Structural,vibrational, optical,photoluminescence, thermal,dielectric, and mechanical studies on zinc(tris) thiourea sulfate single crystal: A noticeable effect of organic dye

In this work, uranine-dyed zinc(tris) thiourea sulfate(ZTS) monocrystals, 26 mm×15 mm×10 mm in size, were synthesized by the solution method at ambient temperature. Their purity, crystallinity, lattice parameters, and functional modes were studied by x-ray diffraction, Fourier transform-infrared spectroscopy(FT-IR), and FT-Raman spectroscopy analyses. The sodium ion content of the crystals from the dye was confirmed by elemental analysis. The diffused reflectance spectral analysis of the dyed crystal revealed a characteristic absorption band at 490 nm attributed to the presence of the dye. The calculated band gaps of the non-dyed and dyed crystals were 4.53 and 4.57 e V, respectively. A green emission peak at ～(512 ± 4) nm was observed in the photoluminescence spectrum of the uranine-dyed crystals. A differential scanning calorimetry study confirmed that the thermal stability improved owing to the addition of the dye. Dielectric and microhardness studies were conducted to examine the significant improvements in the corresponding properties of dyed crystals. The results demonstrated the competency of the dyed ZTS crystals for applications in optoelectronic devices.     

光学实验教学法的改进

对光学实验教学法做了一些改进：1)将单个光学实验划分为相对独立的单元，每个单元用不同的实验方法研究一个待测的物理量或观察分析一个物理现象；2)加强预习报告要求；3)以调整仪器为主的操作考核。     

城市下水污泥和煤/LPG在循环流化床上的混烧试验研究

在高6000 mm、直径300mm的循环流化床上进行了含水率为79％的湿污泥与煤／石油液化气(LPG)的混烧试验。试验结果表明:无论用煤还是LPG作为辅助燃料,试验都能在设定的工况条件下稳定运行;向炉内加入石灰石的量达到钙硫摩尔比为3．4∶1时,二氧化硫和氯化氢的排放达标,脱硫效率和脱氯效率分别为75％和94％;在试验中, 烟气中NOx排放、烟气中汞含量和二恶英类排放都不超标;试验产生的飞灰含碳量低,飞灰中痕量元素的浸出毒性不超标;计算表明,如果利用余热干燥污泥和预热空气可有效地减少辅助燃料的消耗量。     

Two-particle correlations in 360 GeV/cp p interactions

Two particle correlations of hadrons produced in 360 GeV/cpp interactions are investigated in the transverse plane and in rapidity. The data were obtained at the European hybrid spectrometer equipped with a rapid cycling bubble chamber. The observed transverse and rapidity correlations are compared with the one string LUND-and a two string dual parton-model. These models predict in general stronger correlations in the transverse plane and much weaker correlations in rapidity than found in the data. The LUND-FRITIOF-and multichain dual parton models provide a better reproduction of the data, although the agreement is not yet satisfactory. Only the UA5 cluster model GENCL shows agreement with the data.     

Kinetics and mechanisms of the catalyzed decomposition of hydrogen peroxide by ethylenebis(oxyethylenedinitrilo)tetracetate complex of iron(III)

The rate of decomposition of H₂O₂ in the presence of Fe(III)-y complex (y is ethylenebis(oxyethylenedinitrilo)tetraacetic acid (EGTA) anion) was investigated under variable conditions of pH and temperature, various water-miscible solvents, and different concentrations of H₂O₂, [Fe-y]⁻, and acetate ions. The following rate law holds: Rate = (k₁K₃K₄/[H⁺]) [Fe-y(OH)]²⁻ [H₂O₂] at pH less than 9.80, and Rate = (k₂K₅[H⁺]/K₃) [Fe-y(OH)₂]³⁻[OOH]⁻ at pH above 9.80. The values of k₁K₄and k₂K₅ at 25 °C were found to be 1523 and 0.747 M⁻¹ S⁻¹, respectively. Activation enthalpy and activation entropy for this reaction were determined from Arrhenius plots and found to be ΔH^* = 34.38 K J mol⁻¹ and ΔS^* = −167.2 J K⁻¹ mol⁻¹.     

过氧化氢和磷酸对以亚磷酸作磷源合成SAPO-41和AlPO-41的影响

 考察了以亚磷酸作为磷源合成SAPO-41和AlPO-41时加入过氧化氢或磷酸对生成SAPO-41和AlPO-41的影响. 结果表明,向反应体系中加入过氧化氢或者使用磷酸部分替代亚磷酸,都能明显缩短SAPO-41和AlPO-41的晶化时间. 此外,使用混合磷源还能够降低模板剂的用量,获得小晶粒晶化产物.     

非线性项在零点和无穷远处非渐进增长的高维P-Laplacian半拟线性问题的全局分歧

本文将研究一般区域上高维p-Laplacian方程保号解的存在性:{u(x)=0,x∈ЭΩ,-div(φp(■u))=a(x)φp(u⁺+β(x)φp(u^-)+ra(x)f(u)),x∈Ω,其中Ω是R^N中一个有界且在其边界上光滑的区域,N≥2,1p-2s,a(x)∈C(Ω,(0,+∞)),u⁺=max{u,0},u^-=-min{u,0},a{x},β(x)∈C(Ω);f∈C(R,R)对于s>0,sf(s)>0成立.当f0■(0,∞)或f∞∈(0,∞)(其中f0=_|s|→0limf(s)/φp(s),f∞=_|s|→+∞limf(s)/φp(s)),且r≠0属于一定区间时,可以获得上述高维p-Laplacian方程保号解的存在性.我们用全局分歧技巧和连通序列集取极限的方法获得主要结果.     

Emodinol,beta-glucuronidase inhibiting triterpene from Paeonia emodi

Emodinol, a new oleane type triterpene, has been isolated from the chloroform soluble fraction of Paeonia emodi. The structure 1beta, 3beta, 23-trihydroxyolean-12-en-28-oic acid 1 has been assigned on the basis of spectral studies including 2D NMR. It showed significant beta-glucuronidase inhibitory activity. In addition benzoic acid and 3-hydroxybenzoic acid have also been reported for the first time from this species.