Mineralogy and geochemistry of banded iron formation and iron ores from eastern India with implications on their genesis

The geological complexities of banded iron formation (BIF) and associated iron ores of Jilling-Langalata iron ore deposits, Singhbhum-North Orissa Craton, belonging to Iron Ore Group (IOG) eastern India have been studied in detail along with the geochemical evaluation of different iron ores. The geochemical and mineralogical characterization suggests that the massive, hard laminated, soft laminated ore and blue dust had a genetic lineage from BIFs aided with certain input from hydrothermal activity. The PAAS normalized REE pattern of Jilling BIF striking positive Eu anomaly, resembling those of modern hydrothermal solutions from mid-oceanic ridge (MOR). Major part of the iron could have been added to the bottom sea water by hydrothermal solutions derived from hydrothermally active anoxic marine environments. The ubiquitous presence of intercalated tuffaceous shales indicates the volcanic signature in BIF. Mineralogical studies reveal that magnetite was the principal iron oxide mineral, whose depositional history is preserved in BHJ, where it remains in the form of martite and the platy hematite is mainly the product of martite. The different types of iron ores are intricately related with the BHJ. Removal of silica from BIF and successive precipitation of iron by hydrothermal fluids of possible meteoric origin resulted in the formation of martite-goethite ore. The hard laminated ore has been formed in the second phase of supergene processes, where the deep burial upgrades the hydrous iron oxides to hematite. The massive ore is syngenetic in origin with BHJ. Soft laminated ores and biscuity ores were formed where further precipitation of iron was partial or absent.     

Phase transitions in ilvaite,a mixed-valence iron silicate I. A 57Fe Mössbauer study of magnetic order and spin frustration

Ilvaite, Ca(Fe²⁺,Fe³⁺)Fe²⁺Si₂O₈(OH) shows two magnetic phase transitions, which have been studied by Mössbauer spectroscopy within the temperature range 120–4 K. The continued charge localization between Fe²⁺ and Fe³⁺ ions in octahedral A-sites causes the Fe²⁺-Fe³⁺ interaction to be ferromagnetic, although the overall magnetic order is antiferromagnetic. The thermal evolution of the hyperfine fields at the Fe²⁺ (A) and Fe³⁺ (A) sites indicates B _hf: 328 and 523 kOe respectively at 0 K and T _N1= 116K. The corresponding values for Fe²⁺ (B) site are: B _hf 186 kOe and T _N2=36K. An additional hyperfine field exists at the Fe²⁺(B) site within the temperature range 116–36K due to short-range order induced by the spin ordering in A sites. The considerable difference between the two magnetic transition temperatures is due to spin frustration, because the Fe²⁺ (B) site occurs on a corner common between two triangles with respect to two sets of Fe²⁺ (A) and Fe³⁺ (A) sites with opposite spin directions.     

Empirical calculation of roll damping for ships and barges

For a large floating structure in waves, the damping is computed by the linear diffraction/radiation theory. For most degrees of freedom, this radiation damping is adequate for an accurate prediction of the rigid body motions of the structure at the wave frequencies. This is not particularly true for the roll motion of a long floating structure. For ships, barges and similar long offshore structures, the roll damping is highly nonlinear. In these cases the radiation damping is generally quite small compared to the total damping in the system. Moreover, the dynamic amplification in roll may be large for such structures since the roll natural period generally falls within the frequency range of a typical wave energy spectrum experienced by them. Therefore, it is of utmost importance that a good estimate of the roll damping is made for such structures. The actual prediction of roll damping is a difficult analytical task. The nonlinear components of roll damping are determined from model and full scale experiments. This paper examines the roll damping components and their empirical contributions. These empirical expressions should help the designer of such floating structures. The numerical values of roll damping components of typical ships and barges in waves and current (or forward speed) are presented.     

Long waves due to a symmetrical wind stress on the surface of a rotating ocean

Abstract

The problem of unsteady long waves generated by any horizontal and symmetrically distributed, time-periodic surface wind on a rotating ocean is analysed for large times and distances. Uniform asymptotic estimates of the surface displacement in the unsteady state are obtained. The steady-state wave and velocity fields at any distance are also determined. Some characteristics of the unsteady and steady motions are described. Also noted are the features that distinguish the motion from its one-dimensional analogue for which a non-uniform analysis in the unsteady state along with a large-distance form of the surface elevation are already known.     

Line-of-Sight Anisotropies in the Cosmic Dawn and Epoch of Reionization 21-cm Power Spectrum

The line-of-sight direction in the redshifted 21-cm signal coming from the cosmic dawn and the epoch of reionization is quite unique in many ways compared to any other cosmological signal. Different unique effects, such as the evolution history of the signal, non-linear peculiar velocities of the matter etc. will imprint their signature along the line-of-sight axis of the observed signal. One of the major goals of the future SKA-LOW radio interferometer is to observe the cosmic dawn and the epoch of reionization through this 21-cm signal. It is thus important to understand how these various effects affect the signal for its actual detection and proper interpretation. For more than one and half decades, various groups in India have been actively trying to understand and quantify the different line-of-sight effects that are present in this signal through analytical models and simulations. In many ways the importance of this sub-field under 21-cm cosmology have been identified, highlighted and pushed forward by the Indian community. In this article, we briefly describe their contribution and implication of these effects in the context of the future surveys of the cosmic dawn and the epoch of reionization that will be conducted by the SKA-LOW.     

Modelling the 21-cm Signal from the Epoch of Reionization and Cosmic Dawn

Studying the cosmic dawn and the epoch of reionization through the redshifted 21-cm line are among the major science goals of the SKA1. Their significance lies in the fact that they are closely related to the very first stars in the Universe. Interpreting the upcoming data would require detailed modelling of the relevant physical processes. In this article, we focus on the theoretical models of reionization that have been worked out by various groups working in India with the upcoming SKA in mind. These models include purely analytical and semi-numerical calculations as well as fully numerical radiative transfer simulations. The predictions of the 21-cm signal from these models would be useful in constraining the properties of the early galaxies using the SKA data.     

PGE geochemistry of low-Ti high-Mg siliceous mafic rocks within the Archaean Central Indian Bastar Craton: implications for magma fractionation

Boninite-norite (BN) suites emplaced in an intracratonic setting in Archaean Cratons, are reported from many parts of the world. Such high-Mg low-Ti siliceous rocks are emplaced during Neoarchaean-Paleoproterozoic. The Archaean central Indian Bastar Craton also contains such a boninite-norite suite, which occurs in the form of dykes and volcanics. The spatial and temporal correlation of these high-Mg low-Ti siliceous rocks with similar rocks occurring around the northern Bastar and Dharwar Cratons probably represent a Bastar-Dharwar Large Igneous Province during the Neoarchaean-Paleoproterozoic. Platinum group element (PGE) abundances in these rocks provide constraints on their geochemical evolution during the Neoarchaean-Paleoproterozoic. The PGE geochemistry of the boninite-norite suite from the southern part of the central Indian Bastar Craton is presented to understand their behaviour during magma fractionation. In primitive mantle-normalized plots all samples have similar PGE fractionated patterns that are enriched in Pd, Pt and Rh relative to Ru. The Pd/Ru ratios for eight samples range from 2.0 to 7.0 which is higher than primitive mantle (primitive mantle Pd/Ru ≈1.2). The Pd/Pt ratios range between 0.2–2.5 with an average value of 0.7 which is near chondritic (primitive mantle Pd/Pt ≈0.5). PGE variations in these rocks together with those of major and other trace elements are consistent with a model involving olivine fractionation along with chromite as a cotectic phase. The Pt fractionation from Pd and Rh is controlled by both olivine and chromite crystallization at an early stage during high temperature crystal fractionation when the Pt was strongly compatible and Pd and Rh were incompatible. Strong negative correlations of the S content with iron and TiO₂ plus lithophile element contents of the rock suggest a decrease of the S solubility in the parental high-Mg magma and separation of an immiscible sulfide liquid with decreasing temperature. Palladium plus other available chalcophile elements (e.g., Re, Au, Ag) have been fractionated in this immiscible sulfide liquid after considerable olivine fractionation of the magma.     

Studies of accretion flows around rotating black holes – I. Particle dynamics in a pseudo-Kerr potential

We study the formation of the absorption features, called the cyclotron–annihilation lines, in the γ-spectra of the neutron stars (pulsars), owing to the fundamental quantum-electrodynamic effect of the one–photon pair creation in magnetized vacuum. As a result, we substantiate a new method for the determination of the neutron star magnetic fields B based on measuring the interval between the main annihilation and the first cyclotron–annihilation absorption lines. It is found that these lines may be easily resolved, and, consequently, the method is surely applicable if the following conditions are satisfied. (i) A γ-source has to be compact enough and located near a star, but not close to its magnetic poles. For instance, it may be a disc in the plane of a star magnetic equator with latitudinal angular width less than     and radial extent up to 25 per cent of the star radius. (ii) The source is to produce detectable γ-radiation at large angles ≳60° to the local magnetic field. Being situated in a closed field line region and having a broad radiation pattern, such a source is not what is usually considered in the context of the polar cap and outer gap models of the pulsar γ-emission dealing with open field lines only. (iii) Magnetic field strength must lie in a certain narrow interval with the centre at  ∼(3–4) × 10¹²  G. Its width depends on the star orientation and disc radial extend and in the most favourable case is about 20–30 per cent of its lower boundary. Finally, the influence of the star rotation on this method employment is considered and new possibilities arising from forthcoming polarization observations are briefly discussed.     

Cultural and economic residential sorting of Auckland’s population, 1991–2013: an entropy approach

Journal of Geographical Systems - Auckland, the largest city of New Zealand, is one of the most diverse cities in the world, with more than 40% of its population born abroad, more than 200...