全文获取类型
收费全文 | 22498篇 |
免费 | 4385篇 |
国内免费 | 3241篇 |
学科分类
数理化 | 30124篇 |
出版年
2024年 | 64篇 |
2023年 | 496篇 |
2022年 | 646篇 |
2021年 | 955篇 |
2020年 | 1092篇 |
2019年 | 1040篇 |
2018年 | 919篇 |
2017年 | 870篇 |
2016年 | 1247篇 |
2015年 | 1217篇 |
2014年 | 1534篇 |
2013年 | 1958篇 |
2012年 | 2293篇 |
2011年 | 2309篇 |
2010年 | 1638篇 |
2009年 | 1535篇 |
2008年 | 1676篇 |
2007年 | 1366篇 |
2006年 | 1232篇 |
2005年 | 965篇 |
2004年 | 760篇 |
2003年 | 553篇 |
2002年 | 465篇 |
2001年 | 389篇 |
2000年 | 388篇 |
1999年 | 393篇 |
1998年 | 292篇 |
1997年 | 249篇 |
1996年 | 294篇 |
1995年 | 214篇 |
1994年 | 192篇 |
1993年 | 156篇 |
1992年 | 143篇 |
1991年 | 106篇 |
1990年 | 104篇 |
1989年 | 86篇 |
1988年 | 44篇 |
1987年 | 42篇 |
1986年 | 64篇 |
1985年 | 55篇 |
1984年 | 17篇 |
1983年 | 20篇 |
1982年 | 10篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1957年 | 6篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
BP神经网络在上海住宅市场需求预测中的应用 总被引:5,自引:0,他引:5
人工神经网络是近期发展最快的人工智能领域研究成果之一 ,本文在介绍 BP神经网络的有关原理的基础上 ,建立了一个上海住宅市场的 BP神经网络模型 ,并通过该模型对上海住宅市场的需求进行了预测和分析 .分析结果表明人工神经网络方法在住宅市场需求预测中的应用是可行的并且是有效的 . 相似文献
62.
Pyroelectricity and Spontaneous Polarization in [111] Oriented 0.955 Pb(Zn1/3Nb2/3)O3-0.045PbTiO3 Single Crystals 下载免费PDF全文
We report that the measurements of the pyroelectric current of the pre-poled [111]-oriented 0.955 Pb(Zn1/3Nb2/3) O3-0.045 PbTiO3 (PZN-4.5%PT) single crystals can shed some light on the phase transition and spontaneous polarization characters of this material in a similar way to measures of remanent polarization and dielectric properties. The pyroelectric current is measured and the corresponding spontaneous polarization is calculated as a function of temperature with various poling fields added during cooling the sample from 200℃ to room temperature. Critical electric field of 0.061 k V/cm is found to be essential to induce the intermediate ferroelectric orthorhombic phase between the ferroelectric rhombohedral and tetragonal phases. Below the critical field, the polarization increases almost linearly with the increase of poling field. At the critical field, the polarization at 30OC increases abruptly from 14μC/cm^2 for a poling field of O.06kV/cm to 29.5μC/cm^2 for a poling field of 0.061 kV/cm, and afterwards, increases slowly and saturates to 31 μC/cm^2 for poling fields beyond 0.55 kV/cm. 相似文献
63.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect. 相似文献
64.
Stable aminoxyls and an iminoxyl were observed by spin trapping and EPR techniques during the nitration of coumarins containing a hydroxy group by nitric oxide. The trapped free radicals are deduced to be the resonance stabilized phenoxy-like radicals. The mechanisms for the nitrations are suggested. 相似文献
65.
Xiao Xiaohua Cao Yuguan Liu Xia Jiang Shengxiang 《Journal of inclusion phenomena and macrocyclic chemistry》2004,48(3-4):111-115
A PM3 calculation in vacuum of the inclusion complexation ofo-, m-, p-nitro-phenol with calix[n]arenes is performedsuccessfully. The pathways for inclusion process are describedand the most probable structures of the 1:1 complex are soughtthrough a potential energy scan. The energy differences betweenthe inclusion complexes and the hosts, by calculation, show thatthe most stable complexation is calix[4]-p-nitro phenol andcalix[6]-m-nitro phenol. 相似文献
66.
The gas‐transport properties of poly[2,6‐toluene‐2,2‐bis(3,4‐dicarboxylphenyl)hexafluoropropane diimide] (6FDA‐2,6‐DAT) have been investigated. The sorption behavior of dense 6FDA‐2,6‐DAT membranes is well described by the dual‐mode sorption model and has certain relationships with the critical temperatures of the penetrants. The solubility coefficient decreases with an increase in either the pressure or temperature. The temperature dependence of the diffusivity coefficient increases with an increase in the penetrant size, as the order of the activation energy for the diffusion jump is CH4 > N2 > O2 > CO2. Also, the average diffusion coefficient increases with increasing pressure for all the gases tested. As a combined contribution from sorption and diffusion, permeability decreases with increases in the pressure and the kinetic diameter of the penetrant molecules. Even up to 32.7 atm, no plasticization phenomenon can be observed on flat dense 6FDA‐2,6‐DAT membranes from their permeability–pressure curves. However, just as for other gases, the absolute value of the heat of sorption of CO2 decreases with increasing pressure at a low‐pressure range, but the trend changes when the feed pressure is greater than 10 atm. This implies that CO2‐induced plasticization may occur and reduce the positive enthalpy required to create a site into which a penetrant can be sorbed. Therefore, a better diagnosis of the inherent threshold pressure for the plasticization of a glassy polymer membrane may involve examining the absolute value of the heat of sorption as a function of pressure and identifying the turning point at which the gradient of the absolute value of the heat of sorption against pressure turns from a negative value to a positive one. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 354–364, 2004 相似文献
67.
介绍了一台10mm口径两级双程离轴放大系统,实现了对5mm×5mm口径光束的激光放大,耦合系统采用高功率LDA紧密侧面直接抽运棒状Nd:YLF方式。分析并实验研究了在不同抽运电流、放大脉冲与放大器LDA抽运时刻的不同延时及不同注入能量条件下,放大系统及光束每次放大时放大特性的规律。实验得到:在放大系统5mm×5mm软光阑处注入1.58mJ能量时,放大系统可输出129.2mJ能量,能量提取效率达到19.5%,满足该系统的设计指标。 相似文献
68.
69.
着重研究了多孔介质BISQ模型中慢纵波的基本特性.给出了BISQ模型下慢纵波速度 和衰减的低频近似公式.与Biot理论对比,BISQ模型中慢纵波的衰减随频率降低急剧增大, 且随喷射流长度的减小而增加;相速度随喷射流长度的减小而增加,其低频极限值不是零; 孔隙流体位移与固相骨架位移之比的幅值随喷射流长度的增加而减小,其相位特点与Biot模 型预测的不同;在流体与孔隙介质的边界上可产生更大的渗流.为对比,同时也给出快纵波 的行为.依据BISQ模型可推断:非黏滞流体饱和孔隙介质中不存在喷射流机理;BISQ模型中
关键词:
多孔介质
喷射流
慢纵波
动力协调 相似文献
70.
研究了Yb3 掺杂铝氟磷酸盐 (AFP)玻璃的吸收光谱、荧光光谱 ,测量了Yb3 离子的荧光有效线宽 (Δλeff>5 5nm)以及2 F5 2 能级的荧光寿命 (τmax=2ms)及随掺杂浓度的变化 .应用倒易法计算了Yb3 的发射截面 ,其发射截面可达 0 6 6 82 3pm2 ,且激光增益系数τfσemi达 1 2 89ms.pm2 .评估了Yb3 在AFP玻璃中的激光性能 ,发现其具有较理想的激发态最小粒子数 (0 15 )、饱和抽运强度 (8 3kW cm2 )和最小抽运强度 (1 2 4 5kW cm2 )值及良好的热稳定性 .研究结果表明掺Yb3 氟磷酸盐玻璃是实现高功率超短可调谐激光器的理想增益介质 . 相似文献