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101.
Gas-particle concentration and distribution of n-alkanes and polycyclic aromatic hydrocarbons in the atmosphere of Prato (Italy) 总被引:1,自引:0,他引:1
Air samples were collected in an urban and industrialised area of Prato (Italy) during 2002, as part of a study to identify and measure aliphatic hydrocarbons and polycyclic aromatic hydrocarbons (PAHs). Total concentrations of aliphatic hydrocarbons ranged between 170 and 282ngm(-3) in the gas phase and from 48.9 to 276ngm(-3) in the particulate phase. The average total PAH concentrations (gas+particulate) were 59.4+/-26.5ngm(-3), and both gas and particulate phase PAH concentrations decreased with increasing temperature. Source identification using diagnostic ratios and principal component analysis identified automobile traffic, in particular, the strong influence of diesel fuel burning, as the major PAH source. Gas-particle partition coefficients (K(p)'s) of n-alkane and PAHs were well correlated with the sub-cooled liquid vapour pressure (P(L)(0)) and indicate stronger sorption of PAHs to aerosol particles compared with n-alkanes. 相似文献
102.
D’Anna Alessandra Arrigo Rossella Frache Alberto 《Journal of Polymers and the Environment》2022,30(1):102-113
Journal of Polymers and the Environment - The effect of process parameters on the final properties of a poly-lactic acid (PLA) and polyhydroxybutyrate (PHB) polymer blend filled with nanoclays was... 相似文献
103.
Stoski Adriana Latczuk Izabelli Fiuza Muniz Edvani Curti Almeida Carlos Alberto Policiano 《Journal of Polymers and the Environment》2022,30(7):2955-2963
Journal of Polymers and the Environment - The main objective of this research was to set the experimental conditions needed for the successful synthesis of a composite (PU-UBPFS) made from... 相似文献
104.
Paris Elaine Cristina Malafatti João Otávio Donizette Sciena Camila Rodrigues Junior Luiz Ferreira Neves Zenatti Alessandra Escote Márcia Tsuyama Moreira Ailton José Freschi Gian Paulo Giovanni 《Environmental science and pollution research international》2021,28(19):23731-23741
Environmental Science and Pollution Research - Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study... 相似文献
105.
Zemiani Adriana Boldarini Maria Theresa Bettin Anami Marcelo Hidemassa de Oliveira Edson Fontes da Silva Alessandra Furtado 《Environmental science and pollution research international》2021,28(31):42107-42120
Environmental Science and Pollution Research - The tolerance of Mentha crispa L. (garden mint) cultivated in cadmium-contaminated oxisol for 120 days was analyzed using plant growth variables such... 相似文献
106.
107.
Renato Baciocchi Giulia Costa Elisabetta Di Bartolomeo Alessandra Polettini Raffaella Pomi 《Waste management (New York, N.Y.)》2009,29(12):2994-3003
This work presents the results of a study on accelerated carbonation of incinerator air pollution control residues, with a particular focus on the modifications in the leaching behaviour of the ash. Aqueous carbonation experiments were carried out using 100% CO2 at different temperatures, pressures and liquid-to-solid ratios, in order to assess their influence on process kinetics, CO2 uptake and the leaching behaviour of major and trace elements. The ash showed a particularly high reactivity towards CO2, owing to the abundance of calcium hydroxides phases, with a maximum CO2 uptake of ~250 g/kg. The main effects of carbonation on trace metal leaching involved a significant decrease in mobility for Pb, Zn and Cu at high pH values, a slight change or mobilization for Cr and Sb, and no major effects on the release of As and soluble salts. Geochemical modelling of leachates indicated solubility control by different minerals after carbonation. In particular, in the stability pH range of carbonates, solubility control by a number of metal carbonates was clearly suggested by modelling results. These findings indicate that accelerated carbonation of incinerator ashes has the potential to convert trace contaminants into sparingly soluble carbonate forms, with an overall positive effect on their leaching behaviour. 相似文献
108.
A 180 d laboratory experiment was conducted to investigate the degradation rates of chlorpyrifos (10 and 50 mg kg(-1)) and metalaxyl (100 mg kg(-1)) separately and co-applied in a biomix constituted by topsoil, vine-branches and urban-waste-garden compost. The effect of repeated application of metalaxyl was also investigated. Microbial biomass-C (MBC) content and metabolic quotient (qCO(2)) were measured to evaluate changes in microbial biomass size and activity induced by the presence of the two pesticides. Degradation rate decreased with increasing concentration of chlorpyrifos in all treatments. Metalaxyl half-life was significantly reduced in co-application with chlorpyrifos indicating a synergic interaction between the two pesticides in favour of enhanced degradation rate for metalaxyl but not for chlorpyrifos. Furthermore, repeated application resulted in a sharp reduction of metalaxyl half-life from 37 d after first application to 4 d after third application. MBC content was negatively influenced by the addition of pesticides but it started to recover immediately, in both separate and co-applied treatments, reaching the control value when pesticide residues were about 50% of the initial concentration. The qCO(2) reached a steady-state after about 20 d in separately applied and 40 d in co-applied treatments, indicating a tendency to arrive at a new metabolic equilibrium. In conclusion, the biomix tested has been shown to degrade pesticides relatively fast and to have a microbial community that is varied enough to allow selection of those microorganisms able to degrade metalaxyl and chlorpyrifos. 相似文献
109.
Porewater plays an important role in sediment toxicity assessment using bioassays, but the most reliable extracting method and the potential contribution of confounding factors to the real toxicity need to be studied. The applicability of bioassays with the early life stages of Paracentrotus lividus, Mytilus galloprovincialis and Crassostrea gigas on porewaters extracted by centrifugation from the Venice Lagoon (Italy) is evaluated and demonstrated: toxicity tests can discriminate the toxicity of porewaters from sites with different kinds and levels of pollution and, using toxicity scores, data are classified in five toxicity classes. Sulphides do not represent a confounding factor in porewater toxicity; in contrast ammonia exhibited some concentrations above the toxicity threshold for sea urchin embryos. 相似文献
110.
Monika Schlegel Alessandra Baumer Mariluce Riegel Ute Wiedemann Albert Schinzel 《黑龙江环境通报》2002,22(5):418-421
An Erratum has been published for this article in Prenatal Diagnosis 22(11) 2002: 1056. We report a case of maternal isodisomy 10 combined with mosaic partial trisomy 10 (p12.31-q11.1). Chromosome examinations from a CVS sample showed a karyotype 47,XY,+mar/46,XY. The additional marker chromosome which was present in 6/25 interphase nuclei was shown by fluorescence in situ hybridization (FISH) to have been derived from a pericentromeric segment of chromosome 10. DNA analysis was performed from umbilical cord blood from the fetus after termination of the pregnancy at 18 weeks. The results showed that the two structurally normal chromosomes 10 were both of maternal origin, whereas the marker chromosome derived from the father. Autopsy of the fetus revealed hypoplasia of heart, liver, kidneys and suprarenal glands, but, apart from a right bifid ureter, no structural organ abnormalities. This fetus represents the second reported instance of a maternal uniparental disomy (UPD) 10. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献