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Effects of the structural order of canthaxanthin on the Raman scattering cross section in various solvents: A study by Raman spectroscopy and ab initio calculation 下载免费PDF全文
In this work,we measure the Raman scattering cross sections(RSCSs) of the carbon-carbon(CC) stretching vibrational modes of canthaxanthin in benzene,acetone,n-heptane,cyclohexane,and m-xylene.It is found that the absolute RSCS of CC stretching mode of canthaxanthin reaches a value of 10 24 cm 2 ·molecule 1 ·sr 1 at 8×10 5 M,which is 6 orders of magnitude larger than general RSCS(10 30 cm 2 ·molecule 1 ·sr 1),and the RSCSs of canthaxanthin in various solvents are very different due to the hydrogen bond.A theoretical interpretation of the magnetic experimental results is given,which is introduced in a qualitative nonlinear model of coherent weakly damped electron-lattice vibration in the structural order of polyene chains.In addition,the optimal structure and the bond length alternation(BLA) parameter of canthaxanthin are calculated using quantum chemistry calculation(at the b3lyp/6-31g(d,p) level of theory).The theoretical calculations are in good agreement with the experimental results.Furthermore,the combination of Raman spectroscopy and the quantum chemistry calculation study would be a quite suitable method of studying the structures and the properties of the π-conjugated systems. 相似文献
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The effect of an anti-hydrogen bond on Fermi resonance: A Raman spectroscopic study of the Fermi doublet v1-v12 of liquid pyridine 下载免费PDF全文
The effects of an anti-hydrogen bond on the v1 v12 Fermi resonance (FR) of pyridine are experimentally investigated by using Raman scattering spectroscopy. Three systems, pyridine/water, pyridine/formamide, and pyridine/carbon tetrachloride, provide varying degrees of strength for the diluent-pyridine anti-hydrogen bond complex. Water forms a stronger anti-hydrogen bond with pyridine than with formamide, and in the case of adding non-polar solvent carbon tetrachloride, which is neither a hydrogen bond donor nor an acceptor and incapable of forming a hydrogen bond with pyridine, the intermolecular distance of pyridine will increase and the interaction of pyridine molecules will reduce. The dilution studies are performed on the three systems. Comparing with the values of the Fermi coupling coefficient W of the ring breathing mode v1 and triangle mode v12 of pyridine at different volume concentrations, which are calculated according to the Bertran equations, in three systems, we find that the solution with the strongest anti-hydrogen bond, water, shows the fastest change in the v1-v12 Fermi coupling coefficient W with the volume concentration varying, followed by the formamide and carbon tetrachloride solutions. These results suggest that the stronger anti-hydrogen bond-forming effect will cause a greater reduction in the strength of the v1-v12 FR of pyridine. According to the mechanism of the formation of an anti-hydrogen bond in the complexes and the FR theory, a qualitative explanation for the anti-hydrogen bond effect in reducing the strength of the v1 - v12 FR of pyridine is given. 相似文献
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引用方法 :作者 (多位作者间以逗号隔开 ) .题目 .化学通报 ,年 ,卷 :W××× (×××为网络版目次中序号的后三位 )[W 0 1 0 32 ]中性水介质中钙、镁离子对钨酸盐缓蚀机理的影响 Corrosion inhibitionMechanismofTungstateinNeutralAqueousSolutions李 燕 陆 柱 (华东理工大学防腐蚀中心 上海 2 0 0 2 37)用极化曲线法和Auger能谱研究了中性水介质中Ca2 +、Mg2 +离子对钨酸盐缓蚀机理的影响。碳钢极化曲线表明 :在含Cl-和WO42 -的水中 ,添加Ca… 相似文献
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In this Letter, a pair of integrated optoelectronic transceiving chips is proposed. They are constructed by integrating a vertical cavity surface emitting laser unit above a positive-intrinsic-negative photodetector unit. One of the transceiving chips emits light at the wavelength of 848.1 nm with a threshold current of 0.8 mA and a slope efficiency of 0.81 W/A. It receives light between 801 and 814 nm with a quantum efficiency of higher than 70%.On its counterpart, the other one of the transceiving chips emits light at the wavelength of 805.3 nm with a threshold current of 1.1 mA and a slope efficiency of 0.86 W/A. It receives light between 838 and 855 nm with a quantum efficiency of higher than 70%. The proposed pair of integrated optoelectronic transceiving chips can work full-duplex with each other, and they can be applied to single fiber bidirectional optical interconnects. 相似文献
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报道了采用溶胶一凝胶法合成β-BaB2O4纳米粉的方法.该法的特点是反应体系中添加一种表面改性剂HYPO,改变了颗粒的表面状态,防止了氧桥键的形成,从而避免了颗粒的硬团聚.产物经500℃烧结后,β-BaB2O4粉体的平均粒径为70nm,颗粒分布均匀.本文同时对该工艺中引起粉体硬团聚的各个因素作了初步的探讨. 相似文献
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溶液浓度对拉曼光谱线宽和频移影响的实验研究 总被引:2,自引:0,他引:2
将液芯光纤技术用于傅里叶变换拉曼光谱测量中,提高拉曼光谱强度102~104倍.应用该技术,在实验上研究了溶液浓度变化对β-carotene,rhodamine在CS2中的CC键π-π*跃迁拉曼线频移和线宽的影响.实验结果表明,随着浓度降低(1×10-7~1×10-12mol/L),拉曼光谱线峰值发生红移,线宽变窄. 相似文献
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