Fabrication of a magmolecule using nanoparticle and evaluation of its adsorption capacity for selenium ions from nuclear wastewater

The purpose of present study is to fabrication of a magmolecule (amino-functionalized magnetite nanoparticles) and evaluation of its adsorption capacity for selenite (SeO₃ ^2?) ions from nuclear wastewater. To accomplish this, synthesized magnetite nanoparticles is coated with a layer of SiO₂ in order to be chemically stable and then functionalized with 3-aminopropyl triethoxysilane (APTES) to be more effective. Adsorption of SeO₃ ^2? ions was investigated in batch technique. The effect of parameters such as solution pH, presence of competing anions using sulfuric acid and nitric acid (NO₃ ^?, HSO₄ ^? and SO₄ ^2?) and temperature were studied. Maximum adsorption occurred at pH 2.4 for magnetite (naked nanoparticle) and 1.7 for functionalized nanoparticles, while the dose of adsorbent was 1 g/L and selenite ion concentration was 50 mg/L. sulfuric acid was selected as the better acidic agent for controlling pH of solution. Thermodynamic parameters were also calculated and it has been found that the adsorption was endothermic. The obtained result showed that the naked particles had more adsorption capacity but it has been suggested usage of functionalized particles in the magmolecule process duo to stability and reusable capability.     

A Facile Synthesis of Stable Phosphorus Ylides Containing Chlorine and Sulfur Derived from 6-Chloro-2-benzoxazolethiol and 2-Chloro-phenothiazine

Stable crystalline phosphorus ylides containing chlorine and sulfur were obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine and dialkyl acetylene-dicarboxylates in the presence of 6-chloro-2-benzoxazolethiol and 2-chloro-phenothiazine. These stable ylides exist in solution as a mixture of two geometrical isomers. This is caused by the conjugation of the ylide moiety with the adjacent carbonyl group, which results in a restricted rotation around the respective carbon-carbon bond.     

Synthesis of Hollow SiO2 Nanoparticles from Dy2O3@SiO2 Core–Shell Nanocomposites via a Recyclable Sonochemical Method

Hollow silica nanoparticles were prepared from Dy₂O₃@SiO₂ core–shell nanocomposites, for the first time, by a simple ultrasonic assisted sol–gel method. The Dy₂O₃@SiO₂ core–shell nanocomposites were prepared by the deposition of a SiO₂ layer onto the surface of Dy₂O₃ nanoparticles using a three-step coating process. The hollow SiO₂ nanostructures were obtained by selective removal of the Dy₂O₃ cores. The structure, morphology and composition of the products were determined by the techniques of X-ray diffraction, Fourier transfom infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The results indicated that hollow SiO₂ nanostructures were sphere-like shape with the average size of 20?nm and had an amorphous crystal structure. The important advantage of this process is the recyclability of the Dy₂O₃ nanoparticles as the starting material of the reaction.     

Potentiometric behaviour of lanthanum polyalkoxylate complexes in PVC membrane electrodes: effect of plasticizers and applications

Tetraphenylborate salts of lanthanum complexes of nonylphenoxypolyethyleneoxyethanol (Antarox CO-880) and polypropylene glycol-425 (PPG-425) have been prepared and examined for their applicability as sensing species for lanthanum ions by incorporating them in a poly (vinyl chloride) membrane system in the presence of 2-nitrophenyl phenyl ether (NPPE), dioctylphenyl phosphonate or a mixture of both as plasticizers. Almost all of the systems studied showed an excellent response for lanthanum ions in pure solutions with a near Nernstian response of 18–20 mV per decade between 10^?5 and 10^?1 M lanthanum and a static response time of less than 1 min. Among the systems studied, lanthanum(Antarox CO-880)TPB/100% NPPE (TPB=tetraphenylborate) was the best in terms of tolerance to interfering ions. K⁺, Ba²⁺, Pb²⁺ and Al³⁺ were serious interferents, but most other interferents investigated were tolerable at [La³⁺] > 10^?4 M. Plasticizers were found to be decisive in determining the sensor selectivity towards the different metal ions. A lanthanum(Antarox CO-880)TPB/100% NPPE PVC membrane electrode was utilized for the potentiometric titration of fluoride, in sodium fluoride, against lanthanum nitrate solutions. It proved to be successful for fluoride concentrations of ? 10^?3 M.     

Studies on phenol permeation through supported liquid membranes containing functionalized polyorganosiloxanes

In this study, the functionalized, linear, hydrophobic fluid organosiloxane polymers, namely, methylhydrosiloxane–dimethylsiloxane copolymers supported on a polypropylene microporous flat sheet membrane (Celgard 2502 and 2402) have been tested as supported liquid membranes (SLMs) for phenol recovery from aqueous phases into a 0.1 M NaOH phase. The functionalized polymers include, Me₃SiO[MeSi(OR)O]_x[Me₂SiO]_ySiMe₃ (containing x = 15–18, 25–35 and 50–55 mol% of R, where R is –(CH₂)_nNMe₂ (n = 3 or 4 or 6) or –(CH₂)₂OEt pendent organofunctional groups. The functionalities, R, tested were derived from the commercially available 3-dimethylamino-1-propanol and 2-ethoxyethanol as well as newly synthesized 4-dimethylamino-1-butanol and 6-dimethylamino-1-hexanol which have been made for the purpose of this study.

The study showed that phenol permeation expressed as permeate flux through the membranes increases with the larger number of carbon spacers in the alkyl chain of the aminoalcohol pendent, larger porosity of the polypropylene support films, higher mol% of the methylhydrosiloxane portion functionalized and faster flow rates of both the feed and the receiving phases. Phenol permeation was enhanced significantly when the mol% of the methylhydrosiloxane portion was 50–55 or 25–35 with 6-dimethylamino-1-hexanol functionality supported on Celgard 2502.     

Three-dimensional recognition of occluded objects by using computational integral imaging

We have proposed a method to recognize partially occluded three-dimensional (3D) objects by using 3D volumetric reconstruction integral imaging (II). An II system captures multiple perspectives of occluded objects by using a microlens array. The reconstruction of the occluded 3D scene and target recognition are done digitally to reduce the effects of the occlusion. To verify system performance, we have implemented an optimum filter for object recognition. Both two-dimensional (2D) images and 3D II volumetric reconstructed images are considered. The correlation results of occluded 3D images for volumetric reconstruction show substantial improvements compared with those for conventional 2D imaging of occluded images.     

Hall current effect on MHD mixed convection flow from an inclined continuously stretching surface with blowing/suction and internal heat generation/absorption

Hydromagnetic heat transfer by mixed convection along an inclined continuously stretching surface, with power-law variation in the surface temperature or heat flux, in the presence of Hall current and internal heat generation/absorption has been studied. The surface is considered to be permeable to allow fluid suction or blowing, and stretching with a surface velocity varied according to a power-law. Two cases of the temperature boundary conditions were considered at the surface. The governing equations have been transformed into non-similar partial differential equations which have been integrated by the forth-order Runge–Kutta method. The effect of Hall parameter, magnetic parameter, dimensionless blowing/suction parameter, space and temperature dependent internal heat generation/absorption parameters and buoyancy force parameters on the temperature, primary and secondary flow velocity have been studied parametrically. All parameters involved in the problem affect the flow and thermal distributions except the temperature-dependent internal heat generation/absorption in the case of prescribed heat flux (PHF). Numerical values of the local skin-friction and the local Nusselt numbers for various parametric conditions have been tabulated.     

Three-dimensional imaging and visualization of partially occluded objects using axially distributed stereo image sensing

In this Letter, we propose a multiperspective three-dimensional (3D) imaging system using axially distributed stereo image sensing. In this proposed method, the stereo camera is translated along its optical axis and multiple axial elemental image pairs for a 3D scene are collected. The captured elemental images are reconstructed in 3D using a computational reconstruction algorithm based on ray back-projection. The proposed method is applied to partially occluded object visualization. Optical experiments are performed to verify the approach.     

Securing information by use of digital holography

An information security method that uses a digital holographic technique is presented. An encrypted image is stored as a digital hologram. The decryption key is also stored as a digital hologram. The encrypted image can be electrically decrypted by use of the digital hologram of the key. This security technique provides secure storage and data transmission. Experimental results are presented to demonstrate the proposed method.