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101.
Ahmed Sadeq Al‐Fatesh Muhammad Awais Naeem Wasim Ullah Khan Ahmed Elhag Abasaeed Anis Hamza Fakeeha 《中国化学会会志》2014,61(4):461-470
Two series of Co and Ni based catalysts supported over commercial (ZrO2, CeO2, and Al2O3) nano supports were investigated for dry reforming of methane. The catalytic activity of both Co and Ni based catalysts were assessed at different reaction temperatures ranging from 500—800 °C; however, for stability the time on stream experiments were conducted at 700 °C for 6 h. Various techniques such as N2 adsorption‐desorption isotherm, temperature‐programmed reduction (H2‐TPR), temperature‐programmed desorption (CO2‐TPD), temperature‐programmed oxidation (TPO), X‐ray diffraction (XRD), thermogravimetric analysis (TGA) were applied for characterization of fresh and spent catalysts. The catalytic activity and stability tests clearly showed that the performance of catalyst is strongly dependent on type of active metal and support. Furthermore, active metal particle size and Lewis basicity are key factors which have significant influence on catalytic performance. The results indicated that Ni supported over nano ZrO2 exhibited highest activity among all tested catalysts due to its unique properties including thermal stability and reducibility. The minimum carbon deposition and thus relatively stable performance was observed in case of Co‐Al catalyst, since this catalyst has shown highest Lewis basicity. 相似文献
102.
采用并流沉淀法分别制备了CuO-CeO2(物质的量比为5:1)、CuO-ZnO(物质的量比为5:4)、CuO-ZnO-CeO2(物质的量比为5:4:1)三组目标催化剂,通过X射线衍射(XRD)、氢气升温还原(H2-TPR)、CO2程序升温脱附(CO2-TPD)、氮气吸附-脱附、X射线光电子能谱(XPS)、N2O滴定表征技术对催化剂的物化性能进行了测试,并在高温高压微催化反应器中对催化剂进行活性评价。研究了CuO-ZnO-CeO2组成对CO2加氢合成甲醇的影响。结果表明,与二组分催化剂相比较,三组分CuO-ZnO-CeO2催化剂物化性能及催化活性发生了很大变化,催化剂表面碱性位增强,热稳定性增强,CuO颗粒粒径变小,铜分散度以及氧空位浓度提高,最终催化活性显著提高。其中,CuO-ZnO-CeO2催化剂中,CuO颗粒粒径为8.2nm,铜的比表面积为68.4m2/g,铜分散度为7.19%,甲醇的选择性和收率分别为48.6%和0.057mmol/(g·min),催化剂活性较好。 相似文献
103.
A new triterpene named as alysinol 3alpha, 22beta-dihydroxyolean-12-ene [structure: see text] along with known compounds usnic acid, methyl 2,4-dihydroxy-3,6-dimethyl benzoate, 3-hydroxy benzoic acid, stigmasterol, poriferasterol and ursolic acid have been isolated from Alysicarpus monolifer. The structure of [structure: see text] has been established through spectroscopic techniques. 相似文献
104.
一种新型磺化聚醚醚酮的合成、表征和性能 总被引:8,自引:0,他引:8
以特丁基对苯二酚、3,3′-二磺酸钠基-4,4′-二氟二苯酮和4,4′-二氟二苯酮为单体,制备了具有高磺化度的聚醚醚酮.该系列聚合物可溶,并具有良好的成膜性.对聚合物及其膜的一些性能进行了研究. 相似文献
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107.
Calculations of the dependence of the electrical resistivity in liquid Ag-Au binary alloy on composition are reported. The structure of the binary alloy is described as a hard-sphere system. A one-parameter local pseudo-potential which incorporates s-d hybridization effects phenomenologically, is employed in the resistivity calculation. A reasonable agreement with experimental trend is observed. 相似文献
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110.
Samah Ben Atia Anis Messaoud Ridha Ben Abdennour 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2018,24(1):26-43
In this paper, an online algorithm is proposed for the identification of unknown time-varying input delay in the case of discrete non-linear systems described by decoupled multimodel. This method relies on the minimization of a performance index based on the error between the real system and the partial internal models outputs. In addition, a decoupled internal multimodel control is proposed for the compensation of discrete non-linear systems with time-varying delay. This control scheme incorporates partial internal model controls. Each partial controller is associated to a specified operating zone of the non-linear system. The switching between these controllers is ensured by a supervisor that contains a set of local predictors. A simulation example is carried out to illustrate the significance of the proposed time-varying delay identification algorithm and the proposed internal multimodel control scheme. 相似文献