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21.
Timothy W. StephensNohelli E. De La Rosa Mariam SaifullahShulin Ye Vicky ChouAmanda N. Quay William E. Acree Jr. Michael H. Abraham 《Fluid Phase Equilibria》2011,309(1):30-35
Data have been compiled from the published literature on the partition coefficients of solutes and vapors into anhydrous sulfolane. The logarithms of the water-to-sulfolane partition coefficients, log P, and gas-to-sulfolane partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values for solutes dissolved in sulfolane to within average standard deviations of 0.14 log units or less. The log P correlation was extended to include the partition of ions by inclusion of a cation-solvent and an anion-solvent term. 相似文献
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L. W. Winkler Acree Brunel C. von Than und M. Matolesy 《Fresenius' Journal of Analytical Chemistry》1915,54(12):603-604
Ohne Zusammenfassung 相似文献
23.
W. Hiltner H. A. Freye R. J. Fosbinder J. W. Schoonover M. Kilpatrick E. F. Chase L. C. Riesch A. Janke F. Sekera G. F. Davidson J. O. Burton H. Matheson S. F. Acree G. Haugaard F. L. Vodret F. Hovorka W. C. Dearing T. Mikawa E. Newbery A. Itano S. Arakawa T. R. Ball W. B. Schmidt K. S. Bergstresser E. Vellinger A. E. Lorch F. Lux W. von Brehmer M. Déribéré A. F. Peters und A. Osol 《Fresenius' Journal of Analytical Chemistry》1935,103(7-8):285-292
Ohne Zusammenfassung 相似文献
24.
An equation previously developed for estimation of the excess thermodynamic properties of multicomponent systems from binary mixing data has been applied to other physical properties through extrathermodynamic properties such as the excess Gibbs free energy of activation for viscous flow, molar refractivity, and exess surface free energy. This equation provides reasonably accurate predictions for viscosity, refractive index and surface tension of ternary and quaternary systems, given the properties of the various binary combinations of the components. The equation also serves quite well as a point-of-departure for mathematical representation of experimental data, in that all of the data considered could be represented within experimental uncertainty with the aid of no more than one adjustable parameter for each multicomponent system. 相似文献
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Laura M. Sprunger Amy Proctor William E. Acree Jr. Michael H. Abraham Nora Benjelloun-Dakhama 《Fluid Phase Equilibria》2008,270(1-2):30-44
Experimental partition coefficient data have been compiled from the published literature for the water/methyl acetate, water/ethyl acetate and water/butyl acetate partition systems, log P data, and for the gas/methyl acetate, gas/ethyl acetate and gas/butyl acetate partition systems, log K data. Application of the Abraham solvation parameter model to the sets of partition coefficients leads to equations that correlate the log P data and log K data to 0.18 log units for the three dry alkyl acetate solvents. Slightly larger deviations were noted for solute partition into both wet ethyl acetate and wet butyl acetate. The derived correlations were validated using training set and test set analyses. 相似文献
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