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Andrikopoulos PC Armstrong DR Hevia E Kennedy AR Mulvey RE O'Hara CT 《Chemical communications (Cambridge, England)》2005,(9):1131-1133
Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu4(2-) dianions within a polycationic network, is reported. 相似文献
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Blair VL Clegg W Kennedy AR Livingstone Z Russo L Hevia E 《Angewandte Chemie (International ed. in English)》2011,50(42):9857-9860
Ligand domin(o)ated: In contrast to the straightforward deprotonation of benzothiazole using Grignard reagents, treatment of benzothiazole with 1 leads to a novel type of activation. The initial magnesiation initiates an unstoppable domino reaction of C?C coupling, ring opening, nucleophilic addition, and deprotonation to give 2. THF=tetrahydrofuran. 相似文献