The effects of resolution and noise on kinematic features of fine-scale turbulence

The effect of spatial resolution and experimental noise on the kinematic fine-scale features in shear flow turbulence is investigated by means of comparing numerical and experimental data. A direct numerical simulation (DNS) of a nominally two-dimensional planar mixing layer is mean filtered onto a uniform Cartesian grid at four different, progressively coarser, spatial resolutions. Spatial gradients are then calculated using a simple second-order scheme that is commonly used in experimental studies in order to make direct comparisons between the numerical and previously obtained experimental data. As expected, consistent with other studies, it is found that reduction of spatial resolution greatly reduces the frequency of high magnitude velocity gradients and thereby reduces the intermittency of the scalar analogues to strain (dissipation) and rotation (enstrophy). There is also an increase in the distances over which dissipation and enstrophy are spatially coherent in physical space as the resolution is coarsened, although these distances remain a constant number of grid points, suggesting that the data follow the applied filter. This reduction of intermittency is also observed in the eigenvalues of the strain-rate tensor as spatial resolution is reduced. The quantity with which these eigenvalues is normalised is shown to be extremely important as fine-scale quantities, such as the Kolmogorov length scale, are showed to change with different spatial resolution. This leads to a slight change in the modal values for these eigenvalues when normalised by the local Kolmogorov scale, which is not observed when they are normalised by large-scale, resolution-independent quantities. The interaction between strain and rotation is examined by means of the joint probability density function (pdf) between the second and third invariants of the characteristic equation of the velocity gradient tensor, Q and R respectively and by the alignments between the eigenvectors of the strain-rate tensor and the vorticity vector. Gaussian noise is shown to increase the divergence error of a dataset and subsequently affect both the Q–R joint pdf and the magnitude of the alignment cosines. The experimental datasets are showed to behave qualitatively similarly to the numerical datasets to which Gaussian noise has been added, confirming the importance of understanding the limitations of coarsely resolved, noisy experimental data.     

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"Bending to stretching" transition in disordered networks

From polymer gels to cytoskeletal structures, random networks of elastic material are commonly found in both materials science and biology. We present a three-dimensional micromechanical model of these networks and identify a "bending-to-stretching" transition. We characterize this transition in terms of concentration scaling laws, the stored elastic energy, and affinity measurements. Understanding the relationship between microscopic geometry and macroscopic mechanics will elucidate, for example, the mechanical properties of polymer gel networks or the role of semiflexible network mechanics in cells.     

Periodic Solutions for p-Laplacian Neutral Functional Differential Equation with a Deviating Argument

In this paper, by using the continuation theorem of coincidence degree theory and some analysis methods, we study a kind of periodic solutions to p-Laplacian neutral functional differential equation with a deviating argument,some new results on the existence of periodic solutions is obtained.     

Vapor pressure determinations of 8-2 fluorortelomer alcohol and 1-H perfluorooctane by capillary gas chromatography Relative retention time versus headspace methods

Two distinctly different capillary gas chromatographic methods were used to determine the vapor pressure of 8-2 fluorotelomer alcohol (8-2 FTOH) and 1-H perfluoroheptane at several temperatures. For measurements employing the relative retention-time method, a short polymethylsiloxane column was used from 25 to 65 degrees C. For the 8-2 FTOH, hydrocarbon alcohols and perfluoroalcohols were used as reference standards. For 1-H perfluoroheptane, hydrocarbons were used as reference standards. Vapor pressure estimates could differ by as much as an order of magnitude compared to published results determined by other (nonchromatographic) methods. This variance may be a function of solvent-solute interactions within the gas chromatographic column and the infinite dilution assumption, both used in the relative retention method. For comparison, data were also gathered using headspace gas chromatography (GC) with atomic emission detection (AED). The results from this novel GC/AED method were consistent with prior nonchromatographic results. A discussion of why headspace is the preferred technique for the determination of vapor pressure for fluorinated compounds is presented.     

利用有限域上奇异伪辛几何构作具有仲裁的认证码

利用有限域上奇异伪辛几何构作了一个新的具有仲裁的认证码,计算了这个码的参数,当发方编码规则和收方解码规则按等概率分布选取时,计算出各种攻击成功的概率.     

Efficient Hydrolysis of RNA by a PNA - Diethylenetriamine Adduct

The introduction of a urea bond linking a protected diethylenetriamine (DETA) unit and the terminal amino group of a resin-bound peptide nucleic acid (PNA) decamer gave access to a PNA - DETA adduct (shown here), which hydrolyzed the target 25-mer RNA rapidly and sequence specifically.