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41.
Dieter Seebach Thimo L. Sommerfeld Qiongzhong Jiang Luigi M. Venanzi 《Helvetica chimica acta》1994,77(5):1313-1330
The cyclization reaction of aldehydes with Z- and Boc-protected β-hydroxyamino-acid esters (Tables 1 and 2), or of dipeptides containing serine or threonine at the N-terminus (Table 3), to give oxazolidine derivatives, occurs in the presence of isopropyl orthoformate and catalytic amounts of [Rh(MeCN)3(triphos)](CF3SO3)3. The reaction may be carried out under kinetic or under thermodynamic control, so that the ratio of the two possible epimeric products can be changed. The protecting group can be removed from the 3-position of the oxazolidine ring, and the resulting NH group can be coupled with another amino acid. Thus, a new method for the preparation of peptides containing β-hydroxy-amino acid-derived oxazolidines (‘pseudo-prolines’) is available. N-Neopentyl-substituted tripeptides are also described. 相似文献
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Amita Gupta Alexei Yu Ganin Parmanand Sharma Vikrant Agnihotri LM Belova KV Rao Mikhail E Kozlov AA Zakhidov RH Baughman 《Pramana》2002,58(5-6):1051-1059
We present studies of novel nanocomposites of BiNi impregnated into the structure of opals as well as inverse opals. Atomic force microscopy and high resolution elemental analyses show
a highly ordered structure and uniform distribution of the BiNi filler in the matrix. These BiNi-based nanocomposites are
found to exhibit distinct ferromagnetic-like ordering with transition temperature of about 675 K. As far as we know there
exists no report in literature on any BiNi compound which is magnetic. 相似文献
44.
Mercedes Camalli Francesco Caruso Stanislav Chaloupka Ernest M. Leber Heinrich Rimml Luigi M. Venanzi 《Helvetica chimica acta》1990,73(8):2263-2274
The preparation of complexes [MX2( 1 )] (M = Ni, Pd, and Pi; X - Cl, Br, and I; 1 = 1,2-bis[(diphenylphosphino)methyl]benzene). [Pt(OSO2CH3)Et( 1 )], [Pt(alkene)( 1 )] (alkene - C2H2, and CH2 = CHCN), and [( 1 )Pt-(μ-H)2PtH( 1 )][BPh4] is reported. Their 1H- and 31P-NMR spectra were recorded and used lor structural assignments. The X-ray crystal structure of [Pt(C2H4)( 1 )] was determined. It is shown that the P? Pt? P bond angle in this complex differs significantly from those found in related compounds with monodentate phosphines, and that this difference is likely to be due to intramolecular contacts. 相似文献
45.
Gustav Bracher David M. Grove Luigi M. Venanzi Fiorella Bachechi Pasquale Mura Luigi Zambonelli 《Helvetica chimica acta》1980,63(8):2519-2530
It is shown that ligand 1 , designed to span trans-positions, under appropriate conditions also gives cis-mononuclear complexes of platinum (II). The structure of cis-[PtCl2 (1) ] (2) has been determined by single-crystal X-ray diffraction. The major distortion from square planar coordination is the P-Pt-P angle of 104.8°. Values of valence angles within the bidentate ligand indicate that this part of the molecule is very strained. Two phenyl groups, one on each phosphorus, lie almost parallel to each other separated by ca. 3.2–3.3 Å. The 1H-NMR. data for this compound show that the π-phenyl interactions observed in the solid state occur also in solution. The preparation and NMR.-spectroscopic properties of trans- and cis-[PtH(PPh3) (1) ] [BF4] are reported. 相似文献
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13C and 195Pt-NMR. parameters for the complexes trans-[PtCl2(C5H10N)-(CH3CH?CHCH3)] are presented. It is suggested that conclusions, concerning metal olefin bond strengths, drawn from NMR. studies of nuclei not directly involved in the bonding can be misleading. 相似文献
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