A pigment (CuS) identified by micro‐Raman spectroscopy on a Chinese funerary lacquer ware of West Han Dynasty

A blue pigment was identified by micro‐Raman spectroscopy, X‐ray fluorescence spectroscopy (XRF), scanning electron microscopy (SEM)/energy dispersive X‐ray (EDX) and X‐ray diffraction (XRD). The test sample, a funerary lacquer tray, belongs to West Han Dynasty (206 BC–AD 8) of China and was decorated with faint blue patterns. The result from Raman spectroscopy showed that the faint blue is covellite (CuS) due to the presence of a characteristic peak at 474.5 cm⁻¹, which further was confirmed by XRF, SEM–EDX and XRD. This research indicated that CuS had been used as a blue pigment to decorate lacquer wares from the West Han Dynasty in China. Copyright © 2009 John Wiley & Sons, Ltd.     

Study of asymmetric wavenumber shift of the Fermi doublet ν1 − 2ν2 in the Raman spectrum of liquid carbon disulfide

The Raman spectra of liquid carbon disulfide (CS₂) diluted with benzene (C₆H₆) have been measured. By changing the CS₂, the concentration, we found an asymmetric wavenumber shift phenomenon. With decreasing concentration of CS₂, the position of the ν₁ (655 cm⁻¹) band remains practically unchanged, and the 2ν₂ (796 cm⁻¹) band shifts toward higher wavenumbers. To interpret this asymmetric wavenumber shift phenomenon of the Fermi doublet ν₁ − 2ν₂ in the Raman spectra satisfactorily, we propose a modified Bertran model. The values of the Fermi resonance (FR) parameters of CS₂ at different concentrations were calculated using the Bertran equations. In addition, we found the fundamental ν₂, which should be independent of the FR interaction, shifted to higher wavenumbers as the concentration decreased. This shift was probably driven by the tuning of the FR. Copyright © 2009 John Wiley & Sons, Ltd.     

Coexistence of magnetism and superconductivity in the hole doped FeAs-based superconducting compound

The magnetic and superconducting properties of the Sm-doped FeAs-based superconducting compound were investigated under wide ranges of temperature and magnetic field. After the systematical magnetic ion substitution, the superconducting transition temperature decreases with increasing magnetic moment. The hysteresis loop of the La_0.87?xSm_xSr_0.13FeAsO sample shows a superconducting hysteresis and a paramagnetic background signal. The paramagnetic signal is mainly attributed to the Sm moments. The experiment demonstrates that the coexistence of magnetism and superconductivity in the hole doped FeAs-based superconducting compounds is possible. Unlike the electron doped FeAs-based superconducting compounds SmFeAsOF, the hole doped superconductivity is degraded by the substitution of La by Sm. The hole-doped and electron-doped sides are not symmetric.     

基于暗像元的Hyperion高光谱影像大气校正

大气是影响遥感定量分析与应用的重要因素。该文利用暗像元大气校正算法,在IDL平台下,从Hyperion传感器的可见光-近红外波段逐通道提取大气光学厚度信息,并利用该数据实现对Hyperion数据大气校正的目的。研究结果表明,大气光学厚度随着通道中心波长的增加而减小,即与中心波长成负相关。光学厚度与中心波长的最佳经验模型为线性模型,模型的回归系数为0.912 3。通过分析校正前后的水体光谱曲线可知,大气的衰减作用使得卫星遥感信号不能正确表现自然水体的表观光学特性和内在光学特性,且对水体样本层次变化不敏感。在蓝绿波段,大气对光谱数据的污染最为严重,该波段的光谱特征与自然水体的理论光学特性完全相背离。由大气光学厚度光谱特性和自然水体光学特性可知,经过"暗像元"算法校正过的影像数据的质量得到显著改善。在缺少同步大气垂直剖面参数的情况下,暗像元算法将是Hyperion数据一种行之有效的大气效应消除方法。     

Excess titanium in barium titanate nanoparticles directly synthesized from solution

The formation mechanism of excess titanium in BaTiO₃ nanoparticles is different from that in BaTiO₃ bulk materials. In this study, we analyzed the concentration of excess titanium in BaTiO₃ nanoparticles, which were directly synthesized from solution at 65 °C and it was found that it can reach an abnormal high concentration and keep the normal perovskite structure. The mechanism is discussed from the points of both defect chemistry and surface effect. The dielectric property of the ceramics fabricated from as-prepared nanoparticles with different concentration of excess titanium is also studied.     

Deterministic Raman crosstalk effects in amplified wavelength division multiplexing transmission

We study the deterministic effects of inter-pulse Raman-induced crosstalk in amplified wavelength division multiplexing (WDM) optical fiber transmission lines. We show that the dynamics of pulse amplitudes in an N-channel transmission system is described by an N-dimensional predator-prey model. We find the equilibrium states with non-zero amplitudes and prove their stability by obtaining the Lyapunov function. The stability is independent of the exact details of the approximation for the Raman gain curve. Furthermore, we investigate the impact of cross phase modulation and Raman self and cross frequency shifts on the dynamics and establish the stability of the equilibrium state with respect to these perturbations. Our results provide a quantitative explanation for the robustness of differential-phase-shift-keyed WDM transmission against Raman crosstalk effects.     

Effects of interactions among wave aberrations on optical image quality after refractive surgery

Research on wave aberrations indicates that interactions and balances among aberrations can provide better visual quality for normal eyes. In this paper, we investigate the aberration compensatory mechanism for eyes after LASIK surgery. Data of Zernike coefficients of wave-front aberrations are collected from 60 post-operative eyes through a Hartmann-Shack wave-front sensor, and then a series of Monte Carlo simulations are performed by manipulating the value of each Zernike coefficient (second order through seventh order). The modulation transfer function (MTF) ratio as a function of spatial frequency is used to evaluate the aberrations’ characteristic of independence. Finally, in a control condition, “synthetic” model eyes are produced through Monte Carlo arithmetic and the aberration independence of the synthetic eyes is analyzed. The results suggest that, for 6 and 3 mm pupil size, aberrations of the eyes after LASIK surgery are still not independent and the adaptive mechanism still exists. However, the adaptive mechanism does not hold for the “synthetic” eyes.     

Influence of absorbed moisture on desizing of poly(vinyl alcohol) on cotton fabrics during atmospheric pressure plasma jet treatment

This paper studies the influence of moisture absorption of cotton fabrics on the effectiveness of atmospheric pressure plasma jet (APPJ) on desizing of polyvinyl alcohol (PVA). Cotton fabrics with three different moisture regains (MR), namely 1.8%, 7.3%, and 28.4% corresponding to 10%, 65%, and 98% of relative humidity respectively, are treated for 16 s, 32 s, 48 s, and 64 s. X-ray photoelectron spectroscopy analysis indicates that the plasma treated PVA has higher oxygen concentration than the control. Mass loss results show that the fabric with the highest MR has the largest mass loss after 64 s plasma exposure. Solubility measurement reveals that the sample with the lowest MR has the highest desizing efficacy and the percent desizing ratio reaches 96% after 64 s exposure plus a 20 min hot wash, which is shown as clean as the unsized sample through scanning electron microscopy analysis. The yarn tensile strength test results show that APPJ has no negative effect on fabric tensile strength.     

子空间约束下矩阵方程ATXB+BTXTA=D的解及最佳逼近

约束矩阵方程求解是指在满足一定约束条件下求矩阵方程（组）的解.在子空间约束条件下,利用共轭梯度法,结合线性投影算子,得到矩阵方程A^TXB+B^TX^TA=D的解,进一步得到其最佳逼近.最后用数值例子证实了算法的有效性.