中国北方地区水体中四环素族抗生素残留现状分析

为了更好了解北方市政污水等水体中四环素族抗生素残留现状,采用固相萃取方法对中国北方地区市政污水样品进行富集和净化,以高效液相色谱-串联质谱法分析样品中四环素族抗生素残留量。在调查的13个污水样品中四环素族抗生素普遍检出,且浓度分别达到四环素1114.27ng/L、土霉素2175.65ng/L、金霉素149.09ng/L和强力霉素187.45ng/L。结果表明,在我国近岸污水排放中依然有大量四环素类抗生素存在,应加强对近岸海洋环境中抗生素残留的监测与管理。     

黑龙江、松花江和嫩江冰坝凌汛发生原因及预报方法

利用1951-2000年水文、气象资料,在对黑龙江、松花江、嫩江发生的特大冰坝的年份监测中分析发现,冰坝发生大多在二江同时发生,个别年份有三江同时发生,并有群发特点。冰坝发生前,秋季降水多,河槽蓄水量多,河流水位高;冬季降雪多、气温低;春季开江期,有明显的降水和升温过程,是冰坝的形成和凌汛发生的重要原因。并且分析冰坝发生前期高空环流形势特点,依此研制了冰坝凌汛预报方法。     

Phytoremediation potential of indigenous plants from Thai Nguyen province, Vietnam

This study was focused on determining Arsenic (As), Lead (Pb), Cadmium (Cd) and Zinc (Zn) in 33 indigenous plants and 12 soil in-situ plant samples in Thai Nguyen Province, Vietnam. The results showed that the soils of surveyed mining areas contained 181.2- 6754.3 mg kg(-1) As, 235.5-4337.2 mg kg(-1) Pb, 0.8- 419 mg kg(-1) Cd and 361.8-17565.1 mg kg(-1) Zn depending on the characteristics of each mining site. These values are much higher than those typical for normal soil. The heavy metal uptake into shoots and roots of 33 indigenous plant species was also determined. Two species of the plants investigated, Pteris vittata L. and Pityrogramma calomelanos L. were As hyperaccumulators, containing more than 0.1% heavy metals in their shoots. Eleusine indica L., Cynodon dactylon L., Cyperus rotundus L. and Equisetum ramosissimum (Vauch) accumulate very high Pb (0.15-0.65%) and Zn (0.22-1.56%) concentration in their roots. Additional experiments to clarify the potential of six these plants as good candidates for phytoremediation of heavy metal pollution soil are being carried out in our laboratory.     

滴水湖水系表层沉积物中多氯联苯残留与风险评价

于2012年,每2个月采集一次上海人工滩涂湖泊——滴水湖水系表层沉积物,对其多氯联苯(PCBs)的残留水平进行了检测和分析.结果表明,研究期间闸外引水河和闸内引水河沉积物中7种PCBs的总量各月间变化较大,且总体呈上升趋势,而滴水湖沉积物中其总量四季变化幅度不大;空间分布上,闸外引水河[(844.74±687.62)ng/g]>闸内引水河[(516.83±645.45)ng/g]>>滴水湖[(81.63±72.18)ng/g].研究区PCBs组成以六氯联苯和七氯联苯为主,其次为五氯联苯和三氯联苯.采用主成分分析法对PCBs进行源解析,结果显示:PCBs污染源中进口电容器中PCBs的迁移占43%,油漆添加剂污染占33%;国产电容器和变压器污染占11%.生态风险评估表明,闸外引水河和闸内引水河沉积物PCBs对生物体的暴露有严重威胁;滴水湖沉积物PCBs对生物体的暴露有一定的潜在威胁.与国内外研究相比,闸外引水河和闸内引水河属于严重污染水平,滴水湖属于中等污染水平,相关部门应加强污染监管.     

飞行器隔热瓦1200℃性能测试中接触热阻影响仿真与验证

目的 建立统一的飞行器隔热材料性能测试标准。方法 利用数值方法对飞行器隔热瓦1 200℃热环境性能测试中的传热模型进行计算。设计3种不同热导率和表面粗糙度的绝热材料隔热性能对比试验。在考虑接触面间凹凸点完全接触导热、接触间隙介质导热和相邻界面辐射传热联合作用时,能够获得与实测数据基本一致的计算结果。结果 试验证明,接触热阻是导致实测数据与理想传热结果相悖的主要原因。获得了接触热阻条件下热扩散系数随传热过程的变化关系,定量得到了相同测试条件下给定的3种不同热导率与粗糙度底部绝热材料对隔热性能测试结果的影响。结论 测试结果存在较大偏差的主要原因是表面粗糙度所致,两接触面在高温条件下更有利于热流传播。研究结果可为飞行器热防护系统设计与性能考核试验方案的确定提供重要参考依据。     

基于小波相关分析框架的大气腐蚀数据挖掘

目的 针对大气腐蚀中腐蚀数据复杂多变且不易于分析的问题,提出一种基于小波的相关分析框架,挖掘腐蚀的变化特征及其影响因素.方法 首先采用小波功率谱确定腐蚀数据的周期波动特征,然后应用小波相干谱分析腐蚀和环境因素的相关强度、超前滞后及正反相关系,最后利用平均小波相干和显著相干百分比筛选出与腐蚀相关程度较高的环境因素.然后以...     

红壤中Cu、Zn、Pb 污染对蔬菜根伸长的抑制效应

采用盆栽试验,研究红壤中不同浓度Cu(0~400 mg/kg),Zn(0~750 mg/kg)和Pb(0~2000 mg/kg)对小白菜,包菜,萝卜,洋葱,番茄和黄瓜根生长的抑制与毒性效应.结果表明,蔬菜对金属的毒性响敏感程度依次是Cu>Zn>Pb.相同浓度下,Cu、Zn、Pb 对番茄和小白菜的根伸长抑制率最大,对黄瓜和萝卜的根伸长抑制率最小,表明番茄和小白菜对Cu、Zn、Pb 的毒性响应最敏感,黄瓜和萝卜则不敏感.蔬菜根长与土壤Cu有效态含量呈显著或极显著负相关(P<0.05, P<0.01),与土壤Zn 有效态含量或土壤Pb 有效态含量呈极显著负相关(P<0.01),表明土壤中重金属有效态含量是影响蔬菜根伸长的重要因素,重金属对蔬菜生长的抑制响应主要是通过有效态来实现.     

Pharmaceutical removal in tropical subsurface flow constructed wetlands at varying hydraulic loading rates

Determining the fate of emerging organic contaminants in an aquatic ecosystem is important for developing constructed wetlands (CWs) treatment technology. Experiments were carried out in subsurface flow CWs in Singapore to evaluate the fate and transport of eight pharmaceutical compounds. The CW system included three parallel horizontal subsurface flow CWs and three parallel unplanted beds fed continuously with synthetic wastewater at different hydraulic retention times (HRTs). The findings of the tests at 2-6 d HRTs showed that the pharmaceuticals could be categorized as (i) efficiently removed compounds with removal higher than 85% (ketoprofen and salicylic acid); (ii) moderately removed compounds with removal efficiencies between 50% and 85% (naproxen, ibuprofen and caffeine); and (iii) poorly removed compounds with efficiency rate lower than 50% (carbamazepine, diclofenac, and clofibric acid). Except for carbamazepine and salicylic acid, removal efficiencies of the selected pharmaceuticals showed significant (p<0.05) enhancement in planted beds as compared to the unplanted beds. Removal of caffeine, ketoprofen and clofibric acid were found to follow first order decay kinetics with decay constants higher in the planted beds than the unplanted beds. Correlations between pharmaceutical removal efficiencies and log K(ow) were not significant (p>0.05), implying that their removal is not well related to the compound's hydrophobicity.     

高危岗位矿工心理倦怠对注意执行功能的影响

为探究心智游移在倦怠和注意执行功能间的作用机制,有效减少由负性心理状态引起的不安全行为,降低人因事故发生率。在文献研究的基础上,引入心智游移,采用SART范式和AX-CPT范式,以问卷筛选出的100位国有煤炭企业高危岗位作业人员为研究对象,讨论倦怠、心智游移和个体注意执行功能之间的关系。研究结果表明:高频AX试次会引起惯性反应偏向,被试者需要更多的时间来维持线索字母A和解决无效线索B与有效探针X之间的冲突;高倦怠矿工比低倦怠矿工的注意执行控制功能更易受到高频心智游移的影响;心智游移在倦怠与注意执行功能间起到调节作用。