Removal of Volatile Organic Compounds in Vertical Flow Filters: Predictions from Reactive Transport Modeling

Vertical flow filters are containers filled with porous medium that are recharged from top and drained at the bottom, and are operated at partly saturated conditions. They have recently been suggested as treatment technology for groundwater containing volatile organic compounds (VOCs). Numerical reactive transport simulations were performed to investigate the relevance of different filter operation modes on biodegradation and/or volatilization of the contaminants and to evaluate the potential limitation of such remediation mean due to volatile emissions. On the basis of the data from a pilot‐scale vertical flow filter intermittently fed with domestic waste water, model predictions on the system’s performance for the treatment of contaminated groundwater were derived. These simulations considered the transport and aerobic degradation of ammonium and two VOCs, benzene and methyl tertiary butyl ether (MTBE). In addition, the advective‐diffusive gas‐phase transport of volatile compounds as well as oxygen was simulated. Model predictions addressed the influence of depth and frequency of the intermittent groundwater injection, degradation rate kinetics, and the composition of the filter material. Simulation results show that for unfavorable operation conditions significant VOC emissions have to be considered and that operation modes limiting VOC emissions may limit aerobic biodegradation. However, a suitable combination of injection depth and composition of the filter material does facilitate high biodegradation rates while only little VOC emissions take place. Using such optimized operation modes would allow using vertical flow filter systems as remediation technology suitable for groundwater contaminated with volatile compounds.     

2002 Kuiper prize lecture: Dust Astronomy

Dust particles, like photons, carry information from remote sites in space and time. From knowledge of the dust particles' birthplace and their bulk properties, we can learn about the remote environment out of which the particles were formed. This approach is called “Dust Astronomy” which is carried out by means of a dust telescope on a Dust Observatory in space. Targets for a dust telescope are the local interstellar medium and nearby star forming regions, as well as comets and asteroids. Dust from interstellar and interplanetary sources is distinguished by accurately sensing their trajectories. Trajectory sensors may use the electric charge signals that are induced when charged grains fly through the detector. Modern in-situ dust impact detectors are capable of providing mass, speed, physical and chemical information of dust grains in space. A Dust Observatory mission is feasible with state-of-the-art technology. It will (1) provide the distinction between interstellar dust and interplanetary dust of cometary and asteroidal origin, (2) determine the elemental composition of impacting dust particles, and (3) monitor the fluxes of various dust components as a function of direction and particle masses.     

Uncertainty management and the dynamic adjustment of deep decarbonization pathways

Contrary to ‘static’ pathways that are defined once for all, this article deals with the need for policy makers to adopt a dynamic adaptive policy pathway for managing decarbonization over the period of implementation. When choosing a pathway as the most desirable option, it is important to keep in mind that each decarbonization option relies on the implementation of specific policies and instruments. Given structural, effectiveness, and timing uncertainties specific to each policy option, they may fail in delivering the expected outcomes in time. The possibility of diverging from an initial decarbonization trajectory to another one without incurring excessive costs should therefore be a strategic element in the design of an appropriate decarbonization strategy. The article relies on initial experiences in France and Germany on decarbonization planning and implementation to define elements for managing dynamic adjustment issues. Such an adaptive pathway strategy should combine long-lived incentives, like a pre-announced escalating carbon price, to form consistent expectations, as well as adaptive policies to improve overall robustness and resilience. We sketch key elements of a monitoring process based on an ex ante definition of leading indicators that should be assessed regularly and combined with signposts and trigger values at the subsector level.

Policy relevance

These research questions are of special interest and urgency following the Paris Agreement in 2015. It calls on all countries to monitor the implementation of their national contributions and review their ambition regularly. The regular revision of decarbonization pathways constitute a great research opportunity to gather experiences on decarbonization pathway implementation and on dynamic management issues to progress towards an operational dynamic adaptive policy pathway mechanism.     

Numerical investigation of soil plugging inside open-ended piles with respect to the installation method

The development of a soil plug inside an open-ended pile with respect to the installation method is examined using numerical simulations. In this paper, the penetration process of an open-ended tubular pile with diameter D = 61 cm into granular soil is investigated. The aim is to achieve a better understanding of the mechanisms of soil plugging inside open-ended piles with respect to the installation method. As an example, the horizontal stress distribution inside the tubular pile after installation shows significant increase depending on the installation method. The numerical results are compared to experimental data.     

How the Enceladus dust plume feeds Saturn’s E ring

Pre-Cassini models of Saturn’s E ring [Horányi, M., Burns, J., Hamilton, D., 1992. Icarus 97, 248-259; Juhász, A., Horányi, M., 2002. J. Geophys. Res. 107, 1-10] failed to reproduce its peculiar vertical structure inferred from Earth-bound observations [de Pater, I., Martin, S.C., Showalter, M.R., 2004. Icarus 172, 446-454]. After the discovery of an active ice-volcanism of Saturn’s icy moon Enceladus the relevance of the directed injection of particles for the vertical ring structure of the E ring was swiftly recognised [Juhász, A., Horányi, M., Morfill, G.E., 2007. Geophys. Res. Lett. 34, L09104; Kempf, S., Beckmann, U., Moragas-Klostermeyer, G., Postberg, F., Srama, R., Economou, T., Schmidt, J., Spahn, F., Grün, E., 2008. Icarus 193, 420-437]. However, simple models for the delivery of particles from the plume to the ring predict a too small vertical ring thickness and overestimate the amount of the injected dust.Here we report on numerical simulations of grains leaving the plume and populating the dust torus of Enceladus. We run a large number of dynamical simulations including gravity and Lorentz force to investigate the earliest phase of the ring particle life span. The evolution of the electrostatic charge carried by the initially uncharged grains is treated selfconsistently. Freshly ejected plume particles are moving in almost circular orbits because the Enceladus orbital speed exceeds the particles’ ejection speeds by far. Only a small fraction of grains that leave the Hill sphere of Enceladus survive the next encounter with the moon. Thus, the flux and size distribution of the surviving grains, replenishing the ring particle reservoir, differs significantly from the flux and size distribution of the particles freshly ejected from the plume. Our numerical simulations reproduce the vertical ring profile measured by the Cassini Cosmic Dust Analyzer (CDA) [Kempf, S., Beckmann, U., Moragas-Klostermeyer, G., Postberg, F., Srama, R., EconoDmou, T., Smchmidt, J., Spahn, F., Grün, E., 2008. Icarus 193, 420-437]. From our simulations we calculate the deposition rates of plume particles hitting Enceladus’ surface. We find that at a distance of 100 m from a jet a 10 m sized ice boulder should be covered by plume particles in 10⁵-10⁶ years.     

Hazard assessment of underwater landslide-generated tsunamis: a case study in the Padang region, Indonesia

Submarine landslides can generate local tsunamis with high run-ups, posing a hazard to human lives and coastal facilities. Both ancient (giant Storegga slide off Norwegian coast, 8200 B. P.) and recent (Papua New Guinea, 1998) events show high potential danger of tsunamigenic landslides and the importance of mitigation efforts. This contribution presents newly discovered landslides 70 km off Padang (Western Sumatra, Indonesia) based on recent bathymetry measurements. This highly populated city with over 750,000 inhabitants exhibits high tsunami vulnerability due to its very low elevation. We model tsunamis that might have been induced by the detected landslide events. Estimations of run-up heights extrapolated from offshore tsunami amplitudes for Padang and other locations in the northern Mentawai fore-arc basin yield maximum values of about 3 m. We also provide a systematic parametric study of landslide-induced tsunamis, which allows us to distinguish potentially dangerous scenarios for Padang. Inside the fore-arc basin, scenarios involving volumes of 0.5–25 km³ could endanger Padang. Apart from slide volume, the hazard distribution mainly depends on three landslide parameters: distance to Padang, water depth in the generation region, and slide direction.     

Influence of pile installation on adjacent structures

Pile installation leads to significant changes in the main state variables of the surrounding soil. In addition, the installation process may have an influence on adjacent or intersecting structures such as pile grillages. In this paper, three‐dimensional numerical analyses are presented to investigate the effects of pile driving with open or closed cross‐sections on the surrounding soil and on adjacent structures. Two different installation methods are used: quasi‐static pile jacking and vibratory pile driving. The numerical models are evaluated and verified using data from field tests performed in situ during the construction of the quay wall at the container terminal CT4 in Bremerhaven. Two case studies are presented to characterize the main influence factors for additional loading on adjacent structures due to pile installation. Finally, a parametric study is conducted showing the influence of the installation method, pile cross‐section and distance of a pile from an existing structure on the additional loading for this structure. Copyright © 2009 John Wiley & Sons, Ltd.     

Diffusion,degradation or on-site stabilisation – Identifying causes of kinetic processes involved in metal–humate complexation

The applicability of equilibrium models for humic-bound transport of toxic or radioactive metals is affected by kinetic processes leading to an increasing inertness of metal–humic complexes. The chemical background is not yet understood. It is widely believed that bound metals undergo an in-diffusion process within the humic colloids, changing from weaker to stronger binding sites. This work is focussed on the competition effect of Al(III) on complexation of Tb(III) or Eu(III) as analogues of trivalent actinides. By using ion exchange and spectroscopic methods, their bound fractions were determined for solutions of Al and humic acid that had been pre-equilibrated for different periods of time. Whilst the amount of bound Al remained unchanged, its blocking effect was found to increase over a time frame of 2 days, which corresponds to the kinetics of the increase in complex inertness reported in most pertinent studies. Thus, the derived “diffusion theory” turned out to be inapplicable, since it cannot explain an increase in competition for the “initial” sites. A delayed degradation of polynuclear species (as found for Fe) does not occur. Consequently, the temporal changes must be based on structural rearrangements in the vicinity of bound Al, complicating the exchange or access. Time-dependent studies by laser fluorescence spectroscopy (steady-state and time-resolved) yielded evidence of substantial alterations, which were, however, immediately induced and did not show any significant trend on the time scale of interest, suggesting that the stabilisation process is based on comparatively moderate changes.