碱金属和碱土金属促进的Ni/SiO2催化剂上甲烷的二氧化碳重整制合成气

Ni/SiO2 catalysts promoted by alkali metals K and Cs or alkaline earth metals Mg, Ca, Sr and Ba were prepared, characterized by H2-TPR and XRD, and used for the production of synthesis gas via methane reforming with CO2. Though K and Cs promoted Ni catalysts could eliminate coke deposition, the reforming activity of these promoted catalysts was decreased heavily. Mg and Ca promoted Ni/SiO2 catalysts exhibited excellent coke resistance ability with minor loss of the reforming activity of Ni/SiO2. Ba showed poor coke resistance ability and small amount of Sr increased the formation of coke. The possible mechanism of these promoters was discussed.     

由M0.02Cu0.4Mg5.6Al1.98(OH)16CO3 (M=Ru,Re)水滑石为前驱体制备的双金属固体碱催化甘油氢解

采用共沉淀法合成了M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M = Ru,Re)水滑石前驱体,然后经焙烧和还原制备了铜分散度较高的双功能M-Cu/固体碱催化剂.这些双功能催化剂在粗甘油氢解制备丙二醇反应中表现出了很好的催化活性.表征结果证明,M的加入增强了催化剂表面氢的吸附和活化,进而促进了甘油的转化.     

光纤及双光纤扰模器远/近场扰模性能的模拟分析

在高精度视向速度测量系统中,圆形光纤逐渐被多边形光纤替代,结合多边形光纤、透镜和圆形光纤的扰模方案也被陆续提出。通过光线追迹的方法,对圆形、八边形截面的两种光纤以及基于这两种光纤的双光纤扰模器的扰模性能进行了模拟分析。模拟结果表明:虽然圆形光纤有较好的远、近场角向扰模,但是径向扰模效果不佳;八边形光纤的近场径向和角向扰模性能均较优,但远场扰模与圆形光纤没有明显差异;双光纤扰模器能有效提高光纤扰模性能,而使用了八边形光纤的双光纤扰模器的远、近场扰模性能均较优。     

层次分析法在半导体物理实验课成绩评分中的应用

描述了影响半导体物理实验课评分的五个指标 ,介绍了层次分析法的原理 ,并将它应用到半导体物理实验课的评分中 ,建立了完善的、科学的评分方法 .最后列举了对九七级学生的评分实践 ,实践表明这种方法效果良好 .     

The effects of InGaN layer thickness on the performance of InGaN/GaN p-i-n solar cells

InGaN/GaN p-i-n solar cells, each with an undoped In0.12Ga0.88N absorption layer, are grown on c-plane sapphire substrates by metal-organic chemical vapor deposition. The effects of the thickness and dislocation density of the absorp- tion layer on the collection efficiency of InGaN-based solar cells are analyzed, and the experimental results demonstrate that the thickness of the InGaN layer and the dislocation density significantly affect the performance. An optimized InGaN- based solar cell with a peak external quantum efficiency of 57% at a wavelength of 371 nm is reported. The full width at half maximum of the rocking curve of the （0002） InGaN layer is 180 arcsec.     

利用A型原子与光场的纠缠态传送腔场的奇偶相干态的叠加态

根据简并A型三能级原子与单模光场的非共振相互作用系统的改进型有效哈密顿量，利用矩阵方法推导出任意初始情况下原子—光场系统的波函数，通过改变相互作用时间，制备出原子—腔场系统的纠缠态，提出利用原子—腔场系统的纠缠态进行概率传送腔场的奇、偶相干态的叠加态的有效方案，对于振幅很大的单模光场，通过实行Bell态测量，能成功地概率传送腔场的奇偶相干态的叠加态，其成功的总概率为0.25。     

Isolation and Purification of a Novel Long－chain Acyl Catechin from Lipophilic Tea Polyphenols

Llpophilic tea polyphenols (LTP) was prepared by esterification of green tea polyphenols (GTP) with hexadecanoyl chloride. A novel long-chaln acyl catechin was isolated and purified from LTP by high-speed countercurrent chromatography (HSCCC).Its molecular structure was elucidated as epigallocatechin-3-O-gallate-4‘-O-hexadecanate by elemental analysis, IR, MS and ^1H NMR spectra.     

圆形纸层析法的研究Ⅶ.铬酸根、钼酸根、钨酸根和钒酸根的分离

许多作者提出了利用纸层析法分离铬酸根、钼酸根、钨酸根和钒酸根的方案,但都是以上行法和下行法^[1~5],或者是在处理纸^[6,7]上进行展开,比较费时和复杂.作者曾试图利用圆形纸层析法分离,以期快速.结果找出2,4,6-三甲基吡啶-正己醇(正丙醇、异丙醇、正丁醇、异丁醇、正戊醇、或异戊醇)-浓盐酸(1:4:5),和丁酮-8N盐酸-硫脲(10%)(8:1:1)各展开剂都能使上述四离子完成分离,且每展开一次,仅需约2小时,比较省时.     

竞争风险场合一些非参数估计的大样本结果

本文讨论了在竞争风险场合生存曲线的ＰＬ型估计及其相合性和弱收敛性．此外,针对总体中的“豁免”部分,文中提出了一种简单易行的估计,并证明这种估计是相合的且有渐近正态性．