Geochemistry of Cd in groundwater of Winder,Balochistan and suspected health problems

Sedimentary rocks of Jurassic age (Ferozabad group) and igneous rocks (Bela Ophiolite) of Cretaceous age are widely exposed in the east of Winder Town, Balochistan. Representative 48 water and soil samples were collected and analyzed for Cd and other elements. The present study showed that water samples were contaminated by the Cd ion and most of the samples have higher concentration than prescribed WHO standards (3 μg/l) for drinking purpose. The concentration of Cd ions ranged between 1 and 30 with mean values of 10 μg/l and was found high in the vicinity of outcrops. The alkaline pH (av. 7.42) was mainly responsible for elevated Cd content in the water, having near equal molar proportions of Ca and HCO₃ ions. Computed relative mobility values appeared as 0.23, indicating poor leaching from rocks and metal load in the groundwater is also measured low. The estimated values of mobility reflect fairly high mobility of Cd in the study area, decreases with distance from outcrops. The health hazard indices of drinking water was high (av. 1.33) with respect to safe average daily intake of Cd. The consumption of high Cd-bearing water may induce many disorders in the human health.     

The Oued Mellègue: Mining activity,stream sediments and dispersion of base metals in natural environments,North-western Tunisia

In the Northwest of Tunisia, mining works have occurred in an area of vital water reserves and resources (Oued Mellègue and Oued Mejerda), which represent nearly 81% of total potential of water in the region. Demographic growth, insufficient drinkable water, agriculture and industrial plants are factors responsible for the strong demand of this resource. Water supply is done by an interconnected battery of dams built on the major watercourses, the first of which, the Mellègue dam, was erected in the 1960s. Nowadays, most of the mines are closed for almost two decades although one is still active: (Jerissa for Fe). It is important to emphasise the fact that there are millions of cubic metres of abandoned tailings, mainly from Pb–Zn–Ba mines, which are not surveyed, representing a serious threat to the environment.     

Recent developments in immobilizing titanium dioxide on supports for degradation of organic pollutants in wastewater- A review

This review focuses on the various types of supports used for immobilization of titanium dioxide nanomaterial catalyst for degradation of organic pollutants in wastewater. Several supports suitable to particular immobilization technique used for the degradation of pollutants in wastewater streams are explained. In general, a coating of catalyst on supports is carried out either by physical (e.g., thermal treatment) or by chemical (e.g., sol–gel). Among a range of the supports used, some of the prominent ones include glass, silica, activated carbon, stainless steel, cellulose, clay. Also, characterization methods in use such as X-ray diffraction, transmission electron microscope, scanning electron microscope, and UV-spectroscopy are discussed. The operating parameters such as temperature for the selected immobilization techniques are also explained.     

About the variability in thunderstorm and rainfall activity over India and its association with El Niño and La Niña

Thunderstorms are of much importance in tropics, as this region is considered to have central role in the convective overturn of the atmosphere and play an important role in rainfall activity. It is well known that El Niño and La Niña are well associated with significant climate anomalies at many places around the globe. Therefore, an attempt is made in this study to analyze variability in thunderstorm days and rainfall activity over Indian region and its association with El Niño and La Niña using data of thunderstorm day’s for 64 stations well distributed all over India for the period 1981–2005 (25 years). It is seen that thunderstorm activity is higher and much variable during pre-monsoon (MAM) and southwest monsoon (JJAS) than the rest of the year. Positive correlation coefficients (CCs) are seen between thunderstorms and rainfall except for the month of June during which the onset of the southwest monsoon sets over the country. CCs during winter months are highly correlated. Composite anomalies in thunderstorms during El Niño and La Niña years suggest that ENSO conditions altered the patterns of thunderstorm activity over the country. Positive anomalies are seen during pre-monsoon (MAM) and southwest monsoon months (JAS) during La Niña years. Opposite features are seen in southwest monsoon during El Niño periods, but El Niño favors thunderstorm activity during pre-monsoon months. There is a clear contrast between the role of ENSO during southwest monsoon and post-monsoon on thunderstorm activity over the country. Time series of thunderstorms and precipitation show strong association with similarities in their year-to-year variation over the country.     

Spherical harmonic analysis of earth’s conductive heat flow

A reappraisal of the international heat flow database has been carried out and the corrected data set was employed in spherical harmonic analysis of the conductive component of global heat flow. Procedures used prior to harmonic analysis include analysis of the heat flow data and determination of representative mean values for a set of discretized area elements of the surface of the earth. Estimated heat flow values were assigned to area elements for which experimental data are not available. However, no corrections were made to account for the hypothetical effects of regional-scale convection heat transfer in areas of oceanic crust. New sets of coefficients for 12° spherical harmonic expansion were calculated on the basis of the revised and homogenized data set. Maps derived on the basis of these coefficients reveal several new features in the global heat flow distribution. The magnitudes of heat flow anomalies of the ocean ridge segments are found to have mean values of less than 150 mW/m². Also, the mean global heat flow values for the raw and binned data are found to fall in the range of 56–67 mW/m², down by nearly 25% compared to the previous estimate of 1993, but similar to earlier assessments based on raw data alone. To improve the spatial resolution of the heat flow anomalies, the spherical harmonic expansions have been extended to higher degrees. Maps derived using coefficients for 36° harmonic expansion have allowed identification of new features in regional heat flow fields of several oceanic and continental segments. For example, lateral extensions of heat flow anomalies of active spreading centers have been outlined with better resolution than was possible in earlier studies. Also, the characteristics of heat flow variations in oceanic crust away from ridge systems are found to be typical of conductive cooling of the lithosphere, there being little need to invoke the hypothesis of unconfined hydrothermal circulation on regional scales. Calculations of global conductive heat loss, compatible with the observational data set, are found to fall in the range of 29–34 TW, nearly 25% less than the 1993 estimate, which rely on one-dimensional conductive cooling models.     

Destruction of a Holothuria scabra population by overfishing at Abu Rhamada Island in the Red Sea

Populations of Holothuria scabra at Abu Rhamada Island were investigated during 52 months, from July 1999 to October 2003. During the first 23 months (July, 1999-May, 2001) the Island had a robust population with a tri-modal size frequency distribution curve, very high densities (85.7-95.1 ind./100 m2 at the sandy habitat), high abundance (3362-3110 individuals) and biomass (46.7-34.3 kg/100 m2). Also, during this period most individuals were at depths between 4 and 6m and no individuals were recorded deeper than 15m. The population declined after harvesting began (June, 2001) and by March, 2002 the size frequency distribution showed a bimodal pattern with an obvious decrease in abundance of large individuals. There was also a slight reduction in densities (73.2-60.1 ind./100 m2 at the sandy habitat), abundance (2292-1682 individuals) and biomass (21.6-11.3 kg/100 m2), and a marked shift towards deeper waters. Overfishing reached its maximum during the final 19 months of the study, and by October, 2003, density (30.7-0.4 ind./100 m2 at the sandy habitat), abundance (802-10 individuals) and biomass (6.9-0.1 kg/100 m2) were all greatly reduced. The size frequency distribution of the population became unimodal, large animals disappeared and no recruits were seen. During this period, individuals were found at very deep depths (30 to >40 m). The study also showed that sandy substrate was the preferred habitat for H. scabra, accommodating the largest number of individuals. The population of H. scabra at Abu Rhamada Island was found to spawn biannually from 1999 to 2001, then only once during 2002 when high fishing pressure occurred, and ceased completely in 2003. The sex ratio was not significantly different from 1:1 before fishing begun, but shifted to an increasing male bias reaching 93% males by January 2003. None of the small animals remaining after January, 2003 could be sexed. Size at sexual maturity decreased from prefishing (185 mm for females and 160 mm for males) to 155 mm for females and 125 mm for males in January 2003. There was a positive relationship between fecundity and size. And oocyte/female was highest in 1999 (0.73-1.7 million) and 2000 (0.75-1.72 million), decreased during 2001 (0.2-0.85 million) to reach its minimum at 2002 (0.28-0.29 million).     

Climate change,environmental degradation and migration

Climate change will have a progressively increasing impact on environmental degradation and environmentally dependent socio-economic systems with potential to cause substantial population displacement. The key concerns in Less Developed Countries (LDCs) will include serious threats to food security and health, considerable economic decline, inundation of coastal areas, and degradation of land and fresh water resources (Reuveny in Polit Geogr, 2007). The relationship between environmental change and potential humanitarian crises has been captured by: McGregor (Geography and refugees: patterns and processes of change, Belhaven Press, London, pp 159–70, 1993), Kibreab (Environment and Population Change, International Union for the Scientific Study of Population, Liège, 1994), Kibreab (Disasters 21(1):20–38, 1997), Myers (Bioscience 43:752–761, 1993), Myers and Kent (Environmental exodus: an emergent crisis in the global arena, Climate Institute, Washington, DC, 1995), Black (New Issues in Refugee Research, Working Paper no. 34, 2001), Lee (Environmental matters: conflict, refugees and international relations, World Human Development Institute Press, Seoul and Tokyo, 2001), Castles (Environmental Change and Induced Migration: Making Sense of the Debate Working Paper No. 70, 2002), Christian Aid (Human tide: the real migration crisis, Christian Aid, London, 2007), and Massey et al. (, 2007). However, we know little about the interplay between environmental change and stresses on ecological systems, resulting socio-economic vulnerability and potential outcomes in terms of population displacement or induced migration. So far these relationships are poorly conceptualized, lack systematic investigation, and are reduced to simplistic causal explanations. This leads to misleading conclusions that deny the complex multivariate processes—environmental, political, social, and economic— which are the root causes of environmentally induced migration and/or conflict. When people are faced with severe environmental degradation they have one of three options: (1) stay and adapt to mitigate the effects; (2) stay, do nothing and accept a lower quality of life; or (3) leave the affected area. The process of movement and migration is usually subject to a complex set of push and pull forces, where push forces relate to the source area while pull factors relate to the destination. These forces are in constant flux, as much as environmental change, and interact with socio-economic and political conditions including state or government decision making powers, which can tip the balance at any point by either denying movement or the right to settle elsewhere. The paper focuses on how environmental change and environmental hazards contribute to the migration by exploring the mechanisms through which vulnerability and migration are linked—via livelihoods, relocation policies, and other factors. The paper begins by outlining important definitions of what is environmentally induced migration. The paper also considers the question of whether migration is a process that reduces or increases vulnerability. The paper draws on multidisciplinary literature including ecology, environment, and climate change; sociology of migration; anthropology of displacement; and economics; but also on preliminary from various case studies in Egypt, Vietnam, and Mozambique.     

断层含水层在非等温条件下的构造性渗流——一种震前热前兆异常产生的机理

本文用一个简单的解析模式来计算,在被断层带切断的含水层,由于形变产生的渗流引起的热量瞬时流动。在这个模式中,含水层流体的补给被假定只是通过弱隔水层垂向渗流。在这种条件下,能量平衡方程要计算由于含水层体积变化和形变产生的水力压头变化引起的流体水平向和垂直向流动的单位热量传递。数值模拟的结果表明在应力增加期,当渗流的地下水与含水层的地下水混合的时候,地温就表现为瞬时的升高。相应地,当这一渗流过程停止的时候,地温迅速回到平衡状态。利用此解析模型,可以重建观测记录中的地温前兆异常特征。按照模型的结果,地温升高达到稳定状态的时间和流体的补给率相关。热异常的幅度与弱隔水层的温度梯度有关,弱隔水层与含水层之间的渗透率也起到很重要的作用。模型的结果表明热前兆异常只是在离断层近的区域表现明显,由于在这个区域构造渗流的过程对含水层的水力压头有直接的影响。如果断层面对形变敏感,应力模式的改变会使得构造渗流率发生永久的改变,从而很容易使区域的温度场产生剧烈的、不可恢复的改变。在某些构造活跃区域的井孔地温记录中,一些短临异常变化的特征和按照“构造渗流”模型的预测结果非常相似。在土库曼斯坦的Firjusa、乔治亚州的Didiweli和日本的Izu peninsnla都有这种震前热前兆模型的例子。研究表明,与小规模构造形变相关的热前兆异常并不是罕见的。热前兆异常的监测要有合适的井孔和高精度的监测仪器,其观测时间至少要与区域地震复发周期相当。