Quantum ratchets in dissipative chaotic systems

Using the method of quantum trajectories, we study a quantum chaotic dissipative ratchet appearing for particles in a pulsed asymmetric potential in the presence of a dissipative environment. The system is characterized by directed transport emerging from a quantum strange attractor. This model exhibits, in the limit of small effective Planck constant, a transition from quantum to classical behavior, in agreement with the correspondence principle. We also discuss parameter values suitable for the implementation of the quantum ratchet effect with cold atoms in optical lattices.     

CH...O and CH...F links form the cage structure of dioxane-trifluoromethane

The molecular beam Fourier transform microwave spectrum of 1,4-dioxane-trifluoromethane has been assigned and measured. The two subunits form a cage stabilized by one C-H...O and two C-H...F weak hydrogen bonds. The C-H...O link involves the axial lone pair of one of the two equivalent ring oxygens, while the two C-H...F bridges connect trifluoromethane to the two axial hydrogens in positions 3 and 5. The dissociation energy has been estimated from the D(J) centrifugal distortion parameter to be approximately 6.8 kJ/mol.     

Boundary effects on the electrical conductivity of pure and doped cerium oxide thin films

Thin films of CeO(2) (both nominally pure and 10 mol% gadolinium-doped) grown via pulsed-laser deposition were studied. The electrical conductivity of the samples was measured as a function of thickness, temperature and oxygen partial pressure (pO(2)) using impedance spectroscopy. As expected, undoped CeO(2) exhibits electronic conductivity (with activation energy between 1.4 and 1.6 eV) whereas the highly doped samples are oxygen vacancy conductors (activation energy around 0.7 eV for epitaxial films). In order to investigate the influence of the nature of the substrate the thin films were grown on two different substrates, Al(2)O(3) (0001) and SiO(2) (0001), and compared. While the films grown on SiO(2) exhibit a microstructure characterized by columnar grains, the films grown on Al(2)O(3) are epitaxial. Notably, for films on both substrates the conductivity and activation energy vary with film thickness and exhibit remarkable differences when the films on different substrates are compared. In the case of the polycrystalline films (SiO(2) substrate), the space charge layer effects of the grain boundaries dominate over the substrate-film interface effect. In the case of the epitaxial films (Al(2)O(3) substrate), a small interface effect, probably due to a space charge layer or structural strain, is observed.     

Synthesis of Glycosyl Azides by the Addition of Phenylselenenyl Azide to Glycals

Abstract

The addition of phenylselenenyl azide to glycals is carried out under conditions that give 2-deoxy-2-phenylselenoglycosyl azides. This regiochemistry is opposite to that obtained under free-radical conditions, which are known to produce 2-azido-2-deoxyselenoglycosides. The addition reaction is carried out with phenylselenenyl chloride and sodium azide in dimethylformamide, and is stereoselective for trans addition. Tri-O-benzyl-d-glucal and di-O-benzyl-l-rhamnal each gave two addition products, in which the phenylselenyl and azido groups were either trans diaxial or trans diequatorial. Tri-O-benzyl-d-galactal gave only the trans diaxial addition product.     

Convergence of series of dependent φ-subgaussian random variables

The almost sure convergence of weighted sums of φ-subgaussian m-acceptable random variables is investigated. As corollaries, the main results are applied to the case of negatively dependent and m-dependent subgaussian random variables. Finally, an application to random Fourier series is presented.     

Electronic properties of nonhomovalent alloys: A study of the b.c.c. Li−Mg solid solution

Summary The influence of the alloying on the electronic properties of the b.c.c. Li−Mg solid solution has been investigated within the KKR-CPA framework. Such an influence has been studied by computing the band structure, Fermi surface, soft X-ray spectra, residual resistivity and Auger spectra for chosen values of the composition. The theoretical results we obtained are in fair agreement with the surface existing experimental data and support the view that also in ?simple metals? alloys care has to be taken in studying such systems in terms of low-order perturbation approaches.

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Riassunto Sono state studiate varie proprietà elettroniche delle leghe di Li−Mg nell’intervallo di concentrazione in cui questi sistemi cristallizzano nel reticolo b.c.c. In particolare sono state calcolate la struttura a bande, le superfici di Fermi, la resistività residua, gli spettri X ed Auger e si sono confrontati i risultati con i dati sperimentali esistenti. Il buon accordo fra risultati teorici e dati sperimentali indica che, anche per leghe di metalli semplici, gli approcci perturbativi a basso ordine possono essere insufficienti a descrivere il comportamento di tali sistemi.

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Резюме В рамках KKR-CPA исследуется влияние процесса сплавления на электронные свойства объемноцетририованного кубического твердого раствора Li−Mg. Проводятся вычисления зонной структуры, поверхности Ферми, спектров мягкого рентгеновского излучения, остаточного сопротивления и Ож-ye-спектров для выбранных величин состава. Полученные теоретические величины хорошо согласуются с существуюими экспериментальными данными.

     

Nonbinary convolutional codes derived from group character codes

New families of unit memory as well as multi-memory nonbinary convolutional codes are constructed algebraically in this paper. These convolutional codes are derived from the class of group character codes. The proposed codes have basic generator matrices, consequently, they are noncatastrophic. Additionally, the new code parameters are better than the ones available in the literature.     

Long-term diffusive samplers for the indoor air quality evaluation

Three kinds of diffusion samplers, conceived to perform long-term samplings in indoor sites are illustrated in this work. Two of them, in part deriving from the previous "Analyst for VOC" device, extend the field of application up to the semi-volatile organic compounds (SVOC), PAHs and nicotine in particular. A third device, which employs a basic barium hydroxide solution as an absorbing medium, is proposed for the determination of carbon dioxide levels which indicate the air change quality in the indoor sites. Laboratory and field experiments, performed in order to assess the reliability of the proposed devices, are shown. A monthly monitoring campaign, performed at three private apartments in Rome and its outskirts highlights that the indoor pollution levels are a complex function of various concurrent and opposite factors, like external air pollution, internal sources, air change rate and sink effect of surfaces, which contribute to depletion phenomena through adsorption and/or decomposition processes.