波状膜层全角度偏振分束特性的分析

从能带结构和等频面两方面完整阐述了利用光子晶体实现全角度偏振分束的条件，分析等频面目的在于确保波矢的切向分量保持连续，采用时域有限差分(FDTD)方法模拟了高斯光束在波状膜层中的传播过程，通过对比TE模与TM模在0°—89°不同入射角情况下的振幅透射系数，理论上验证了波状膜层的全角度偏振分束效应. 关键词： 光子晶体 偏振分束 等频面     

原子玻色-爱因斯坦凝聚体对V型三能级原子激光压缩性质的影响

利用格子液体方法对V型三能级原子玻色-爱因斯坦凝聚体与双模压缩相干态光场相互作用系统的哈密顿量进行分析,发现文献中对原子间相互作用部分的处理有不合理之处,从而对该哈密顿量作出了改进并研究了V型三能级原子玻色-爱因斯坦凝聚体与双模压缩相干态光场相互作用系统中原子激光的两个正交分量的压缩性质.研究表明:V型三能级原子玻色-爱因斯坦凝聚体中光场-原子相互作用强度对原子激光的两正交分量的涨落有明显的影响. 关键词： 玻色-爱因斯坦凝聚 V型三能级原子 压缩相干态 压缩原子激光     

压力对聚苯胺导电性的影响

 导电高聚物聚苯胺薄膜经过定向拉伸后，其有序度、电导及跃迁势垒都发生了很大变化。本文研究了准静水压力对定向拉伸前后，聚苯胺薄膜电学性质的影响。发现未定向拉伸的聚苯胺薄膜的电导随压力单调增加，跃迁势垒T₀随压力单调减少，而定向拉伸后的聚苯胺薄膜则在0.47 GPa出现电导的极大值，在0.35~0.71 GPa之间出现T₀的极小值，这个异常行为与聚乙炔、聚噻吩等导电高聚物均不相同。     

La0.33Pr0.34Ca0.33MnO3薄膜的应变效应

采用脉冲激光沉积法分别在(100)LaAlO₃和(100)SrTiO₃基片上生长了La_0.33Pr_0.34Ca_0.33MnO₃薄膜,并通过磁测量和电输运测量对生长在不同基片上的La_0.33Pr_0.34Ca_0.33MnO₃薄膜的物性进行了研究.结果表明,基片和薄膜之间的压应力导致La_{关键词： 钙钛矿锰氧化物 相分离 电荷有序}     

Determination of Thickness of an Inaccessible Thin Film under a Multilayered System from Natural Frequencies

We investigate the relationship between natural frequencies of a multilayered system of different elastic materials and the thickness of the undermost thin film. The natural frequencies are numerically calculated from the reflection coefficient of a sample system of ＂steel-epoxy resin-aluminium-thin polymer＂ with normal incidence. Strain energy ratio is defined and calculated to give the physics explanation why some frequencies are sensitive to thickness of the thin film in certain range. Experiments of three specimens indicate that the measured natural frequencies agree well with the theoretical ones. It is found in our experiments that the ratio of the lowest film thickness to wavelength is about 1/5. The average relative errors for the inverted polymer film thicknesses are found to be 11.8%, -4.8% and -1.3%, respectively.     

Flowrate behavior and clustering of self-driven robots in a channel

In this paper, the collective motion of self-driven robots is studied experimentally and theoretically. In the channel,the flowrate of robots increases with the density linearly, even if the density of the robots tends to 1.0. There is no abrupt drop in the flowrate, similar to the collective motion of ants. We find that the robots will adjust their velocities by a serial of tiny collisions. The speed-adjustment will affect both robots involved in the collision, and will help to maintain a nearly uniform velocity for the robots. As a result, the flowrate drop will disappear. In the motion, the robots neither gather together nor scatter completely. Instead, they form some clusters to move together. These clusters are not stable during the moving process, but their sizes follow a power-law-alike distribution. We propose a theoretical model to simulate this collective motion process, which can reproduce these behaviors well. Analytic results about the flowrate behavior are also consistent with experiments.     

Ultrafast dynamics of three types of simultaneous shockwaves and filament attenuation in femtosecond laser multi-pulse ablation of PMMA

Cylindrical shockwaves inside polymethyl methacrylate(PMMA) generated simultaneously with two hemispherical shockwaves induced by a femtosecond Gaussian beam laser were investigated using an ultrafast pump–probe imaging technique. The evolutions of these three shockwaves with probe delay and incident pulse number have been systematically analyzed. The plasma intensity and filament length in the center of cylindrical shockwave both decayed with pulse number. Moreover, the self-focused filament moved downstream towards the output surface with an increased pulse number. The experimental results and mechanism illustrated that energy deposition was suppressed by a degraded nonlinear effect due to a pre-ablated structure in multi-pulse irradiation.     

基于三维荧光光谱法和PARAFAC对多环芳烃定性定量分析

三维荧光光谱法在研究多环芳烃(PAHs)类物质的荧光信息时起到了重要作用。多环芳烃类物质具有致癌性,难降解性,多由尾气排放,垃圾焚烧产生,危害着人类健康及环境,因此人们不断探索对多环芳烃检测的方法。实验选取多环芳烃中的苊和萘作为检测物质,利用FLS920荧光光谱仪,为避免荧光光谱仪本身产生的瑞利散射影响,设置起始的发射波长滞后激发波长40 nm,设置扫描的激发波长(λex)范围为:200~370 nm,发射波长(λem)范围为:240~390 nm,对多环芳烃进行荧光扫描获取荧光数据,采用三维荧光光谱技术结合平行因子算法对混合溶液中的苊和萘进行定性定量分析。实验选用的苊和萘均购于阿拉丁试剂官网,配制浓度为10 mg·L-1的一级储备液,再将一级储备液稀释,得到苊和萘浓度为0.5,1,1.5,2,2.5,3,3.5,4和4.5 mg·L-1的二级储备液,并将苊和萘进行混合。在进行光谱分析前需要对苊和萘的光谱进行预处理,采用空白扣除法扣除拉曼散射的影响,并采用集合经验模态分解(EEMD)消除干扰噪声。实验测得苊存在两个波峰,位于λex=298 nm,λem=324/338 nm处,萘存在一个波峰,位于λex=280 nm,λem=322 nm处。选用的PARAFAC算法对组分数的的选择很敏感,因此采用核一致诊断法预估组分数,估计值2和3的核一致值都在60%以上,分别对混合样品进行了2因子和3因子的PARAFAC分解,将分解后得到的激发发射光谱数据和各组分浓度数据进行归一化处理,并绘制光谱图,与归一化处理后的真实的激发发射光谱图和各组分浓度图进行对比。同时将PARAFAC得到的混合样本的预测浓度,通过计算回收率(R)和均方根误差(RMSEP)来判定定量分析的准确度。选择2因子时,各混合样品中苊和萘拟合度为95.7%和96.7%,平均回收率分别为101.8%和98.9%,均方根误差分别为0.0187和0.0316;选择3因子时,各混合样品中苊和萘拟合度为95.3%和95.8%,平均回收率分别为97%和102.5%,均方根误差分别为0.033和0.116,由三项指标可得选用2因子进行定性定量分析的效果明显好于选用3因子。分析实验结果表明,基于三维荧光光谱法和PARAFAC算法对混合样品进行定性定量分析,能够有效的判定混合样品的类别,同时能够成功的预测出混合样品的浓度。     

等离子体综合实验仪

介绍了自行研制的等离子体实验仪,用双探针法测量了电子密度随放电电压的变化关系. 采用光谱辅助诊断技术对等离子体原子激发温度沿轴向位置的变化进行比较测量.     

微波辅助萃取加拿大一枝黄花的花中总黄酮的工艺研究

对加拿大一枝黄花的花进行微波处理,考察微波辅助萃取对加拿大一枝黄花的花中总黄酮提取率的影响.以卢丁为标准品,用硝酸铝做显色剂,采用分光光度法在530nm波长处测定了加拿大一枝黄花的花中总黄酮的含量,探讨了料液比、乙醇浓度、微波功率、微波处理时间等因素对加拿大一枝黄花的花中总黄酮提取率的影响.结果表明,在料液比1:10、乙醇浓度70%、微波功率700W、微波处理时间15min最优条件下,加拿大一枝黄花的花中总黄酮的提取率为17.86%.