind with SCIEO. The complexation leads to loss of most of the lysozyme activity. In the presence of NaCl, lysozyme can be released from the complexes. The released lysozyme molecules recover their native structure and activity completely. In the condition of physiological pH and ionic strength, a sustained and extended release of lysozyme was achieved.

     

Controlling the Optical Properties of Hyperbranched Conjugated Polyazomethines through Terminal‐Backbone Interactions

A simple approach to tune the optical properties of the hyperbranched conjugated polymers by only adjusting the terminal‐backbone interactions has been reported in this article. Hyperbranched conjugated polyazomethines have been successfully prepared by the reaction of tetramine and dialdehyde. Not only varying the monomer feed ratio to change the quantity of terminal amino groups, but also adopting protonation or complexion with proper dopants (SnCl₂ and β‐cyclodextrin), can alter the interactions between amino terminals and imine bonds in the backbone. Correspondingly, the optical properties of the resulting hyperbranched polymers are controlled.

     

Highly selective piezoelectric sensor for lead(II) based on the lead-catalyzed release of gold nanoparticles from a self-assembled nanosurface

A novel quartz crystal microbalance (QCM) sensor has been developed for highly selective and sensitive detection of Pb²⁺ by exploiting the catalytic effect of Pb²⁺ ions on the leaching of gold nanoparticles from the surface of a QCM sensor. The use of self-assembled gold nanoparticles (AuNPs) strongly enlarges the size of the interface and thus amplifies the analytical response resulting from the loss of mass. This results in a very low detection limit for Pb²⁺ (30 nM). The high selectivity is demonstrated by studying the effect of potentially interfering ions both in the absence and presence of Pb²⁺ ions. This simple and well reproducible sensor was applied to the determination of lead in the spiked drinking water. This work provides a novel strategy for fabricating QCM sensors towards Pb²⁺ in real samples. Figure

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空气自由场爆炸冲击波数值建模及应用

为建立描述任意时刻、距离下空气自由场爆炸波冲击波压力、密度、粒子速度的经验公式,支撑复杂场景下冲击波载荷的快速计算,采用一维精细数值模拟的方法计算了不同比例距离下的压力、密度、粒子速度时程,并利用曲线拟合方法得到了正相超压峰值等22个冲击波参数与比例距离关系的经验公式,采用改进修正Friedlander方程建立了冲击波压力、密度、粒子速度随时间变化的关系式;利用爆炸冲击波地面反射和建筑后绕射两个典型工况,阐释了提出模型的应用场景,并与试验、数值模拟结果对比。结果表明：压力、密度、粒子速度随比例距离、时间变化的经验关系与数值模拟结果基本吻合;爆炸冲击波地面反射和建筑后绕射两个典型工况下,理论计算与数值模拟的压力云图基本吻合,在相同硬件条件下,理论计算耗时仅为千万级网格数值模拟的5%左右,在计算速度上有明显的优越性。

     

超高效液相色谱-串联质谱法测定人尿液中全氟有机化合物

采用超高效液相色谱-串联质谱(UPLC-MS/MS)联用技术,建立了对人尿液中12种全氟有机化合物(PFCs)的分析方法。首先在尿液样品中加入相应的同位素内标,以2%(体积分数)甲酸甲醇溶液超声萃取、离心后,将提取液用弱阴离子交换固相萃取柱净化,采用UPLC-MS/MS测定,内标法定量。12种目标化合物在0.05～50 μg/L质量浓度范围内线性良好,相关系数(r)均大于0.992,检出限在0.44～3.47 ng/L之间。在20、100、500 ng/L添加水平下,平均回收率范围为80.3%～116.2%,相对标准偏差(n=6)在5.5%～13.8%之间。该方法灵敏度高、重现性好、回收率高、操作简单,适合人尿液中PFCs的测定。     

Thiophene‐S,S‐dioxidized Indophenine: A Quinoid‐Type Building Block with High Electron Affinity for Constructing n‐Type Polymer Semiconductors with Narrow Band Gaps

Three thiophene‐S,S‐dioxidized indophenine (IDTO) isomers, 3 a (E,E,E), 3 b (Z,E,E), and 3 c (Z,E,Z), were synthesized by oxidation of an indophenine compound. 3 b and 3 c could be converted into the most‐stable 3 a by heating at 110 °C. An IDTO‐containing conjugated polymer, PIDTOTT, was prepared using 3 a as a comonomer through a Stille coupling reaction, and it possesses a narrow band gap and low energy levels. In organic field effect transistors (OFETs), PIDTOTT exhibited unipolar n‐type semiconductor characteristics with unexpectedly high electron mobility (up to 0.14 cm² V^?1 s^?1), despite its rather disordered chain packing.     

基于MPEG-7的视频数据组织与管理

针对现有视频数据库系统存在的不足,根据视频数据的特点,提出并实现了一种基于MPEG-7标准的视频数据组织与管理方法.该方法将视频内容的描述数据按照不同层次的视频内容单元进行组织,并针对不同的描述数据,分别生成结构索引、文本索引和特征索引,以满足基于内容的视频浏览和检索的需求.实验证明,通过视频描述数据库对视频数据进行管理,不仅降低了服务器的存储要求,而且为基于内容的视频检索奠定了基础,具有很好的通用性和可扩展性.