Evaluation of the Residual Mass Fractionation in High-Precision Cr Isotopic Analysis with TIMS

The Cr isotope ratios of terrestrial and extra-terrestrial materials are emerging as one of the most important tracers in geosciences. Previous studies on Cr isotopic measurements using TIMS have found that there is residual Cr isotopic fractionation between the mass-fractionation-corrected ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios, which may cause an offset of obtained ratios from the reference values. The residual fractionation was thought to be caused by the evaporation of Cr-oxide species during thermal ionisation, but the mechanism by which this residual fractionation could be reduced remained unclear. Here we revisit the issue of residual fractionation and propose that this problem can be alleviated by utilising W filaments instead of conventionally used Re filaments for Cr ionisation. Using W filaments, the formation of CrO⁺ was suppressed during heating as the filament temperature was ~ 100 °C lower than when Re filaments were used. In repeated measurement of a carbonaceous chondrite, the intermediate precisions of ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios in the W filament runs were two to three times better than those of the Re filament runs. Therefore, the new finding of this study will be of key importance for future studies of Cr isotopes for terrestrial and extra-terrestrial materials.     

Hydrometeorological behaviour of pine and larch forests in eastern Siberia

Seasonal changes in the water and energy exchanges over a pine forest in eastern Siberia were investigated and compared with published data from a nearby larch forest. Continuous observations (April to August 2000) were made of the eddy‐correlation sensible heat flux and latent heat flux above the canopy. The energy balance was almost closed, although the sum of the turbulent fluxes sometimes exceeded the available energy flux (R_n ? G) when the latent heat flux was large; this was related to the wind direction. We examined the seasonal variation in energy balance components at this site. The seasonal variation and magnitude of the sensible heat flux (H) was similar to that of the latent heat flux (λE), with maximum values occurring in mid‐June. Consequently, the Bowen ratio was around 1·0 on many days during the study period. On some clear days just after rainfall, λE was very large and the sum of H and λE exceeded R_n ? G. The evapotranspiration rate above the dry canopy from May to August was 2·2 mm day^?1. The contributions of understory evapotranspiration (E_u) and overstory transpiration (E_o) to the evapotranspiration of the entire ecosystem (E_t) were both from 25 to 50% throughout the period analysed. These results suggest that E_u plays a very important role in the water cycle at this site. From snowmelt through the tree growth season (23 April to 19 August 2000), the total incoming water, comprised of the sum of precipitation and the water equivalent of the snow at the beginning of the melt season, was 228 mm. Total evapotranspiration from the forest, including interception loss and evaporation from the soil when the canopy was wet, was 208–254 mm. The difference between the incoming and outgoing amounts in the water balance was from +20 to ?26 mm. The water and energy exchanges of the pine and larch forest differed in that λE and H increased slowly in the pine forest, whereas λE increased rapidly in the larch forest and H decreased sharply after the melting season. Consequently, the shape of the Bowen ratio curves at the two sites differed over the period analysed, as a result of the differences in the species in each forest and in soil thawing. Copyright © 2003 John Wiley & Sons, Ltd.     

Effects of riverbed incision on the hydrology of the Vietnamese Mekong Delta

The hydrogeomorphology of the Vietnamese Mekong Delta (VMD) has been significantly altered by natural and anthropogenic drivers. In this study, the spatiotemporal changes of the flow regime were examined by analysing the long-term daily, monthly, annual and extreme discharges and water levels from 1980 to 2018, supported by further investigation of the long-term annual sediment load (from the 1960s to 2015), river bathymetric data (in 1998, 2014 and 2017) and daily salinity concentration (from the 1990s to 2015) using various statistical methods and a coupled numerical model. Then, the effects of riverbed incision on the hydrology were investigated. The results show that the dry season discharge (i.e., in March–June) of the Tien River increased by up to 23% from the predam period (1980–1992) to the postdam period (1993–2018) but that the dry season water level at My Thuan decreased by up to −46%. The annual mean and monthly water levels in June at Tan Chau and in January and June–October at My Thuan in the Tien River decreased statistically, even though the respective discharges increased significantly. These decreased water levels instead of the increased discharges were attributed to the accelerated riverbed incision upstream from My Thuan, which increased by more than three times, from a mean rate of −0.16 m/year (−16.7 Mm³/year) in 1998–2014 to −0.5 m/year (−52.5 Mm³/year) in 2014–2017. This accelerated riverbed incision was likely caused by the reduction in the sediment load of the VMD (from 166.7 Mt/year in the predam period to 57.6 Mt/year in the postdam period) and increase in sand mining (from 3.9 Mm³ in 2012 to 13.43 Mm³ in 2018). Collectively, the decreased dry season water level in the Tien River is likely one of the main causes of the enhanced salinity intrusion.     

Dune-forming winds on Titan and the influence of topography

Numerous extended dunes on Saturn's moon Titan detected by the Cassini RADAR constrain the long-term pattern of surface winds. We analyse the statistics of surface wind speed and direction and their spatial and temporal variability predicted by a general circulation model (GCM) in order to constrain surface wind predictions of this GCM by dune observations. The model shows that modern winds are sufficient for saltation and dune formation at low latitudes, in agreement with the presence of dunes there. The best condition for the dune-forming wind occurs with a threshold friction speed of 0.02 m s⁻¹ or slightly less. The equatorial region is conducive to longitudinal dunes because of a combined effect of a high sand drift potential and obtuse bimodal wind pattern oblique to the equator caused by the seasonal reversal of the Hadley circulation. The cross-equatorial wind is steady, and is characterised by a high Weibull shape parameter (k∼4). The wind pattern at higher latitudes is more complex and gusty, and neither longitudinal nor transversal dunes would be able to form. Putative large-scale topography is found to have a profound influence on the near-surface wind pattern. Generally mountains cause a convergence and speeding up on the flank, while basins weaken the wind and cause a divergent flow. Longitudinal dunes can be deflected on the foot of mountains by up to 90°. If Xanadu is a hypothetical large mountain, a wind pattern converging in Xanadu that entirely disagrees with the dune observations is predicted. If instead Xanadu is a large basin, the wind arcs clockwise north of Xanadu and anti-clockwise west and southwest of Xanadu, in agreement with the dune orientations in the vicinity of Xanadu. The albedo pattern has comparatively little influence on the wind field. Isolated mountain chains cause only local-scale change in the wind pattern. However, the persistent surface easterlies in Belet, which are in conflict with the dune orientations, do not disappear by any combination of large-scale topography.     

Development of partial factor design method on bending strength of piles for Japanese Specifications for Highway Bridges

ABSTRACT

This paper describes the development of a partial factor design method on the bending strength of piles for the Japanese Specifications for Highway Bridges. First, uncertainties in mobilised bending moments and yield bending moments were evaluated by Monte Carlo simulations. Second, the reliability of piles designed by the previous specifications were evaluated on the basis of reliability analysis considering uncertainties in the mobilised bending moments, yield bending moments, and other factors. Finally, a partial factor design method utilising a survey subsurface investigation method and ground type was developed to reach target reliability levels determined by the Standards.     

Meltwater discharge during the Holocene from the Wilkes subglacial basin revealed by beryllium isotope analysis of marine sediments

Understanding Antarctic Ice Sheet dynamics related to global climate change is of scientific and societal interest as the future behaviour of the ice sheet under the currently changing climate is unknown. We present beryllium‐10 (¹⁰Be) analysis of a high‐resolution marine sediment core from the Adélie Basin near the eastern Wilkes Land margin, which is susceptible to marine ice sheet instability due to the low‐lying nature and down‐sloping trough of the Wilkes Subglacial Basin. Combined with a newly constructed age model using compound specific radiocarbon dates, the data reveal three events associated with high meteoric ¹⁰Be at ca. ~10 ka, ca. ~6.5 ka and from ca. ~4 ka. We interpret these high meteoric ¹⁰Be events to be derived from the deposition of ¹⁰Be released from the ice sheet during meltwater discharge. In particular, the shift to higher meteoric ¹⁰Be concentration at~4 ka may correspond to changes in climate patterns at this time. Copyright © 2019 John Wiley & Sons, Ltd.     

Radionuclides produits par le rayonnement cosmique dans la météorite Saint-Séverin

]The activities of 18 radionuclides in 4 samples from the Saint-Séverin meteorite have been measured after chemical separation. The results show that the DI sample from the D piece has been less irradiated than the samples B₂, B₃ and B₄ from the B piece. This is based on activities of isotopes produced both by spallation as ²⁶Al, ⁵³Mn, ⁵⁴Mn, ⁵⁵Fe, ⁵⁷Co and by thermal neutron capture as ⁵⁹Ni and ⁶⁰Co.Comparison of experimental values to calculated production rates suggests that the D piece was connected to the main body of the meteorite by a small surface, and that the DI sample in this piece was opposite to the main body of the meteorite.     

Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

New Late Jurassic palaeomagnetic data from the northern Sichuan basin: implications for the deformation of the Yangtze craton

Upper Jurassic red sandstones and red siltstones were collected from 67 layers at 12 localities in the Penglaizhen formation. This formation is in the north of Bazhong county (31.8°N, 106.7°E) in the Sichuan basin, which is located in the northern part of the Yangtze craton. Thermal demagnetization isolated a high-temperature magnetic component with a maximum unblocking temperature of about 690 °C from 45 layers. The primary nature of the magnetization acquisition is ascertained through the presence of magnetostratigraphic sequences with normal and reversed polarities, as well as positive fold and reversal tests at the 95 per cent confidence level. The tilt-corrected mean direction of 36 layers is D = 20.0°, I = 28.8° with α ₉₅ = 5.8°. A Late Jurassic palaeomagentic pole at 64.7°N, 236.0°E with A ₉₅ = 7.0° is calculated from the palaeomagnetic directions of 11 localities. This pole position agrees with the two other Late Jurassic poles from the northern part of the Yangtze craton. A characteristic Late Jurassic pole is calculated from the three poles (68.6°N, 236.0°E with A ₉₅ = 8.0°) for the northern part of the Yangtze craton. This pole position is significantly different from that for the southern part of the Yangtze craton. This suggests that the southern part of the Yangtze craton was subjected to southward extrusion by 1700 ± 1000  km with respect to the northern part. Intracraton deformation occurred within the Yangtze craton.     

Sediment transport in high‐speed flows over a fixed bed: 2. Particle impacts and abrasion prediction

Single bed load particle impacts were experimentally investigated in supercritical open channel flow over a fixed planar bed of low relative roughness height simulating high‐gradient non‐alluvial mountain streams as well as hydraulic structures. Particle impact characteristics (impact velocity, impact angle, Stokes number, restitution and dynamic friction coefficients) were determined for a wide range of hydraulic parameters and particle properties. Particle impact velocity scaled with the particle velocity, and the vertical particle impact velocity increased with excess transport stage. Particle impact and rebound angles were low and decreased with transport stage. Analysis of the particle impacts with the bed revealed almost no viscous damping effects with high normal restitution coefficients exceeding unity. The normal and resultant Stokes numbers were high and above critical thresholds for viscous damping. These results are attributed to the coherent turbulent structures near the wall region, i.e. bursting motion with ejection and sweep events responsible for turbulence generation and particle transport. The tangential restitution coefficients were slightly below unity and the dynamic friction coefficients were lower than for alluvial bed data, revealing that only a small amount of horizontal energy was transferred to the bed. The abrasion prediction model formed by Sklar and Dietrich in 2004 was revised based on the new equations on vertical impact velocity and hop length covering various bed configurations. The abrasion coefficient k_v was found to be vary around k_v ~ 10⁵ for hard materials (tensile strength f_t > 1 MPa), one order of magnitude lower than the value assumed so far for Sklar and Dietrich's model. Copyright © 2017 John Wiley & Sons, Ltd.