Groundwater flow and contaminant transport modelling at an air weapons range

Numerical modelling was done at the Cold Lake Air Weapons Range, Canada, to test whether the dissolved RDX and nitrate detected in groundwater come from the same sources, and to predict whether contamination poses a threat to the surface water receptors near the site. Military live fire training activities may indeed pose a risk of contamination to groundwater resources, however field investigations on military bases are quite recent, and little information is available on the long-term behaviour of munition residues related contaminants. Very limited information was available about the contaminant source zones, which were assigned based on our knowledge of current training activities. The RDX plume was well represented with the model, but the heterogeneous distribution of nitrate concentrations was more difficult to reproduce. It was nonetheless determined that both contaminants originate from the same areas. According to the model, both contaminants should reach the nearby river, but concentrations in the river should remain very low if the source zone concentration does not change. Finally, the model allowed the recommendation of a new location for the main bombing target, which would offer added protection to the river and the lake into which it flows.     

Effects of wave–current interaction on the current profile

Wave–current laboratory experiments have shown that the logarithmic current profile observed in pure current flows is modified due to the presence of waves. When waves propagate opposite the current, an increase in the current intensity is achieved near the mean water level, while a reduction is obtained for following waves and currents. With the aim of analyzing these nonlinear effects along the whole water column, an Eulerian wave–current model is presented. In contrast to previously presented wave–current models, the present is able to include the variation of the free surface elevation due to the wave motion and the effect of a non hydrostatic pressure field. Therefore it does not restrict its application to waves in shallow waters. Moreover, the model is able to simulate all the possible angles between waves and currents.     

Preboreal climatic oscillations recorded by pollen and foraminifera in the southern Adriatic Sea

Core SA03-1 from the southern Adriatic Sea (EC-Eurostrataform project) provides new information about climate changes and palaeocirculation in the Adriatic region during the last deglaciation. The results of an integrated study based on pollen and foraminifera records of the part of the core spanning the late Pleistocene–early Holocene transition (including the late Younger Dryas, the Preboreal and the beginning of the Boreal) are presented. The major vegetation changes and the short-term oscillations occurred during the early Holocene warming in the southern Adriatic basin on the basis of a high-resolution pollen record are documented. Vegetation changes are correlated to short-term oscillations detected in the foraminifera record during the same interval. The two independent terrestrial and marine proxies indicate at least three short-term cold and dry oscillations occurring at 11.2–11, 10.8–10.4 and 10 cal ka BP, according to the age–depth model adopted in this study. Finally, adopting an event-stratigraphy approach, the comparison of these results with two western Mediterranean records of Preboreal short-term oscillations suggest the occurrence of synchronous bio-events in the Mediterranean basin.     

Global changes in extreme events: regional and seasonal dimension

This study systematically analyzes the complete IPCC AR4 (CMIP3) ensemble of GCM simulations with respect to changes in extreme event characteristics at the end of the 21st century compared to present-day conditions. It complements previous studies by investigating a more comprehensive database and considering seasonal changes beside the annual time scale. Confirming previous studies, the agreement between the GCMs is generally high for temperature-related extremes, indicating increases of warm day occurrences and heatwave lengths, and decreases of cold extremes. However, we identify issues with the choice of indices used to quantify heatwave lengths, which do overall not affect the sign of the changes, but strongly impact the magnitude and patterns of projected changes in heatwave characteristics. Projected changes in precipitation and dryness extremes are more ambiguous than those in temperature extremes, despite some robust features, such as increasing dryness over the Mediterranean and increasing heavy precipitation over the Northern high latitudes. We also find that the assessment of projected changes in dryness depends on the index choice, and that models show less agreement regarding changes in soil moisture than in the commonly used ‘consecutive dry days’ index, which is based on precipitation data only. Finally an analysis of the scaling of changes of extreme temperature quantiles with global, regional and seasonal warming shows that much of the extreme quantile changes are due to a seasonal scaling of the regional annual-mean warming. This emphasizes the importance of the seasonal time scale also for extremes. Changes in extreme quantiles of temperature on land scale with changes in global annual mean temperature by a factor of more than 2 in some regions and seasons, implying large changes in extremes in several countries, even for the commonly discussed global 2°C-warming target.     

Subduction erosion of forearc mantle wedge implicated in the genesis of the South Sandwich Island (SSI) arc: Evidence from boron isotope systematics

The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ¹¹B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ¹¹B is roughly positively correlated with B concentrations and with ⁸⁷Sr/⁸⁶Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ¹¹B (ca. + 10‰) and elevated B contents (38–140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ¹¹B (+ 5 to ? 13‰; average = ? 4.1‰), with negative values most common. The unusually high δ¹¹B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ¹¹B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely ¹¹B-rich fluids at slab depths beneath the volcanic arc. Infiltration of such fluids into the mantle wedge likely accounts for the unusual magma sources inferred for this arc.     

Rb/Sr dating of the Upper Proterozoic basement of Zambesia,Mozambique

The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.

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Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.

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Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.

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Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.     

Sulfur Determination in Geological Samples Based on Coupled Analytical Techniques: Electric Furnace-IC and TGA-EGA

A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO₃, Cu, W and V₂O₅) and sample/catalyst ratio, and the detection limit was 10 μg g⁻¹. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.     

A multi-physics ensemble of present-day climate regional simulations over the Iberian Peninsula

This work assesses the influence of the model physics in present-day regional climate simulations. It is based on a multi-phyiscs ensemble of 30-year long MM5 hindcasted simulations performed over a complex and climatically heterogeneous domain as the Iberian Peninsula. The ensemble consists of eight members that results from combining different parametrization schemes for modeling the Planetary Boundary Layer, the cumulus and the microphysics processes. The analysis is made at the seasonal time scale and focuses on mean values and interannual variability of temperature and precipitation. The objectives are (1) to evaluate and characterize differences among the simulations attributable to changes in the physical options of the regional model, and (2) to identify the most suitable parametrization schemes and understand the underlying mechanisms causing that some schemes perform better than others. The results confirm the paramount importance of the model physics, showing that the spread among the various simulations is of comparable magnitude to the spread obtained in similar multi-model ensembles. This suggests that most of the spread obtained in multi-model ensembles could be attributable to the different physical configurations employed in the various models. Second, we obtain that no single ensemble member outperforms the others in every situation. Nevertheless, some particular schemes display a better performance. On the one hand, the non-local MRF PBL scheme reduces the cold bias of the simulations throughout the year compared to the local Eta model. The reason is that the former simulates deeper mixing layers. On the other hand, the Grell parametrization scheme for cumulus produces smaller amount of precipitation in the summer season compared to the more complex Kain-Fritsch scheme by reducing the overestimation in the simulated frequency of the convective precipitation events. Consequently, the interannual variability of precipitation (temperature) diminishes (increases), which implies a better agreement with the observations in both cases. Although these features improve in general the accuracy of the simulations, controversial nuances are also highlighted.