Uraninite recrystallization and Pb loss in the Oklo and Bangombé natural fission reactors, Gabon

The Oklo and Bangombé natural fossil fission reactors formed ca. 2 Ga ago in the Franceville basin, Gabon. The response of uraninite in the natural reactors to different geological conditions has implications for the disposal of the UO₂ in spent nuclear fuel. Uraninite and galena from two reactor zones, RZ16 at Oklo and RZB at Bangombé, were studied to clarify the chronology and effect of alteration events on the reactor zones. In addition, ion microprobe U-Pb analysis of zircons from a dolerite dyke in the Oklo deposit were completed to better constrain the age of the dyke, and thereby testing the link between the dyke and an important alteration event in the reactor zones.The analyzed uraninite from RZ16 and RZB contains ca. 6 wt% PbO, indicating a substantial loss of radiogenic Pb. Transmission electron microscopy showed that microscopic uraninite grains in the reactor zones consist of mainly defect-free nanocrystalline to microcrystalline aggregates. However, the nanocrystalline regions have elevated Si contents and lower Pb contents than coarser uraninite crystallites. Single stage model ages of large, millimeter-sized galena grains at both RZ16 and RZB correlate well with the age of the Oklo dolerite dyke, 860 ± 39 Ma (2σ). Thus, the first major Pb loss from uraninite occurred at both Oklo and Bangombé during regional extension and the intrusion of a dyke swarm in the Franceville basin, ∼860-890 Ma ago. Uraninite Pb isotopes from RZ16 and RZB give lower ages of ca. 500 Ma. These ages agree with the “chemical” ages of the uraninite, and show that an ancient Pb loss occurred after the intrusion of the dolerite dykes. The presence of nanocrystallites in the reactor uraninite indicates internal recrystallization, which may have occurred around 500 Ma, resulting in the 6wt% PbO uraninite. It is suggested that leaching by fluid interaction triggered by the Pan-African orogeny was important during this second Pb-loss event. Thus, there are indications that uraninite at both the Oklo and Bangombé natural reactors has experienced at least two ancient episodes of Pb loss associated with internal recrystallization. These recrystallization events have occurred without significantly depleting the 2 Ga fission products compatible with the uraninite structure.     

A lunar cryptomare dome near Mee H and Drebbel F

In this study, we examine the lunar mare dome Mee 1 situated near the craters Mee H and Drebbel F in a region showing evidence of ancient (pre-Orientale) mare volcanism and cryptomare deposits. Regional stratigraphic relations indicate that Mee 1 was formed prior to the Orientale impact at the beginning of the Imbrian period. Based on a combined photoclinometry and shape from shading technique applied to telescopic CCD images of the dome acquired under oblique illumination, we determined a diameter of Mee 1 of 25 km, a height of 250 m, a flank slope of 1.15^°, and a volume of . Based on rheologic modelling of the dome and a viscoelastic model of the feeder dike, we obtained a magma viscosity of , an effusion rate of , a duration of the effusion process of 1.6 years, a magma rise speed of , a width of the feeder dike of 32 m, and a horizontal dike length of 144 km. A comparison of Mee 1 with domes with similar morphometric properties, which are located near Milichius and inside the crater Petavius, reveals strong similarities with respect to the viscosity of the dome-forming magma and the feeder dike geometry, while the effusion rate and magma rise speed of Mee 1 are somewhat higher. The pronounced morphometric differences between Mee 1 and a smaller dome situated close to the crater Doppelmayer and characterised by a similar magma viscosity suggest that the growth of that dome was limited by exhaustion of the magma reservoir, while Mee 1 and the other larger domes display morphometric properties presumably coming closer to the cooling limit. The comparison of the ancient dome Mee 1 with the younger (Eratosthenian) edifices near Milichius and Doppelmayer suggests that the conditions in the upper mantle and the crust favoured high eruption volumes, effusion rates, and magma rise speeds, implying the occurrence of large magma reservoirs preventing the limitation of dome growth by magma exhaustion. On the other hand, we observe similar general morphometric, rheologic, and feeder dike characteristics and, thus, conclude that the formation conditions of lunar mare domes did not change fundamentally during the Imbrian period.     

Detailed geomorphological survey of a small mountain drainage area, Abisko, northern Swedish Lapland

A thorough geomorphological survey of a small (2km²) drainage area has been conducted using digital magnification of aerial photographs in conjunction with field visits. The result presented is a geomorphological map where individual geomorphological features down to metre size can be identified. The study was done in connection with a project focusing on the relationship between geomorphological processes and lacustrine sedimentation. Good knowledge of the geomorphological setting and the related process activity in the catchment is important in studies using lacustrine sediments as environmental archives.
The survey reveals a small–scale geomorphology dominated by a number of different periglacial upfreezing forms together with bedrock–controlled slope processes. Three different geographically separated geomorphological assemblages were recognised with few sediment transportation pathways connecting them. Composition of substrate, soil water content and vegetation cover combined with different slope angles are probably the most important factors controlling the distribution of the geomorphological features.     

Nocturnal Near-Surface Temperature,but not Flow Dynamics,can be Predicted by Microtopography in a Mid-Range Mountain Valley

We investigate nocturnal flow dynamics and temperature behaviour near the surface of a 170-m long gentle slope in a mid-range mountain valley. In contrast to many existing studies focusing on locations with significant topographic variations, gentle slopes cover a greater spatial extent of the Earth’s surface. Air temperatures were measured using the high-resolution distributed-temperature-sensing method within a two-dimensional fibre-optic array in the lowest metre above the surface. The main objectives are to characterize the spatio-temporal patterns in the near-surface temperature and flow dynamics, and quantify their responses to the microtopography and land cover. For the duration of the experiment, including even clear-sky nights with weak winds and strong radiative forcing, the classical cold-air drainage predicted by theory could not be detected. In contrast, we show that the airflow for the two dominant flow modes originates non-locally. The most abundant flow mode is characterized by vertically-decoupled layers featuring a near-surface flow perpendicular to the slope and strong stable stratification, which contradicts the expectation of a gravity-driven downslope flow of locally produced cold air. Differences in microtopography and land cover clearly affect spatio-temporal temperature perturbations. The second most abundant flow mode is characterized by strong mixing, leading to vertical coupling with airflow directed down the local slope. Here variations of microtopography and land cover lead to negligible near-surface temperature perturbations. We conclude that spatio-temporal temperature perturbations, but not flow dynamics, can be predicted by microtopography, which complicates the prediction of advective-heat components and the existence and dynamics of cold-air pools in gently sloped terrain in the absence of observations.     

Application of micro-computed X-ray tomography for improving the hole erosion test analysis on high plastic clay

Acta Geotechnica - The hole erosion test (HET) was developed to simulate piping erosion and to study the erosion parameters of cohesive soils. The erosion rate in the HET is evaluated by the...     

Nonsulfide and sulfide-rich zinc mineralizations in the Vazante, Ambrósia and Fagundes deposits, Minas Gerais, Brazil: Mass balance and stable isotope characteristics of the hydrothermal alterations

The Vazante Group hosts the Vazante nonsulfide zinc deposit, which comprises high-grade zinc silicate ore (ZnSiO₄), and late-diagenetic to epigenetic carbonate-hosted sulfide-rich zinc deposits (e.g. Morro Agudo, Fagundes, and Ambrósia). In the sulfide-rich deposits, hydrothermal alteration involving silicification and dolomitization was related with ground preparation of favorable zones for fluid migration (e.g. Fagundes) or with direct interaction with the metalliferous fluid (e.g. Ambrósia). At Vazante, hydrothermal alteration resulted in silicification and dolomite, siderite, jasper, hematite, and chlorite formation. These processes were accompanied by strong relative gains of SiO₂, Fe₂O_3(T), Rb, Sb, V, U, and La, which are typically associated with the nonsulfide zinc mineralization. All sulfide-rich zinc ores in the district display a similar geochemical signature suggesting a common metal source from the underlying sedimentary sequences.Oxygen and carbon isotope compositions of hydrothermally altered rocks reveal a remarkable alteration halo at the Vazante deposit, which is not a notable feature in the sulfide-rich deposits. This pattern could be attributed to fluid mixing processes involving the metalliferous fluid and channelized meteoric water, which may control the precipitation of the Vazante nonsulfide ore. Sulfide deposition resulted from fluid–rock interaction processes and mixing between the ascending metalliferous fluids and sulfur-rich tectonic brines derived from reduced shale units.     

Formation of lunar mare domes along crustal fractures: Rheologic conditions, dimensions of feeder dikes, and the role of magma evolution

In this study we examine a set of lunar mare domes located in the Hortensius/Milichius/T. Mayer region and in northern Mare Tranquillitatis with respect to their formation along crustal fractures, their rheologic properties, the dimensions of their feeder dikes, and the importance of magma evolution processes during dome formation. Many of these domes display elongated summit vents oriented radially with respect to major impact basins, and several dome locations are also aligned in these preferential directions. Analysis of Clementine UV/VIS and Lunar Prospector gamma ray spectrometer data reveals that the examined mare domes formed from low-Si basaltic lavas of high FeO and low to moderate TiO₂ content. Based on their morphometric properties (diameter, height, volume) obtained by photoclinometric and shape from shading analysis of telescopic CCD images, we derive rheologic quantities (lava viscosity during eruption, effusion rate, duration of the effusion process, magma rise speed) and the dimensions of the feeder dikes. We establish three rheologic groups characterised by specific combinations of rheologic properties and dike dimensions, where the most relevant discriminative parameter is the lava viscosity η. The first group is characterised by and contains the domes with elongated vents in the Milichius/T. Mayer region and two similar domes in northern Mare Tranquillitatis. The second group with comprises the very low aligned domes in northern Mare Tranquillitatis, and the third group with the relatively steep domes near Hortensius and in the T. Mayer region. The inferred dike dimensions in comparison to lunar crustal thickness data indicate that the source regions of the feeder dikes are situated within the upper crust for six of the domes in northern Mare Tranquillitatis, while they are likely to be located in the lower crust and in the upper mantle for the other examined domes. By comparing the time scale of magma ascent with the time scale on which heat is conducted from the magma into the host rock, we find evidence that the importance of magma evolution processes during ascent such as cooling and crystallisation increases with lava viscosity. We conclude that different degrees of evolution of initially fluid basaltic magma are able to explain the broad range of lava viscosities inferred for the examined mare domes. The spectral data reveal that differences in TiO₂ content may additionally account for the systematic difference in lava viscosity between the two examined lunar regions. We show that the described mechanisms are likely to be valid also for other lunar mare domes situated near Cauchy and Arago, regarded for comparison. On the other hand, we find for the Gruithuisen and Mairan highland domes that despite their inferred high lava viscosities of , no significant magma cooling in the dike occurred during ascent, supporting previous findings that the highland domes were formed during a specific phase of non-mare volcanism by highly silicic viscous lavas.