Novel Hyperbranched predominantly Alternating Copolymers Made From A Charge Transfer Complex monomer pair of p-(chloromethyl)styrene and Acrylonitrile via Controlled Living Radical Copolymerization

Summary Novel hyperbranched copolymers were successfully synthesized by the controlled charge transfer complex inimer and living radical copolymerization of p-(chloromethyl)styrene (PCMS) and acrylonitrile (AN). The resulting copolymers were characterized by SEC, NMR, FTIR, DSC and elemental analysis etc.. The influences of reaction conditions, such as the polymerization temperature, the catalyst (CuBr) concentration and the monomer ratio, on the resulting copolymers were investigated in detail. The monomer reactivity ratios were evaluated to be r_PCMS=0.937 and r_AN=0.088 respectively by the Fineman-Ross method. The higher are the polymerization temperature and the ratio of catalyst to monomer, the higher is the branching degree of the resulting copolymer. When the amount of monomer AN was used in excess than that of the monomer PCMS in the raw feed, the hyperbranched predominantly alternating copolymers HP[PCMS-co-AN] could be obtained. These hyperbranched copolymers were successfully used as functional macroinitiators to synthesize the star-shaped poly(PCMS-co-AN)/poly(MMA) block copolymers.     

多级网络多处理机系统的性能评估

本文建立了多级网络(δ-网)多处理机系统的马尔柯夫模型,为系统结构参数和任务粒度的选择提供了依据。文中分析了处理机数目、网络结构参数和任务粒度对系统性能的影响,并对模型计算结果和仿真结果作了比较。     

微波仪器远程自动测试系统的设计与实现

针对大多通信测试仪器仅局限于本地测试监控的现状,提出了一种将本地测试仪器用于对远程微波设备进行测试监控的开发模式,从而实现了远程仪器的自动化测试。分别就系统中的关键技术和交互方式作了详细的介绍,得出系统具有较强的可扩展性,且简单易操作的特点,相信该系统会有广阔的的应用前景。     

Higher order soliton pulse compression in dispersion-decreasingoptical fibers

Compression of higher order optical solitons in fibers with anomalous dispersion decreasing along their length is investigated. We demonstrate high-quality compression of pulses with initial soliton order 1相似文献   

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Multiple negative-differential-resistance (MNDR) phenomena of ametal-insulator-semiconductor-insulator-metal (MISIM)-like structurewith step-compositioned InxGa1-xAs quantum wells

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