全文获取类型
收费全文 | 7326篇 |
免费 | 1345篇 |
国内免费 | 718篇 |
学科分类
数理化 | 9389篇 |
出版年
2024年 | 22篇 |
2023年 | 145篇 |
2022年 | 247篇 |
2021年 | 279篇 |
2020年 | 347篇 |
2019年 | 260篇 |
2018年 | 246篇 |
2017年 | 233篇 |
2016年 | 351篇 |
2015年 | 385篇 |
2014年 | 419篇 |
2013年 | 523篇 |
2012年 | 670篇 |
2011年 | 709篇 |
2010年 | 462篇 |
2009年 | 412篇 |
2008年 | 455篇 |
2007年 | 424篇 |
2006年 | 410篇 |
2005年 | 289篇 |
2004年 | 259篇 |
2003年 | 163篇 |
2002年 | 193篇 |
2001年 | 123篇 |
2000年 | 134篇 |
1999年 | 148篇 |
1998年 | 130篇 |
1997年 | 144篇 |
1996年 | 129篇 |
1995年 | 118篇 |
1994年 | 101篇 |
1993年 | 101篇 |
1992年 | 71篇 |
1991年 | 59篇 |
1990年 | 62篇 |
1989年 | 34篇 |
1988年 | 35篇 |
1987年 | 31篇 |
1986年 | 12篇 |
1985年 | 24篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1916年 | 1篇 |
排序方式: 共有9389条查询结果,搜索用时 0 毫秒
31.
关于不完全双二次非协调板元的误差估计 总被引:1,自引:0,他引:1
本文在[1,2]的基础上,对不完全双二次板元作了进一步的讨论,不仅得到了最优的L~2—误差估计,改进了[1]的相应结果,而且利用“辅助元技巧”并结合正则Green函数法,得到了拟最优的L~∞—误差估计. 相似文献
32.
本利用矩阵对的标准相关分解,得到了矩阵方程(A^TXB,B^TXB)=(C,D)反对称解存在的充分必要条件及通解表达式,同时给出了解关于已知矩阵的最佳逼近. 相似文献
33.
34.
Lanthanide Complexes for Oligomerization of Phenyl Isocyanate 总被引:1,自引:0,他引:1
IntroductionThestudyonthereactivitiesoflanthanidecomplexesto wardisocyanateshasattractedmuchattention .Ithasbeenre portedthatlanthanidealkoxides,1anddivalentdiaza pentadi enyllanthanidecomplexes2 canbeusedasthesinglecompo nentinitiatorsforisocyanatespolymerization .Recentlyourre searchgrouphasalsofoundthatlanthanoceneamide ,3diva lentaryloxideofsamarium4 ,5anddivalentsamarocene6 areallactivefortheoligomerizationofphenylisocyanate,andtheactivespeciesforthesethreesystemswereallsuccessfullyisolat… 相似文献
35.
Wenping Deng Gang Xu Lei Wan Anwen Liu Bo Gao Junhe Du Shuiming Hu Yang Chen 《Acta Physico》2008,24(8):1329-1334
Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied. 相似文献
36.
Ru Ju Wang Feng Ying LiTing Zhang Deng Ji Fang WangHong Chen Chang Qing Jin 《Solid State Communications》2003,127(1):47-50
Using pulse echo overlap measurement, the elastic behavior of amorphous carbon has been studied at ambient and low temperatures. The smaller ratio B/G of the bulk modulus to shear modulus and smaller Poisson's ratio σ at room temperature indicate that there is an intrinsic stiffening of transverse acoustic phonons in the amorphous carbon. The acoustic velocity and attenuation for longitudinal modes have been measured between 2.1 and 300 K at three frequencies of 7, 21 and 35 MHz, respectively. Their frequency and temperature dependence are observed. The elastic constant C11 increases with decreasing temperature and show enhanced stiffening at low temperatures. In the 130-220 K region, the abnormal change and effect of longitudinal velocity and attenuation with temperature and frequency, and a phase transition associated with structure relaxations are discussed. 相似文献
37.
38.
用温度场论方法计算了F-L模型在有限温度和密度下的状态方程,分析了压强对净重子数密度的等温线.结果表明,在平均场近似下,F-L模型所给出的退禁闭相变为一级相变. 相似文献
39.
闪光灯泵浦的Nd:KGd(WO4)2激光器 总被引:1,自引:0,他引:1
报道了用闪光灯泵浦的掺钕的钨酸钆镓(Nd3+:KGd(WO4)2激光器.在重复频率1Hz,脉宽120μs的灯泵下,测量了不同透过率下激光输出能量,获得最大输出能量384mJ,斜率效率1.0%,外推阈值0.54J.在调Q运行时,Nd:KGW晶体的斜率效率为0.16%,最大输出能量46mJ. 相似文献
40.
Zhigang Zhang Jianping Deng Weiguo Zhao Jianmin Wang Wantai Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):500-508
A novel chiral N‐propargylsulfamide monomer ( 1a ) and its enantiomer ( 1b ) were synthesized and polymerized with (nbd)Rh+B?(C6H5)4 as a catalyst providing poly(1) (poly( 1a ) and poly( 1b )) in high yields (≥99%). Poly(1) could take stable helices in less polar solvents (chloroform and THF), demonstrated by strong circular dichroism signals and UV–vis absorption peaks at about 415 nm and the large specific rotations; but in more polar solvents including DMF and DMSO, poly(1) failed to form helix. Quantitative evaluation with anisotropy factor showed that the helical screw sense had a relatively high thermal stability. These results together with the IR spectra measured in solvents showed that hydrogen bonding between the neighboring sulfamide groups is one of the main driving forces for poly(1) to adopt stable helices. In addition, copolymerization of monomer 1a and monomer 2 was conducted, the solubility of poly(1) was improved drastically. However, the copolymerization had adverse effects on the formation of stable helices in the copolymers. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 500–508, 2007 相似文献